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Title: Photoinduced Electron Transfer in an Ethyne Bridged Donor-Acceptor Complex Depends Strongly on Torsion Angle
Photoinduced electron transfer (ET) between electron donor (dimethylaniline) and acceptor (N-isopropyl-1,8-napthalimide) covalently linked by ethyne bridge is investigated by a mid-IR transient absorption spectroscopy and TD-DFT computations. We found that electronic and vibrational properties of the complex, including ET rate, depends strongly on the D-A torsion angle.  more » « less
Award ID(s):
1954853
PAR ID:
10253689
Author(s) / Creator(s):
; ; ; ; ; ; ;
Editor(s):
Kubarych, Kevin; Ogilvie, Jennifer
Date Published:
Journal Name:
International Conference on Time Resolved Vibrational Spectroscopy
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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