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   Jin, Shengfei; Dang, Hang T.; Haug, Graham C.; Nguyen, Viet D.; Arman, Hadi D.; Larionov, Oleg V. (September 2020, Chemical Science)

   null (Ed.)

   Construction of C–C bonds at the α-carbon is a challenging but synthetically indispensable approach to α-branched carbonyl motifs that are widely represented among drugs, natural products, and synthetic intermediates. Here, we describe a simple approach to generation of boron enolates in the absence of strong bases that allows for introduction of both α-alkyl and α-aryl groups in a reaction of readily accessible 1,2-dicarbonyls and organoboranes. Obviation of unselective, strongly basic and nucleophilic reagents permits carrying out the reaction in the presence of electrophiles that intercept the intermediate boron enolates, resulting in two new α-C–C bonds in a tricomponent process. 

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5. Polynomial α-attractors

   https://doi.org/10.1088/1475-7516/2022/04/017  

   Kallosh, Renata; Linde, Andrei (April 2022, Journal of Cosmology and Astroparticle Physics)

   Abstract Inflationary α -attractor models can be naturally implemented in supergravity with hyperbolic geometry. They have stable predictions for observables, such as n s = 1 - 2/ N e , assuming that the potential in terms of the original geometric variables, as well as its derivatives, are not singular at the boundary of the hyperbolic disk, or half-plane. In these models, the potential in the canonically normalized inflaton field φ has a plateau, which is approached exponentially fast at large φ . We call them exponential α-attractors . We present a closely related class of models, where the potential is not singular, but its derivative is singular at the boundary. The resulting inflaton potential is also a plateau potential, but it approaches the plateau polynomially. We call them polynomial α-attractors . Predictions of these two families of attractors completely cover the sweet spot of the Planck/BICEP/Keck data. The exponential ones are on the left, the polynomial are on the right. 

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