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   https://doi.org/10.29356/jmcs.v67i4.2014  

   Alpuche Aviles, Mario A; Gutierrez-Portocarrero, Salvador (September 2023, Journal of the Mexican Chemical Society)

   Single-particle electrochemistry has become an important area of research with the potential to determine the rules of electrochemical reactivity at the nanoscale. These techniques involve addressing one entity at the time, as opposed to the conventional electrochemical experiment where a large number of molecules interact with an electrode surface. These experiments have been made feasible  through the utilization of ultramicroelectrode (UMEs), i.e., electrodes with at least one dimension, e.g., diameter of 30 μm or less. This paper provides a theoretical and practical introduction to single entity electrochemistry (SEE), with emphasis on collision experiments between suspended NPs and UMEs to introduce concepts and techniques that are used in several SEE experimental modes. We discuss the intrinsically small currents, below 1 nA, that result from the electroactive area of single entities in the nanometer scale. Individual nanoparticles can be detected using the difference in electrochemical reactivity between a substrate and a nanoparticle (NP). These experiments show steady-state behavior of single NPs that result in discrete current changes or steps. Likewise, the NP can have transient interactions with the substrate electrode that result in current blips. We review the effect of diffusion, the main mass transport process that limits NP/electrode interactions. Also, we pointed out the implications of aggregation and tunneling in the experiments. Finally, we provid a perspective on the possible applications of single-element electrochemistry of electrocatalyst. 

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2. Elastic solution of a polyhedral particle with a polynomial eigenstrain and particle discretization

   https://doi.org/10.1115/1.4051869  

   Wu, Chunlin; Zhang, Liangliang; Yin, Huiming (August 2021, Journal of Applied Mechanics)

   null (Ed.)

   Abstract The paper extends the recent work (JAM, 88, 061002, 2021) of the Eshelby's tensors for polynomial eigenstrains from a two dimensional (2D) to three dimensional (3D) domain, which provides the solution to the elastic field with continuously distributed eigenstrain on a polyhedral inclusion approximated by the Taylor series of polynomials. Similarly, the polynomial eigenstrain is expanded at the centroid of the polyhedral inclusion with uniform, linear and quadratic order terms, which provides tailorable accuracy of the elastic solutions of polyhedral inhomogeneity by using Eshelby's equivalent inclusion method. However, for both 2D and 3D cases, the stress distribution in the inhomogeneity exhibits a certain discrepancy from the finite element results at the neighborhood of the vertices due to the singularity of Eshelby's tensors, which makes it inaccurate to use the Taylor series of polynomials at the centroid to catch the eigenstrain at the vertices. This paper formulates the domain discretization with tetrahedral elements to accurately solve for eigenstrain distribution and predict the stress field. With the eigenstrain determined at each node, the elastic field can be predicted with the closed-form domain integral of Green's function. The parametric analysis shows the performance difference between the polynomial eigenstrain by the Taylor expansion at the centroid and the 𝐶0 continuous eigenstrain by particle discretization. Because the stress singularity is evaluated by the analytical form of the Eshelby's tensor, the elastic analysis is robust, stable and efficient. 

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3. Cosmological particle production: a review

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   Ford, L H (October 2021, Reports on Progress in Physics)

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4. A survey of feedback particle filter and related controlled interacting particle systems (CIPS)

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   Cheng, Cih; Moon, Yoon Jae; Hwang, Jun Young; Chiu, George T.-C.; Han, Bumsoo (August 2022, International Journal of Heat and Mass Transfer)