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1. Evidence of cluster dipole states in germanium detectors operating at temperatures below 10 K

   https://doi.org/10.1063/5.0094194  

   Mei, D-M; Panth, R.; Kooi, K.; Mei, H.; Bhattarai, S.; Raut, M.; Acharya, P.; Wang, G-J (June 2022, AIP Advances)

   By studying charge trapping in germanium detectors operating at temperatures below 10 K, we demonstrate for the first time that the formation of cluster dipole states from residual impurities is responsible for charge trapping. Two planar detectors with different impurity levels and types are used in this study. When drifting the localized charge carriers created by α particles from the top surface across a detector at a lower bias voltage, significant charge trapping is observed when compared to operating at a higher bias voltage. The amount of charge trapping shows a strong dependence on the type of charge carriers. Electrons are trapped more than holes in a p-type detector, while holes are trapped more than electrons in an n-type detector. When both electrons and holes are drifted simultaneously using the widespread charge carriers created by γ rays inside the detector, the amount of charge trapping shows no dependence on the polarity of bias voltage. 

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2. Development of planar P-type point contact germanium detectors for low-mass dark matter searches

   https://doi.org/10.1140/epjc/s10052-022-10162-x  

   Wei, W.-Z.; Mei, H.; Kooi, K.; Mei, D.-M.; Liu, J.; Li, J.-C.; Panth, R.; Wang, G.-J. (March 2022, The European Physical Journal C)

   Abstract The detection of low-energy deposition in the range of sub-eV through ionization using germanium (Ge) with a bandgap of $$\sim $$ ∼ 0.7 eV requires internal amplification of the charge signal. This can be achieved through high electric field that accelerates charge carriers, which can then generate more charge carriers. The minimum electric field required to generate internal charge amplification is derived for different temperatures. We report the development of a planar point contact Ge detector in terms of its fabrication and the measurements of its leakage current and capacitance as a function of applied bias voltage. With the determination of the measured depletion voltage, the field distribution is calculated using GeFiCa, which predicts that the required electric field for internal charge amplification can be achieved in proximity to the point contact. The energy response to an Am-241 source is characterized and discussed. We conclude that such a detector with internal charge amplification can be used to search for low-mass dark matter. 

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3. Ab initio nonadiabatic molecular dynamics of charge carriers in metal halide perovskites

   https://doi.org/10.1039/d1nr01990b  

   Li, Wei; She, Yalan; Vasenko, Andrey S.; Prezhdo, Oleg V. (June 2021, Nanoscale)

   Photoinduced nonequilibrium processes in nanoscale materials play key roles in photovoltaic and photocatalytic applications. This review summarizes recent theoretical investigations of excited state dynamics in metal halide perovskites (MHPs), carried out using a state-of-the-art methodology combining nonadiabatic molecular dynamics with real-time time-dependent density functional theory. The simulations allow one to study evolution of charge carriers at the ab initio level and in the time-domain, in direct connection with time-resolved spectroscopy experiments. Eliminating the need for the common approximations, such as harmonic phonons, a choice of the reaction coordinate, weak electron–phonon coupling, a particular kinetic mechanism, and perturbative calculation of rate constants, we model full-dimensional quantum dynamics of electrons coupled to semiclassical vibrations. We study realistic aspects of material composition and structure and their influence on various nonequilibrium processes, including nonradiative trapping and relaxation of charge carriers, hot carrier cooling and luminescence, Auger-type charge–charge scattering, multiple excitons generation and recombination, charge and energy transfer between donor and acceptor materials, and charge recombination inside individual materials and across donor/acceptor interfaces. These phenomena are illustrated with representative materials and interfaces. Focus is placed on response to external perturbations, formation of point defects and their passivation, mixed stoichiometries, dopants, grain boundaries, and interfaces of MHPs with charge transport layers, and quantum confinement. In addition to bulk materials, perovskite quantum dots and 2D perovskites with different layer and spacer cation structures, edge passivation, and dielectric screening are discussed. The atomistic insights into excited state dynamics under realistic conditions provide the fundamental understanding needed for design of advanced solar energy and optoelectronic devices. 

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4. Topologies of $$^{76}$$Ge double-beta decay events and calibration procedure biases

   https://doi.org/10.1140/epjc/s10052-023-11396-z  

   Comellato, Tommaso; Agostini, Matteo; Schönert, Stefan (March 2023, The European Physical Journal C)

   Abstract The analysis of the time profile of electrical signals produced by energy depositions in germanium detectors allows discrimination of events with different topologies. This is especially relevant for experiments searching for the neutrinoless double beta decay of $$^{76}$$ 76 Ge to distinguish the sought-after signal from other background sources. The standard calibration procedures used to tune the selection criteria for double-beta decay events use a $$^{228}$$ 228 Th source, because it provides samples of signal-like events. These samples exhibit energy spatial distributions with subtle different topologies compared to neutrinoless double-beta decay events. In this work, we will characterize these topological differences and, with the support of a $$^{56}$$ 56 Co source, evaluate biases and precision of calibration techniques which use such event samples. Our results will be particularly relevant for future experiments in which a solid estimation of the efficiency is required. 

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5. Plasmon-Induced Electron Transfer between Gold Nanorods and a Carbon Thin Film

   https://doi.org/10.1021/acs.jpcc.3c07754  

   Vo, Tamie; Chang, Wei-Shun (January 2024, The Journal of Physical Chemistry C)

   Plasmonic nanostructures have been demonstrated as emergent photocatalysts because of their efficient photon absorption and their ability to produce hot carriers. However, the plasmon-generated hot carriers decay through ultrafast relaxation pathways, resulting in a short lifetime that impedes the exploitation of hot carriers for chemical reactions. Charge separation at the heterojunction of the hybrid nanostructures can counteract the ultrafast decay to extend the carrier lifetime. Here, we fabricate hybrid nanostructures composed of gold nanorods and a carbon thin film and demonstrate efficient charge transfer between these two materials. Using single-particle dark-field scattering spectroscopy, we observe a broadening of the longitudinal plasmon for gold nanorods on a carbon film compared to those on a glass substrate. We attribute this plasmon damping to the electron transfer from gold nanorods to the carbon film and exclude the contribution from plasmon-induced resonance energy transfer. The electron transfer efficiencies are calculated as 52.8 ± 4.8 and 57.4 ± 4.0% for carbon films with thicknesses of 10 and 25 nm, respectively. This work demonstrates efficient charge separation at the gold–carbon film interface, which can extend the lifetime of hot carriers to promote plasmonic photocatalysts. 

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