<?xml-model href='http://www.tei-c.org/release/xml/tei/custom/schema/relaxng/tei_all.rng' schematypens='http://relaxng.org/ns/structure/1.0'?><TEI xmlns="http://www.tei-c.org/ns/1.0">
	<teiHeader>
		<fileDesc>
			<titleStmt><title level='a'>Winding down the Chicxulub impact: The transition between impact and normal marine sedimentation near ground zero</title></titleStmt>
			<publicationStmt>
				<publisher></publisher>
				<date>12/01/2020</date>
			</publicationStmt>
			<sourceDesc>
				<bibl> 
					<idno type="par_id">10291888</idno>
					<idno type="doi">10.1016/j.margeo.2020.106368</idno>
					<title level='j'>Marine Geology</title>
<idno>0025-3227</idno>
<biblScope unit="volume">430</biblScope>
<biblScope unit="issue">C</biblScope>					

					<author>Michael T. Whalen</author><author>Sean P.S. Gulick</author><author>Christopher M. Lowery</author><author>Timothy J. Bralower</author><author>Joanna V. Morgan</author><author>Kliti Grice</author><author>Bettina Schaefer</author><author>Jan Smit</author><author>Jens Ormö</author><author>Axel Wittmann</author><author>David A. Kring</author><author>Shelby Lyons</author><author>Steven Goderis</author>
				</bibl>
			</sourceDesc>
		</fileDesc>
		<profileDesc>
			<abstract><ab><![CDATA[subsequent continental margin collapse events. Highly siderophile element-enrichment at the top of the unit is likely from fine-grained ejecta that circulated in the atmosphere for several years prior to settling. The Transitional Unit is thus an exquisite record of the final phases of impact-related sedimentation related to one of the most consequential events in Earth history.]]></ab></abstract>
		</profileDesc>
	</teiHeader>
	<text><body xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:xlink="http://www.w3.org/1999/xlink">
<div xmlns="http://www.tei-c.org/ns/1.0"><p>The Chicxulub impact led to the formation of a ~ 200-km wide by ~1-km deep crater on M&#233;xico's Yucat&#225;n Peninsula. Over a period of hours after the impact the ocean re-entered and covered the impact basin beneath several hundred meters of water. A suite of impactites were deposited across the crater during crater formation, and by the resurge, tsunami and seiche events that followed. International Ocean Discovery Program/International Continental Scientific Drilling Program Expedition 364 drilled into the peak ring of the Chicxulub crater, and recovered ~130 m of impact deposits and a 75-cm thick, fine-grained, carbonate-rich "Transitional Unit", above which normal marine sedimentation resumed. Here, we describe the results of analyses of the uppermost impact breccia (suevite) and the Transitional Unit, which suggests a gradual waning of energy recorded by this local K-Pg boundary sequence.</p><p>The dominant depositional motif in the upper suevite and the Transitional Unit is of rapid sedimentation characterized by graded bedding, local cross bedding, and evidence of oscillatory currents. The lower Transitional Unit records the change from deposition of dominantly sand-sized to mainly silt to clay sized material with impact debris that decreases in both grain size and abundance upward. The middle part of the Transitional Unit is interrupted by a 20 cm thick soft sediment slump overlain by graded and oscillatory current cross-laminated beds. The uppermost Transitional Unit is also soft sediment deformed, contains trace fossils, and an increasing abundance of planktic foraminifer and calcareous nannoplankton survivors. The Transitional Unit, as with similar deposits in other marine target impact craters, records the final phases of impact-related sedimentation prior to resumption of normal marine conditions. Petrographic and stable isotopic analyses of carbon from organic matter provide insight into post-impact processes. &#948; 13 C org values are between terrestrial and marine end members with fluctuations of 1-3&#8240;.</p><p>Timing of deposition of the Transitional Unit is complicated to ascertain. The repetitive normally graded laminae, both below and above the soft sediment deformed interval, record rapid deposition from currents driven by tsunami and seiches, processes that likely operated for weeks to potentially years post-impact due to</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="1.">Introduction</head><p>Chicxulub, on the Yucat&#225;n Peninsula of M&#233;xico, is one of the bestpreserved impact structures on Earth due to its relatively rapid burial by Paleogene carbonate sediments (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Morgan &amp; Warner, 1999;</ref><ref type="bibr">Whalen et al., 2013)</ref>. For this reason, the Chicxulub impact structure affords an ideal natural laboratory for documenting cratering events, impact processes, impact melt and breccia deposition, and sedimentary infill of a marine target crater <ref type="bibr">(Gulick et al., 2017;</ref><ref type="bibr">Morgan et al., 2016)</ref>.</p><p>Asteroid or comet impacts into marine target rocks produce a distinctive suite of deposits that are related to crater formation, impact breccia and melt-rock deposition, and resurge of seawater into the crater that reworks and redeposits breccia and melt-rock <ref type="bibr">(Dypvik &amp; Jansa, 2003;</ref><ref type="bibr">Orm&#246; &amp; Lindstr&#246;m, 2000;</ref><ref type="bibr">W&#252;nnemann &amp; Lange, 2002)</ref>. Of the Fig. <ref type="figure">1</ref>. A) Location of IODP-ICDP Site M0077 in the Gulf of Mexico and other wells illustrated in Fig. <ref type="figure">2</ref>. The red rectangle indicates the location of B. B) Various crater features like the exterior ring fault (blue dashed line), crater rim (white dashed line), missing crater rim (thick solid white line), and peak ring (solid black line), are illustrated over a Bouguer gravity anomaly map of the Chicxulub impact structure (gravity data courtesy of A. <ref type="bibr">Hildebrand and M. Pilkington)</ref>. The Yucat&#225;n coastline is displayed with the thin white line. Small black dots around southern crater rim indicate cenotes. The location of Site M0077 and Yax-1 are illustrated with red stars. The city of Merida is indicated with a purple star. The position of the seismic line in C is denoted with a red line next to the red star indicating site M0077. Modified from work by <ref type="bibr">Gulick et al. (2008)</ref>, <ref type="bibr">Christensen et al. (2018)</ref>, and <ref type="bibr">Lowery et al. (2018)</ref>. C) Seismic reflection image shown in depth with full waveform velocities overlain. The position of Site M0077 atop the peak ring is illustrated with the crater center toward the southeast. Modified from work by <ref type="bibr">Morgan et al. (2011)</ref> and <ref type="bibr">Morgan et al. (2016)</ref>. D) Lithology documented at Site M0077 from 503.6 m to total depth, illustrating Paleogene sedimentary rocks, suevite, impact melt rock, felsic granitoid basement, suevite and melt rock dikes, and pre-and post-impact dikes. Modified from the work of <ref type="bibr">Morgan et al. (2016)</ref>. (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.) previously documented marine impacts, only the Chesapeake Bay impact structure (CBIS; <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2008;</ref><ref type="bibr">Poag, 1997;</ref><ref type="bibr">Poag, 2002)</ref>), Mj&#248;lnir <ref type="bibr">(Dypvik et al., 2004)</ref>, Lockne and Tv&#228;ren <ref type="bibr">(Frisk &amp; Orm&#246;, 2007;</ref><ref type="bibr">Orm&#246; et al., 2007)</ref> have well documented records of this transition from impact-related to normal marine sedimentation. The nearly continuous core-recovery and exceptionally complete record at International Ocean Discovery Program/International Continental Scientific Drilling Program (IODP-ICDP) Site M0077 on the peak ring (an uplifted ring of mountains surrounding the crater's center) of Chicxulub <ref type="bibr">(Morgan et al., 2017)</ref> provides insight into the depositional processes operating as the energy associated with the impact and subsequent seismic and continental margin collapse events waned <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Sanford et al., 2016)</ref>.</p><p>Analysis of marine impact deposits and numerical modeling suggests that oblique impacts and those with varying water depths result in strongly asymmetric resurge <ref type="bibr">(Orm&#246; et al., 2010a;</ref><ref type="bibr">W&#252;nnemann et al., 2007)</ref>. Impact angle and trajectory for Chicxulub were initially examined using gravity data, where conflicting arguments were made on the position of the buried central peak <ref type="bibr">(Hildebrand et al., 1991)</ref> versus a basement feature <ref type="bibr">(Schultz &amp; D'Hondt, 1996)</ref>. Another study looked into how surficial features of impacts such as position of the peak ring or central uplift are not definitive in terms of tracking impact direction <ref type="bibr">(McDonald et al., 2008)</ref>. A full 3D model of the impact matched against the crustal structure from joint seismic and gravity data was required to work out the signature of impact direction. These data were summarized in <ref type="bibr">Gulick et al. (2013)</ref> and the impact trajectory was convincingly modeled with a clear fit to the data at Chicxulub by <ref type="bibr">Collins et al. (2020)</ref>. This singular attempt at a full 3D hydrocode model of the impact, that matches with the 3D velocity model from refraction data and joint inversions with the gravity data, supports the conclusion of a steeplyinclined (45-60 &#8226; from horizontal) impact from the northeast <ref type="bibr">(Collins et al., 2020)</ref>; this trajectory is now broadly adopted by the greater impact cratering community. Such modeling also suggests that there is a larger volume of sedimentary rock volatilization than at either lower or higher impact angles <ref type="bibr">(Artemieva et al., 2017;</ref><ref type="bibr">Collins et al., 2020)</ref>.</p><p>The pre-impact paleogeography of the Yucat&#225;n carbonate ramp deepened from tens of meters water depth in the south-southwest to approximately 2 km in the north-northeast <ref type="bibr">(Collins et al., 2008;</ref><ref type="bibr">Gulick et al., 2008)</ref>. This slope northward into the Gulf of Mexico likely influenced both impact dynamics <ref type="bibr">(Gulick et al., 2008;</ref><ref type="bibr">Orm&#246; et al., 2020)</ref> and the resulting resurge of water into the crater <ref type="bibr">(Gulick et al., 2019)</ref>. When the water is much deeper on one side of a crater, as with Chicxulub (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Gulick et al., 2008)</ref>, modeling shows that the deep water resurge will move across the crater faster and may stop or even reverse the resurge at the rim on the shallow water side <ref type="bibr">(Orm&#246; et al., 2010a)</ref>. The peak ring of the Chicxulub crater was open to the Gulf of Mexico through a gap in the crater rim to the north-northeast (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Gulick et al., 2008)</ref>. The asymmetries in the morphology and structure of the transient and final crater, peak ring relief, and the presence or absence of a crater rim <ref type="bibr">(Christeson et al., 1999;</ref><ref type="bibr">Christeson et al., 2001;</ref><ref type="bibr">Gulick et al., 2008;</ref><ref type="bibr">McDonald et al., 2008)</ref> likely had a significant effect on resurge and subsequent erosional and depositional processes <ref type="bibr">(Gulick et al., 2019)</ref>.</p><p>Post-impact depositional processes are highly dependent on the impact-generated water movements that in turn depend on the target water depth <ref type="bibr">(W&#252;nnemann et al., 2007)</ref>. During impacts in which the water depth is less than the diameter of the impactor, (impactor ~12 km <ref type="bibr">(Collins et al., 2020)</ref>, water depth &lt; 2 km <ref type="bibr">(Gulick et al., 2008)</ref>), part of the transient crater rim develops in the water column while part is within the crust. The upper part of the water column within the transient crater collapses outward forming a rim wave tsunami, while simultaneously the lower part collapses inward and water resurges back into the crater <ref type="bibr">(Orm&#246; et al., 2010a;</ref><ref type="bibr">W&#252;nnemann et al., 2007)</ref>. If the transient crater is largely symmetrical, resurge from all directions results in the formation of a central plume that collapses, causing radial flows that travel back toward the crater rim <ref type="bibr">(Orm&#246; et al., 2010a;</ref><ref type="bibr">W&#252;nnemann et al., 2007)</ref>. However, the asymmetry of the Chicxulub crater (i.e. presence or absence of a crater rim, variable peak ring relief, <ref type="bibr">(Gulick et al., 2008)</ref>) may have prevented the development of a central water plume.</p><p>The lack of a crater rim and deeper water to the north/northeast points toward that direction for initial resurge <ref type="bibr">(Gulick et al., 2008;</ref><ref type="bibr">Gulick et al., 2019)</ref>. Thus, post-impact movement of water in the semienclosed crater and the Gulf of Mexico was particularly susceptible to multiple reflected seiches, i.e. standing waves in a partially enclosed body of water, after the initial resurge and rim wave tsunami. The outward radiating rim wave tsunami would have reflected off the highlands of central M&#233;xico, and perhaps the Gulf coastline, forming a reflected tsunami within the first day after impact <ref type="bibr">(Gulick et al., 2019)</ref>. Waning rim wave energy combined with seismic energy would have created a long-lasting series of seiches moving back and forth across the basin as energy subsided. Deposits as far away as the Adriatic carbonate platform in Croatia appear to record tsunami deposits at the K-Pg boundary <ref type="bibr">(Korbar et al., 2015)</ref>. Seismic energy may have resulted in a phenomenal inland seiche wave that inundated the Western Interior Seaway, recently documented in a deposit in North Dakota that preserves fossil fish with impact spherules within their gills, an ejecta deposit, and an Ir anomaly <ref type="bibr">(DePalma et al., 2019)</ref>. Additionally, seismic energy, estimated between M10 <ref type="bibr">(Kring, 1993)</ref> and M11 <ref type="bibr">(Day &amp; Maslin, 2005)</ref>, from the impact induced continental margin collapse and high energy deposits like turbidites, slumps, and slides, around the Gulf resulting in additional tsunami and seiches <ref type="bibr">(Alegret et al., 2001;</ref><ref type="bibr">Bralower et al., 1998;</ref><ref type="bibr">Campbell et al., 2007;</ref><ref type="bibr">Ferrell et al., 2011;</ref><ref type="bibr">Grajales-Nishimura et al., 2000;</ref><ref type="bibr">Paull et al., 2014;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Sanford et al., 2016;</ref><ref type="bibr">Smit et al., 1992;</ref><ref type="bibr">Soria et al., 2001;</ref><ref type="bibr">Stinnesbeck et al., 1993;</ref><ref type="bibr">Yancey, 1996;</ref><ref type="bibr">Yancey &amp; Liu, 2013)</ref>. These impact-induced seismic and margin collapse events around the Gulf of Mexico region resulted in the single largest event deposit documented on Earth <ref type="bibr">(Denne et al., 2013;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Sanford et al., 2016;</ref><ref type="bibr">Scott et al., 2014)</ref> and likely influenced deposition within the crater as tsunami and seiche waves entered and moved across the impact basin. Local collapse events from the peak ring itself and the crater rim to the east, south, and west that exhibited 500-800 m of relief <ref type="bibr">(Gulick et al., 2008)</ref> could also have resulted in tsunami and seiches that influenced the impact basin. These events and their seismic energy likely waned within years of the impact, following Oromi's law <ref type="bibr">(Parsons, 2002)</ref>.</p><p>IODP/ICDP Expedition 364 recovered core atop the peak ring in the Chicxulub impact structure at Site M0077 <ref type="bibr">(Morgan et al., 2016;</ref><ref type="bibr">Riller et al., 2018)</ref>. The core penetrated Paleogene sedimentary rocks, suevite, melt rock, and granitic basement (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Morgan et al., 2016)</ref>. Deposition of the suevite (polymict, impact melt-bearing breccia, <ref type="bibr">(Claeys et al., 2003;</ref><ref type="bibr">Shoemaker &amp; Chao, 1961;</ref><ref type="bibr">St&#246;ffler &amp; Grieve, 2007)</ref> atop the 500 m-high peak ring largely took place during and subsequent to the resurge in a flooded crater <ref type="bibr">(Gulick et al., 2019)</ref>. The upper suevite, extending from ~617.3-664.5 m below sea floor (mbsf) in the core, records a remarkable succession of 25 fining upward packages that near the base grade upward from coarse pebble to medium sand-size suevite near the base and transition to medium or fine-sand grading into dominantly clay-sized material toward the top <ref type="bibr">(Gulick et al., 2019)</ref>. The transition between suevite and basal Paleocene limestones is a series of fining upward carbonate-rich couplets, that contains two intervals with soft sediment-deformation, and records the deposition of fine-grained material post-impact <ref type="bibr">(Gulick et al., 2019)</ref>. This, mostly laminated Transitional <ref type="bibr">Unit (616.58-617.33 mbsf, Unit 1G, (Gulick et al., 2017)</ref>) is the focus of our study.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.">Regional setting</head><p>IODP/ICDP Site M0077 (21.45 &#8226; N, 89.95 &#8226; W) is offshore of the Yucat&#225;n Peninsula and was chosen due to its position atop a high-relief portion of the Chicxulub peak ring (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Gulick et al., 2017;</ref><ref type="bibr">Morgan et al., 2016)</ref>. The site was selected primarily to test models of peak-ring formation <ref type="bibr">(Morgan et al., 2016)</ref>. Seismic images of the location suggested that the K-Pg boundary deposit was located within a depression atop the peak ring that was anticipated to contain a relatively complete succession of impact-related and lowermost Paleocene post-impact rocks, at relatively shallow burial depth <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Morgan et al., 2017)</ref>. Cores were collected from 505.7-1334.7 mbsf penetrating approximately 110 m of post-impact, hemipelagic and pelagic sedimentary rocks, ranging from middle Eocene (Ypresian) to basal Paleocene (Danian) in age overlying the Transitional Unit and suevite which by definition were deposited in the earliest Danian (Fig. <ref type="figure">1</ref>) <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Lowery et al., 2018;</ref><ref type="bibr">Molina et al., 2006;</ref><ref type="bibr">Morgan et al., 2017;</ref><ref type="bibr">Morgan et al., 2016)</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.1.">Stratigraphy</head><p>Prior to drilling at Site M0077 the stratigraphy of the Chicxulub impact basin was largely informed by a series of relatively deep (1500-3500 m), discontinuously cored, exploratory wells drilled by Petr&#243;leos Mexicanos ("Pemex") between the 1950s-70s (Fig. <ref type="figure">2</ref>) <ref type="bibr">(Hildebrand et al., 1991;</ref><ref type="bibr">Ward et al., 1995)</ref>. Pemex wells C1, S1, and Y6 penetrated the Paleogene carbonates and underlying suevite but being near the crater center also penetrated intact melt rock <ref type="bibr">(Hildebrand et al., 1991;</ref><ref type="bibr">Kring &amp; Boynton, 1991;</ref><ref type="bibr">Kring &amp; Boynton, 1992;</ref><ref type="bibr">Sharpton et al., 1996;</ref><ref type="bibr">Ward et al., 1995)</ref>. These wells provided the first impactite samples that were initially misinterpreted as volcanic rocks <ref type="bibr">(Lopez Ramos, 1975)</ref>. Lower to Upper Cretaceous rocks were penetrated by Pemex wells T1, Y1, and Y2 and contain a mixture of limestone, dolostone, and anhydrite interpreted to represent shallow-water carbonate platform environments (Fig. <ref type="figure">2</ref>) <ref type="bibr">(Ward et al., 1995)</ref>. Upper Cretaceous rocks in these wells are overlain by suevite that is in turn overlain by Paleogene carbonate rocks <ref type="bibr">(Ward et al., 1995)</ref>.</p><p>Another series of short cores (60-700 m), that mainly penetrated impact breccia and overlying Paleogene carbonate rocks, were drilled by Universidad Nacional Aut&#243;noma de M&#233;xico (UNAM) in the 1990s <ref type="bibr">(Rebolledo-Vieyra et al., 2000;</ref><ref type="bibr">Urrutia-Fucugauchi et al., 1996)</ref>. The most recent well in the structure prior to IODP/ICDP 364 was the ICDP core Yaxcopoil-1 (Yax-1) drilled in <ref type="bibr">2001</ref><ref type="bibr">-2002 (Figs. 1-3) (Figs. 1-3)</ref> <ref type="bibr">(Stinnesbeck et al., 2004;</ref><ref type="bibr">Urrutia-Fucugauchi et al., 2004;</ref><ref type="bibr">Whalen et al., 2013)</ref> These onshore wells and cores provide the basic late Mesozoic-early Cenozoic stratigraphic framework of the Yucat&#225;n Peninsula (Figs. <ref type="figure">1</ref> and<ref type="figure">2</ref>).</p><p>Along with wells and cores, seismic data provide constraints on the subsurface stratigraphy of the Chicxulub structure (Fig. <ref type="figure">1</ref>). A 1996 experiment collected 650 km of marine two-dimensional (2D) seismic reflection profiles <ref type="bibr">(Morgan &amp; Warner, 1999;</ref><ref type="bibr">Morgan et al., 1997)</ref>. These data in conjunction with an additional 1500 km of 2D seismic reflection profiles acquired in 2005 <ref type="bibr">(Gulick et al., 2008;</ref><ref type="bibr">Morgan et al., 2005)</ref> provide a wealth of information about the crater's structure and the Cenozoic sedimentary infill of the basin <ref type="bibr">(Bell et al., 2004;</ref><ref type="bibr">Gulick et al., 2013;</ref><ref type="bibr">Whalen et al., 2013)</ref>. The distinctive seismic signature and physical properties of the suevite and related impact deposits enables mapping of the K-Pg event deposits in the Gulf of Mexico <ref type="bibr">(Christeson et al., 2018;</ref><ref type="bibr">Morgan et al., 2011;</ref><ref type="bibr">Sanford et al., 2016)</ref>.</p><p>At Site M0077 Chicxulub impact-related deposits include ~130 m of melt rock and suevite deposited during or shortly after crater formation; water clearly played a role in the emplacement of the sorted upper suevite <ref type="bibr">(Gulick et al., 2019)</ref>. As these energetic processes waned the termination of these events appears to be recorded in a 75 cm thick micritic unit that documents the transition from impact-related to normal marine sedimentation atop the peak ring in the Chicxulub crater.</p><p>Here we present a detailed investigation of stratigraphy, sedimentology and stable organic carbon isotope analyses of the organic fraction of the Transitional Unit and contact intervals of super-and subjacent units at Site M0077 that we integrate with published biostratigraphy, ichnology and rare earth element data to provide insight into the waning deposits of one of the most consequential events in Earth history.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.">Materials and methods</head><p>We employed visual core description, along with grain size and petrographic analyses, to characterize the lithology and sedimentary structures in the Transitional Unit at Site M0077. Additionally, we analyzed the stable isotopic composition of bulk organic carbon to gain insight into carbon cycling and sources of organic matter in the Transitional Unit. The morphology of micrite, charcoal content, biomarkers  <ref type="formula">2017</ref>). <ref type="bibr">(Bralower et al., 2020a;</ref><ref type="bibr">Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Gulick et al., 2019;</ref><ref type="bibr">Schaefer et al., 2020)</ref>, sedimentology, biostratigraphy, and ichnology of the Transitional Unit <ref type="bibr">(Gulick et al., 2017;</ref><ref type="bibr">Lowery et al., 2018;</ref><ref type="bibr">Whalen et al., 2017)</ref> are also employed to document the depositional processes associated with the waning energy related to the Chicxulub impact.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.1.">Visual core description</head><p>Cores recovered by IODP/ICDP Expedition 364 at Site M0077 were  <ref type="formula">2018</ref>), and from <ref type="bibr">Arz et al. (2004)</ref> for Yax-1. The K/Pg boundary cocktail includes reworked Cretaceous fossils <ref type="bibr">(Bralower et al., 1998;</ref><ref type="bibr">Lowery et al., 2018)</ref>. The uppermost portion of the Transitional Unit in both cores records bioturbation in the form of discrete traces at site M0077 (see Fig. <ref type="figure">5</ref>) and a cross cutting burrow (black arrow) and burrow mottling in Yax-1.</p><p>examined and described by the science party <ref type="bibr">(Morgan et al., 2017)</ref> who documented colour, grain size, bedding thickness and character, physical sedimentary structures, fossils, alteration features, and facies stacking patterns. Ichnological analysis focuses on the ichnofabric index (1-5) <ref type="bibr">(Droser &amp; Bottjer, 1986)</ref> and the infilling material of the trace fossils <ref type="bibr">(Lowery et al., 2018)</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.2.">Grain size analysis</head><p>Eleven samples (Table <ref type="table">S1</ref>) from the Transitional Unit and one from the overlying green marlstone were disaggregated in a bath of hydrogen peroxide or deionized water and were agitated on a shaker table for approximately two weeks. Disaggregated material was decanted to leave behind larger rock fragments that did not break down. The decanted samples were then analyzed using a Beckman Coulter laser diffraction particle size analyzer. Modal, median, and mean grain sizes were obtained (Table <ref type="table">S1</ref>). We determined D90 values (the grain size fraction that is larger than 90% of all other components in the sample), that were anomalously high thus identifying the coarsest 10% of the total sample. Additional analyses of maximum grain size were determined petrographically as discussed below.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.3.">Thin section petrography</head><p>Sixty-three thin sections from the Transitional Unit, 2 from the overlying green marlstone, and 5 from the underlying suevite were examined microscopically under plane and cross polarized light. Transitional Unit samples were categorized using the carbonate classification of <ref type="bibr">Dunham, 1962</ref> as modified by <ref type="bibr">Embry and Klovan, 1972. Bedding, lamination, ichnofabric, and</ref> other sedimentary structures were identified. Grains, matrix material and diagenetic products were classified, their mineralogy evaluated, and visible maximum grain diameters for 37 thin sections were measured using the microscope's reticle (Table <ref type="table">S2</ref>).</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.4.">Stable C isotopes</head><p>Thirty-eight samples for stable carbon isotope analyses of bulk organic matter (&#948; 13 C org )(27 from the Transitional Unit, 4 from the overlying green marlstone, and 7 from underlying upper suevite (Table <ref type="table">S3</ref>) were prepared by acidifying 1-g subsamples of powdered material with an excess of 1 M HCl. The acid-insoluble residues were rinsed, freeze-dried and analyzed for their C contents using a Costech Elemental Analyzer (ECS 4010). C Isotope ratios were then measured using a Conflo III interface with a Delta+XP Mass Spectrometer and ratios were reported using delta (&#948;) notation relative to the Vienna PeeDee Belemnite (VPDB). The internal lab standard is peptone No. P-7750 (Sigma Chemical Company, Lot #76f-0300) with &#948; 13 C = -15.80. Typical instrumental precision is &lt;0.2&#8240;.</p><p>Organic C concentrations in the acid-insoluble residues were used to calculate the whole rock weight percent total organic carbon (TOC) by determining the mass lost during carbonate acidification, also yielding total CaCO 3 content (Table <ref type="table">S3</ref>). The analytical precision and accuracy associated with these analyses is respectively within 2% and 5% of the reported values.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.">Results</head></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.1.">Transitional unit: lithology and stratigraphy</head><p>The Transitional Unit (Unit 1G, <ref type="bibr">(Gulick et al., 2017)</ref>) extends from 616. , consists dominantly of clay to silt-sized micrite (Table <ref type="table">S1</ref>) <ref type="bibr">(Bralower et al., 2020b, in press)</ref>, is underlain by suevite (Unit 2A, <ref type="bibr">(Gulick et al., 2017)</ref>) and overlain by green marlstone (Fig. <ref type="figure">3</ref>)(Unit 1F, <ref type="bibr">(Gulick et al., 2017)</ref>. The Transitional Unit's lithology is mainly dark brown to dark grayish brown wackestone but the unit is complex with several different lithologies and post-depositional pyrite nodules that disrupt bedding (Figs. <ref type="figure">3</ref><ref type="figure">4</ref><ref type="figure">5</ref>). In general, the Transitional Unit fines upward with a maximum of pebble size grains (up to 4.7 mm) at its base and fine sand size grains (up to 0.20 mm) near its top (Figs. <ref type="figure">3</ref><ref type="figure">4</ref><ref type="figure">5</ref><ref type="figure">6</ref>, Table <ref type="table">S2</ref>). The unit rests above a cross-bedded package of dominantly sand-sized (up to 2 mm) suevite (Fig. <ref type="figure">3</ref>) <ref type="bibr">(Gulick et al., 2017;</ref><ref type="bibr">Gulick et al., 2019)</ref>.</p><p>The base of the unit is a sharp, stylolitized contact overlain by two ~1 cm-thick, normally graded beds (617.31-617.33 mbsf) of floatstone, packstone, and wackestone with significant non-carbonate components (Figs. <ref type="figure">3,</ref><ref type="figure">4</ref>). Coarser grains (&#8804; 4.7 mm) are mainly altered impact glass (clay, zeolite, chalcedony), carbonate intraclasts, composite and coated grains, crystalline calcite grains, foraminifera, and other bioclasts within a micrite matrix (Fig. <ref type="figure">4</ref>, Table <ref type="table">S2</ref>). Some grains were altered by the longlived hydrothermal system in the crater and the peak ring <ref type="bibr">(Kring et al., 2020)</ref>. Clasts in the basal normally graded beds are similar to those in the underlying suevite. The beds exhibit coarse-tail grading with altered glass and carbonate grains that are locally distributed above similar size grains within a graded bed due to their lower density (Fig. <ref type="figure">4A</ref>). These two graded beds (617.31-617.33 mbsf) display enrichment of Ni and Cr, based on micro X-ray fluorescence (Fig. <ref type="figure">5</ref>) <ref type="bibr">(Gulick et al., 2017)</ref> and elevated levels of Co, Ir, Ni, Re and Os detected using several analytical methods <ref type="bibr">(Goderis et al., 2019)</ref>. While this lowermost portion of the Transitional Unit contains altered impact melt rock the bulk of the unit is composed of micrite and is not a polymict conglomerate and thus is not classified as suevite <ref type="bibr">(Claeys et al., 2003;</ref><ref type="bibr">Shoemaker &amp; Chao, 1961;</ref><ref type="bibr">St&#246;ffler &amp; Grieve, 2007)</ref>.</p><p>Above the graded beds (617.01-617.31 mbsf) is a 30 cm thick package of dark gray to dark grayish brown wackestone to mudstone couplets that display submillimeter-to millimeter-scale planar laminations commonly within centimeter-scale beds (Figs. <ref type="figure">3</ref><ref type="figure">4</ref><ref type="figure">5</ref><ref type="figure">6</ref>). Locally laminae are sharp based with erosional scours and have very thin intervals of silt-to sand-sized grains at their base (Fig. <ref type="figure">4</ref>). Grains are similar to the underlying graded beds but altered impact melt grains become less common and maximum grain size generally decreases upwards (Fig. <ref type="figure">6</ref>). This package records at least 39, mm to cm-bedded couplets of dark brown and grayish brown wackestone to mudstone with an ichnofabric index of 1 (Fig. <ref type="figure">3</ref>).</p><p>Above this sequence of laminated beds, bedding is indistinct and is obscured by soft sediment deformation from about 616.81-617.01 mbsf (Figs. <ref type="figure">3</ref> and<ref type="figure">5</ref>). Laminae are not present and grains are chaotically arranged (Fig. <ref type="figure">5B</ref>). Due to soft sediment deformation the ichnofabric index is indeterminate. Truncation of underlying laminae characterizes the base of the deformed unit; the return of bedded facies, similar to those present below the deformation, mark its upper limit (Fig. <ref type="figure">3</ref>).</p><p>Above the deformed interval, in the upper part of the Transitional Unit (616.62-616.81 mbsf), the lowest deposits comprise three cm-scale beds (Figs. <ref type="figure">3</ref> and<ref type="figure">5</ref>). The remainder of this part of the unit is characterized by mm-thick laminae, many with basal erosional scours, low angle cross lamination, and an ichnofabric index of 1 (Fig. <ref type="figure">7</ref>). Cross laminated intervals commonly display bidirectional laminae and one  <ref type="table">S2</ref>). C. Modal grain size of the micritic matrix of the Transitional Unit determined with a Beckman Coulter laser diffraction particle size analyzer (Table <ref type="table">S1</ref>). (For interpretation of the references to colour in this figure legend, the reader is referred to the web version of this article.) lamina with a well-developed scour (616.77 mbsf), with approximately 2 mm of relief, is overlain by small-scale cross laminae (Fig. <ref type="figure">7C</ref>). Laminae that offlap and thin in one direction, and then reverse, occur at 616.62, 616.69, and 616.76 mbsf (Fig. <ref type="figure">7</ref>).</p><p>The uppermost part of the Transitional Unit (616.58-616.62 mbsf) is laminated at the mm-scale and the upper 2 cm is a lighter gray-brown colored wackestone and contains a thin interbed of greenish marlstone similar to the overlying unit (Figs. <ref type="figure">3</ref> and<ref type="figure">5</ref>). The strata are slightly deformed with the greenish marlstone and interbedded lighter graybrown wackestone displaying a distinct down warp and 8 mm of normal-fault displacement from 616.58-616.61 mbsf (Figs. <ref type="figure">3</ref> and<ref type="figure">5F</ref>). The first Chondrites and Planolites burrows, filled with material similar to the overlying lighter gray-brown micrite, are located at 616.64 mbsf in the darker portion of the uppermost Transitional Unit that has an ichnofabric index of 1 (Fig. <ref type="figure">5</ref>) <ref type="bibr">(Lowery et al., 2018;</ref><ref type="bibr">Whalen et al., 2017)</ref>. The lighter colored, uppermost 2 cm of the Transitional Unit is slightly more bioturbated with an ichnofabric index of 2. It contains small Chondrites and Planolites burrows infilled with material similar to the overlying greenish marlstone, the contact with which (616.58 mbsf) is relatively sharp (Figs. <ref type="figure">3</ref> and<ref type="figure">5</ref>) <ref type="bibr">(Lowery et al., 2018)</ref>. Charcoal is documented in the uppermost suevite, throughout the Transitional Unit and in the overlying green marlstone, but has spikes in charcoal grain counts in the uppermost suevite and lowermost Transitional Unit (617.24-617.40 mbsf) and the uppermost Transitional Unit (616.58-616.60 mbsf) <ref type="bibr">(Bralower et al., 2020a;</ref><ref type="bibr">Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Gulick et al., 2019)</ref>. Above, the overlying greenish marlstone also has an ichnofabric index of 2 and Chondrites and Planolites burrows (Fig. <ref type="figure">5</ref>) <ref type="bibr">(Lowery et al., 2018)</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.2.">Stable C isotopes&#948; 13 C org and total organic carbon</head><p>Total organic carbon (TOC) values are very low in the Transitional Unit and uppermost suevite, with all samples containing less than 0.15% TOC (Fig. <ref type="figure">8</ref>, Table <ref type="table">S3</ref>). &#948; 13 C org values vary between -27.7&#8240; and -23.4&#8240; (Fig. <ref type="figure">8</ref>, Table <ref type="table">S3</ref>).</p><p>In samples from the suevite and the lowermost part of the Transitional Unit &#948; 13 C org values display a monotonic 2.5&#8240; 13 C enrichment (-26.0 to -23.6&#8240;) from 617.26-617.65 mbsf. From that interval up to 616.61 mbsf &#948; 13 C org shows numerous 0.3&#8240; to 3.8&#8240; fluctuations with the most 13 C-enriched sample (-23.4&#8240;) at 616.79 mbsf and the most 13 C-depleted sample (-27.7&#8240;) at 616.73 mbsf. Immediately above that is a positive carbon isotope excursion of 3.8&#8240; up to 616.61 mbsf. Most of the fluctuations span 4-5 cm of stratigraphy in the core (Fig. <ref type="figure">8</ref>). Above 616.61 mbsf, to the top of the Transitional Unit and into the lowermost overlying green marlstone, &#948; 13 C org values record a monotonoic negative excursion from -23.9&#8240; to -26.5&#8240; (Fig. <ref type="figure">8</ref>).</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.">Discussion</head><p>The lithologies in the Transitional Unit represent a continuum of deposition that began with the underlying suevite <ref type="bibr">(Gulick et al., 2019)</ref>. Understanding the depositional processes of the suevite and the paleogeography of the nascent Chicxulub crater informs our interpretation of deposition of the Transitional Unit. Here we present analysis of the specific features of the Transitional Unit that support its interpretation as the termination of impact-related deposition. We also compare the record at Site M0077 with other proximal localities and the record of post-impact sedimentation in other craters. </p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.1.">Post-impact deposits and processes</head><p>Impact events result in probably the most voluminous deposits with the highest accumulation rates of any sedimentological process <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Sanford et al., 2016)</ref>. In marine impacts, depending on the relative target water depth, these range from ejecta curtain fallout, processes similar to ground hugging pyroclastic flows, melt-water interactions, marine, debris-, hyperconcentrated-, or suspension flows, avalanches, tsunami and seiches, to long-term post-impact settling of fine material from suspension <ref type="bibr">(Dypvik &amp; Jansa, 2003;</ref><ref type="bibr">Gulick et al., 2019;</ref><ref type="bibr">Orm&#246; et al., 2007;</ref><ref type="bibr">Orm&#246; et al., 2010a;</ref><ref type="bibr">Orm&#246; et al., 2010b;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Shuvalov et al., 2008)</ref>. Rocks of the lower suevite (706-721 mbsf) are interpreted to have formed from violent interactions between melt and resurging seawater overlain by deposits from the resurge cresting Site M0077 (698-706 mbsf) <ref type="bibr">(Gulick et al., 2019)</ref>. In the graded suevite at 698 mbsf, there is a significant change in parameters such as number of clasts per meter, clast size, sorting, roundness, and matrix content <ref type="bibr">(Gulick et al., 2019)</ref>. Above 698 mbsf, the deposits are interpreted to have formed from settling in the now flooded crater with rapidly decreasing transport energy <ref type="bibr">(Gulick et al., 2019)</ref>. Above approximately 665 mbsf, the ever-finer grained deposits begin to show repeated graded beds, cross-bedding and other sedimentary structures interpreted as indicating deposition by oscillatory flow, seiches, and local increase in transport energy due to crater-rim generated gravity flows causing seiches within the impact basin <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Orm&#246; et al., 2020)</ref>,. This thick package, interpreted as deposits from resurge and settling, is overlain by the cross bedded suevite beginning at 617.42 mbsf (Fig. <ref type="figure">3</ref>). The Transitional Unit overlies the cross bedded suevite beginning at 617.33 mbsf (Fig. <ref type="figure">3</ref>)</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.2.">Deposition of uppermost suevite and transitional unit</head><p>The Transitional Unit records a continued reduction in transport energy that began with the underlying suevite <ref type="bibr">(Gulick et al., 2019)</ref> interrupted by episodic increases in energy related to seismic and/or mass wasting events. The upper suevite (617.33-664.52 mbsf, Unit 2A, <ref type="bibr">(Gulick et al., 2017)</ref>) at Site M0077 contains about 25 packages that fine upward from gravel to sand sized (35-2 mm) and are interpreted as seiche deposits triggered by earthquakes and submarine slumps, perhaps locally, along the newly formed crater rim or peak ring <ref type="bibr">(Gulick et al., 2019)</ref>. The uppermost suevite (617.33-617.42 mbsf, Fig. <ref type="figure">3</ref>) is crossbedded and interpreted as a deposit from the reflected rim wave tsunami after returning from the Gulf of Mexico shoreline <ref type="bibr">(Gulick et al., 2019)</ref>. The cross bedded suevite contains terrestrial components including perylene, a polycyclic aromatic hydrocarbon (PAH) that is a pigment made by wood-degrading fungi <ref type="bibr">(Grice et al., 2009)</ref>, and charcoal, from impact induced fires in terrestrial environments adjacent to the Gulf of Mexico, that were likely transported by tsunami and seiches and deposited in the uppermost suevite and the lowermost Transitional Unit <ref type="bibr">(Bralower et al., 2020a;</ref><ref type="bibr">Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Gulick et al., 2019)</ref>.</p><p>However, there were also likely additional tsunami and seiche waves that influenced deposition of the Transitional Unit, caused by postimpact seismic and platform margin collapse events in the Gulf of Mexico and Caribbean Sea <ref type="bibr">(Alvarez et al., 1992;</ref><ref type="bibr">Bralower et al., 1998;</ref><ref type="bibr">Denne et al., 2013;</ref><ref type="bibr">Grajales-Nishimura et al., 2009;</ref><ref type="bibr">Kiyokawa et al., 2002;</ref><ref type="bibr">Maurrasse &amp; Sen, 1991;</ref><ref type="bibr">Montanari et al., 1994;</ref><ref type="bibr">Paull et al., 2014;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Sanford et al., 2016;</ref><ref type="bibr">Tada et al., 2003;</ref><ref type="bibr">Takayama et al., 2000)</ref>. Soft sediment deformation in the Transitional Unit, reported here, likely attests to continued seismic disturbances and local mass wasting on the topographically high peak ring although site M0077 may have been shielded from some disturbances due to its location in a depression atop the peak ring <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Morgan et al., 2017)</ref>. In addition, the crater rim to the east and west was steep <ref type="bibr">(Gulick et al., 2008)</ref> and to the south it remained steep for up to 10 Myrs resulting in coarse-grained redeposited carbonates <ref type="bibr">(Whalen et al., 2013)</ref> implying that mass wasting and subsequent tsunami and seiches were likely common.</p><p>Two relatively coarse-grained, graded beds indicate a change in depositional processes from the underlying cross-bedded suevite to the micrite dominated Transitional Unit that consists predominantly of a series of graded beds (Figs. <ref type="figure">3</ref> and<ref type="figure">4</ref>). Other components in the Transitional Unit include altered glass and grains from sedimentary target rocks (Figs. <ref type="figure">4</ref> and<ref type="figure">5</ref>). The outsized clasts at the base of the initial and subsequent graded beds indicate increased current strength but the range of composition of the clasts (foraminifera, carbonate grains, altered impact glass) complicates determination of current velocity. The general upward decrease in grainsize; however, implies a decrease in current velocity upward. The origin of much of the micrite is likely related to impact processes that vaporized a massive volume of carbonate rock releasing up to 585 Gt of CO 2 <ref type="bibr">(Artemieva et al., 2017)</ref>. Most of the micrite in the Transitional Unit is interpreted as derived via backreaction of CaO formed from vaporization of this carbonate <ref type="bibr">(Bralower et al., 2020a</ref>) as proposed at other K-Pg boundary sites <ref type="bibr">(Yancey &amp; Guillemette, 2008)</ref> although <ref type="bibr">Bralower et al. 2020b, (in press</ref>) identified some micrite in the Transitional Unit as microbially precipitated.</p><p>Most of the Transitional Unit, above and below the soft sediment deformed interval (616.81-617.01 mbsf), is comprised of laminated and graded beds with basal scours indicating deposition from repeated accelerating and waning currents (Figs. <ref type="figure">3</ref><ref type="figure">4</ref><ref type="figure">5</ref><ref type="figure">6</ref>) which we interpret as deposits from reverberating seiches within the crater. Although basal scours of graded beds represent episodes of increased current agitation, the change from thin graded beds with sand-sized grains in a micrite matrix below the deformed interval to dominantly thin graded beds of silt-to clay-sized carbonate indicates an overall waning of transport energy (Figs. <ref type="figure">3-5,</ref> and<ref type="figure">7</ref>).</p><p>Currents capable of moving sand to pebble sized grains at similar water depth to Site M0077 are varied and include density currents, deep water tidal currents, benthic storm currents, eddies, internal waves, solitons, and tsunami and seiche related traction currents, among others <ref type="bibr">(Rebesco et al., 2014)</ref>. Storm currents were considered as a possible transport mechanism but measurements from buoys in the Gulf of Mexico and western Atlantic Ocean demonstrate a maximum of ~250 m for storm wave base <ref type="bibr">(Peters &amp; Loss, 2012)</ref>. Storm currents would thus seem incapable of moving sediments at the depth of Chicxulub's peak ring (~600 m, <ref type="bibr">(Lowery et al., 2018)</ref>). Sand to pebble size grains are transported by the Gulf of Mexico loop current at similar depths along the slope of the modern Campeche Bank <ref type="bibr">(Zavala-Hidalgo et al., 2003)</ref>. However, the repetitive deposition of graded beds and the occurrence of sedimentary structures indicative of oscillatory flow in the upper Transitional Unit (Figs. <ref type="figure">6</ref> and<ref type="figure">7</ref>) indicate that these were deposited by seiche or tsunami waves. Given their exceptionally long wavelengths (10s-100s of km) tsunami and seiches act as shallow water waves even at abyssal depths <ref type="bibr">(Dawson &amp; Stewart, 2007)</ref>. Tsunami or seiche waves with periods &gt;3 min can impart oscillatory motion at several km depth (Fig. <ref type="figure">9</ref>) <ref type="bibr">(Dawson &amp; Stewart, 2007)</ref>. Based on the physical location within the crater and its proximity to the initial rim wave tsunami, resurge, and mass-wasting derived tsunami and seiches, the latter seems to be the most likely depositional mechanism responsible for most of the sedimentary features recorded in the Transitional Unit.</p><p>The period of seiches within the crater, as a semi-enclosed basin, is directly proportional to basin length and inversely proportional to the square root of water depth and can be estimated as being between two end-members: T = 2l &#773;&#773;&#773; &#773; gd &#8730; sec for enclosed basins and,</p><p>where T = period, l = basin length, g = acceleration of gravity, d = water depth <ref type="bibr">(Trujillo &amp; Thurman, 2017)</ref>. Given the dimensions of the crater (~180 km diameter, inner rim to inner rim, ~600 m deep peak ring) tsunami or seiche periods of between 78 and 157 min would be expected. Assuming a period in the middle of this range (~100 min) a tsunami wave train and associated seiches within the crater could potentially deposit 25 couplets in about 40 h.</p><p>The soft-sediment slump in the middle part of the Transitional Unit (616.81-617.01 mbsf) (Figs. <ref type="figure">3</ref> and<ref type="figure">5</ref>) could be the direct result of seismic shaking or platform-margin collapse and associated tsunamiinduced cyclic pressure waves that have the potential to cause spontaneous liquefaction (Fig. <ref type="figure">9</ref>) <ref type="bibr">(Dawson &amp; Stewart, 2007)</ref>. Whether related directly to seismicity or platform margin collapse these processes likely waned hyperbolically within years of the impact following Oromi's law <ref type="bibr">(Parsons, 2002)</ref>. Above the slump, graded bedding and several intervals that clearly indicate oscillatory flow (Figs. <ref type="figure">6</ref> and<ref type="figure">8</ref>) point toward seiches as continued mechanisms of transport and deposition. The smaller-scale soft sediment deformation in the uppermost Transitional Unit (616.58-616.61 mbsf, Fig. <ref type="figure">5F</ref>) is also significant as it had to occur prior to deposition of the overlying green marlstone. The completely horizontal surface at the top of the Transitional Unit indicates that any topography caused by the deformation was leveled prior to deposition of the green marlstone. This indicates that seismic disturbance and/or slope instability was sustained throughout deposition of most of the Transitional Unit. Processes causing deposition of graded couplets and soft sediment deformation appear to cease and normal marine sedimentation ensued near the top of the Transitional Unit (~616.62 mbsf).</p><p>Based on biostratigraphy, He-isotope and Ir analyses the Transitional Unit was likely deposited in months to years at most, with a significant reduction in sedimentation rates in the uppermost few cm <ref type="bibr">(Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Goderis et al., 2019;</ref><ref type="bibr">Lowery et al., 2018)</ref>. Microfossils in the Transitional Unit include a mix of reworked Maastrichtian foraminifera and nannofossils <ref type="bibr">(Lowery et al., 2018)</ref> commonly referred to as the K-Pg boundary cocktail (Fig. <ref type="figure">3</ref>) <ref type="bibr">(Bralower et al., 1998)</ref>. The first well-defined oval structures that are interpreted to be individual Planolites and Chondrites burrows occur in the upper part of the Transitional Unit <ref type="bibr">(Fig. 5,</ref> indicating that burrowing organisms were re-established in the crater before the end of deposition of the Transitional Unit <ref type="bibr">(Lowery et al., 2018;</ref><ref type="bibr">Whalen et al., 2017)</ref>. The settling time, based on Stokes' law, of the fine grained micrite that makes up most of the Transitional Unit suggests that it was deposited in &lt;6 years <ref type="bibr">(Lowery et al., 2018)</ref>; however, this is a maximum estimate because the sedimentary structures documented here indicate deposition from oscillatory currents. The green marlstone represents 30 kyr post-impact at most, based on biostratigraphy <ref type="bibr">(Lowery et al., 2018)</ref> but likely preserves components derived via airfall near its base <ref type="bibr">(Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Goderis et al., 2019)</ref>. Specifically, Cr enrichment from &#956;XRF analyses was reported near the top of the Transitional Unit (Fig. <ref type="figure">5</ref>) <ref type="bibr">(Gulick et al., 2017)</ref>. Recent trace element analyses identified a 5 cm interval (616.55-616.60 mbsf), spanning the contact of the Transitional Unit with the overlying green marlstone, with significant enrichment in highly siderophile elements, including Ir <ref type="bibr">(Goderis et al., 2019)</ref>. This enrichment likely indicates deposition of the finest fraction of ejecta which, numerical modeling suggests took approximately 1-5 years to settle from the atmosphere and through the water column <ref type="bibr">(Bardeen et al., 2017;</ref><ref type="bibr">Claeys et al., 2017;</ref><ref type="bibr">Sato et al., 2017;</ref><ref type="bibr">Toon et al., 2016)</ref>. The presence of charcoal at both the base and top of the Transitional Unit further supports the rapid timeline, wherein the lower charcoal was generated locally by the thermal plume from the impact, whereas the upper charcoal represents fine-grained particles in the stratosphere from globally distributed wildfires <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Kring &amp; Durda, 2002;</ref><ref type="bibr">Morgan et al., 2013;</ref><ref type="bibr">Wolbach et al., 1990;</ref><ref type="bibr">Bralower et. al., 2020a;</ref><ref type="bibr">Bralower et al., 2020b, in press</ref>) and/or soot from heated and ejected fossil organics within the target rocks <ref type="bibr">(Lyons et al., 2020)</ref>. If we assume deposition of the Transitional Unit took between 3 and 6 years, accumulation rates would be on the order of 25-12.5 cm/yr. These are still extremely high accumulation rates that outpace even those found in glacial settings <ref type="bibr">(Montelli et al., 2017)</ref>. However, this age information indicates drastic reduction in sedimentation rates postimpact, as rates were as high as 130 m/d while the bulk of the suevite was deposited <ref type="bibr">(Gulick et al., 2019)</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.3.">Stable carbon isotopes and total organic carbon</head><p>The stable isotopic variations of carbon in organic matter (&#948; 13 C org ) provides insight into the source(s) of organic matter (transported terrestrial material, microbial mats, and changes in microbial productivity) and biogeochemical carbon cycling within the crater in the immediate and near-term aftermath of the impact event. Total organic carbon contents are uniformly low throughout the Transitional Unit, with a maximum of 0.15 Wt% (Fig. <ref type="figure">8</ref>). The carbon isotopic data display a rather monotonic positive shift from the uppermost suevite into the lowermost Transitional Unit and in the very uppermost Transitional Unit into the overlying Paleocene facies (Fig. <ref type="figure">8</ref>). The 13 C org enrichment in the uppermost suevite and lowermost Transitional Unit (617.26-617.65 mbsf, Fig. <ref type="figure">8</ref>) coincides with the influx of terrestrially derived material including perylene, charcoal <ref type="bibr">(Bralower et al., 2020a;</ref><ref type="bibr">Bralower et al. (2020b), in press;</ref><ref type="bibr">Gulick et al., 2019)</ref> and potentially PAHs, which were also derived from organic matter released from the target rock <ref type="bibr">(Lyons et al., 2020)</ref>. The upper negative excursion in &#948; 13 C org mirrors that recorded at K-Pg boundary deposits worldwide (Fig. <ref type="figure">8</ref>) <ref type="bibr">(D'Hondt et al., 1998;</ref><ref type="bibr">Hs&#252; &amp; MacKenzie, 1985;</ref><ref type="bibr">Zachos &amp; Arthur, 1986)</ref>.</p><p>Between 617.2 and 616.7 mbsf, the &#948; 13 C org record displays considerable variation with multiple short-term fluctuations of ~3&#8240; (Fig. <ref type="figure">8</ref>). Given the relatively rapid deposition of the Transitional Unit <ref type="bibr">(Bralower et al. (2020b)</ref>, in press; <ref type="bibr">Lowery et al., 2018)</ref> the repeated positivenegative fluctuations in &#948; 13 C org are unlikely associated with extinction-related changes in C (e.g. <ref type="bibr">(Sep&#250;lveda et al., 2019)</ref>) but rather variable sediment or organic matter sources. Terrestrial organic matter averages about -22 to -25&#8240; &#948; 13 C org , whereas marine organics can be more negative, approximately -20 to -30&#8240; <ref type="bibr">(Saltzman &amp; Thomas, 2012)</ref>. Thus, the positive &#948; 13 C org fluctuations (up to -23.44&#8240;) could be linked to higher concentrations of terrestrial organic matter and the negative values (down to -27.72&#8240;) to relatively higher amounts of marine organics (Fig. <ref type="figure">8</ref>). We cannot rule out other potential sources of organic carbon, such as ancient terrigenous organic matter eroded from land or carbon released from sedimentary target rocks, which has been identified as a major contributor of PAHs within the Transitional Unit <ref type="bibr">(Lyons et al., 2020)</ref>. Rather we assume that contemporaneous terrigenous and marine organic matter were dominant source of TOC, as organic matter from the crater was largely burned, ejected, and redistributed globally <ref type="bibr">(Lyons et al., 2020)</ref>. Evidence of contemporanceous organic matter includes the presence of biomarkers including 2&#945;-methylhopanes and heterocyst glycolipids in the Transitional Unit that were interpreted as cyanobacterial material from microbial mats transported to the crater by tsunami as well as from blooms of nonheterocystous unicellular pelagic cyanobacteria living in the crater <ref type="bibr">(Schaefer et al., 2020)</ref>. We suggest that the isotopic shifts are thus likely from a mixing of sources including, but not limited to, terrigenous and marine biomass. The &#948; 13 C org record above the soft sediment deformed interval in the Transitional Unit trends more negatively (Fig. <ref type="figure">8</ref>), which we interpret as increasing marine input, although additional sources of organics cannot be ruled out.</p><p>Recent work by <ref type="bibr">Sep&#250;lveda et al. (2019)</ref> examined &#948; 13 C org , &#948; 13 C carb , &#948; 13 C phytane , and &#948; 15 N org from eight neritic to upper bathyal successions in Tunisia, Spain, France and Denmark. They documented spatial and temporal heterogeneity in various carbon isotope records and observe that organic and inorganic carbon are locally decoupled <ref type="bibr">(Sep&#250;lveda et al., 2019)</ref>. They attributed this heterogeneity to complex processes influencing both organic and inorganic carbon pools. They contend that carbon cycling and primary productivity recovered to pre-K-Pg boundary levels more quickly in these neritic and upper bathyal settings compared to open ocean locations <ref type="bibr">(Sep&#250;lveda et al., 2019)</ref> similar to interpretations from microfossils in the Chicxulub crater itself <ref type="bibr">(Lowery et al., 2018)</ref>. <ref type="bibr">Sep&#250;lveda et al. (2019)</ref> also call on productivity driven by non-calcifying phytoplankton analogous to the cyanobacterial productivity interpreted at Site M0077 <ref type="bibr">(Schaefer et al., 2020)</ref>. Our study provides further evidence for carbon transport and carbon cycle changes as demonstrated by <ref type="bibr">Sep&#250;lveda et al. (2019)</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.4.">K-Pg Event deposits and comparison with other gGulf of mMexico records</head><p>The K-Pg event deposit, documented at over 350 localities worldwide, varies in stratigraphy with distance from the Chicxulub structure <ref type="bibr">(Schulte et al., 2010;</ref><ref type="bibr">Smit, 1999)</ref>. Distal deposits (&gt;5000 km from Chicxulub) are very thin (mm-scale), fine-grained, and consist dominantly of platinum group element-enriched clay and spherules and contain shocked quartz and Ni-rich spinels <ref type="bibr">(Schulte et al., 2010;</ref><ref type="bibr">Smit, 1999)</ref>. Proximal deposits (&lt;1500 km from Chicxulub), on the other hand, are meters to kilometers thick and contain coarse-grained clastic sediments (including suevite), indicating a variety of high-energy depositional processes including resurge, tsunami, seiches, and mass wasting events <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Sanford et al., 2016)</ref>.</p><p>Deposits interpreted as tsunami-derived were a key component in the sedimentology of the K-Pg boundary event <ref type="bibr">(Bourgeois et al., 1988;</ref><ref type="bibr">Smit &amp; Romein, 1985)</ref> even before documentation of Chicxulub as the "smoking gun" <ref type="bibr">(Hildebrand et al., 1991)</ref>. Interpretation of coarsegrained siliciclastic deposits interbedded with shelf mudstones in the Brazos River area <ref type="bibr">(Bourgeois et al., 1988;</ref><ref type="bibr">Smit &amp; Romein, 1985)</ref> and other areas (summarized in <ref type="bibr">(Smit, 1999)</ref>) were some of the first clues leading to the identification of the Gulf of Mexico region as the potential location of the K-Pg impact <ref type="bibr">(Hildebrand et al., 1991)</ref>. Several K-Pg outcrop sections along the east coast of M&#233;xico, including La Ceiba, Mimbral, Lajilla, and El Pe&#241;on, contain coarse clastic units with local evidence of oscillatory flow that overlie spherule-rich deposits and are interbedded with marls <ref type="bibr">(Smit, 1999)</ref>. The La Popa basin in northeastern M&#233;xico records a multiphase deposit at the K-Pg boundary with a chaotic, up to 8 m thick, lower portion interpreted as the result of seismicity and shelf collapse, ejecta deposition and reworking by backflow from the initial tsunami. This deposit, with sandstone boulders and abundant shallow water clasts is interpreted as deposited from hyperconcentrated density flows <ref type="bibr">(Schulte et al., 2012)</ref>. Multiple tsunami backwash deposits characterized by graded beds follow this chaotic unit <ref type="bibr">(Schulte et al., 2012)</ref>. In Cuba, K-Pg deposits over 500 m-thick contain coarse-grained deposits interpreted as debris flows or turbidites and a finer grained, homogeneous, 40 m-thick unit interpreted as a tsunami deposit <ref type="bibr">(Kiyokawa et al., 2002;</ref><ref type="bibr">Tada et al., 2003;</ref><ref type="bibr">Takayama et al., 2000)</ref>.</p><p>Cores from Deep Sea Drilling Project Sites 536 and 540 in the southeast Gulf of Mexico contain 40 m-thick K-Pg boundary deposits with matrix supported pebbly mudstone overlain by five ~2 m-thick packages of fining upward carbonate sandstone to mudstone with altered impact glass, spherules, and shocked minerals, overlain by about 0.5 m of carbonate mudstone enriched in Ir near the top <ref type="bibr">(Alvarez et al., 1992;</ref><ref type="bibr">Bralower et al., 1998;</ref><ref type="bibr">Sanford et al., 2016)</ref>. <ref type="bibr">Alvarez et al. (1992)</ref> noted that the uppermost fining upward carbonate sandstone to mudstone unit contains bidirectional cross bedding indicating that it was deposited, at least in part, by a tsunami or seiche. <ref type="bibr">Sanford et al. (2016)</ref> interpreted the deposit as muddy debris flows overlain by turbidites with the upper 0.5 m recording the settling of fine material suspended by the impact and documented small-scale fining-upward cycles within this package that resemble deposits in the Transitional Unit at Site M0077.</p><p>ICDP Yaxcopoil-1 core (Yax-1, Figs. 1, 3), located above Chicxulub's annular trough (Fig. <ref type="figure">2</ref>), is one of the few other cores that preserves a post-impact succession resting directly atop suevite (Unit 0 of Goto et al. ( <ref type="formula">2004</ref>)), Unit 1a of <ref type="bibr">(Stinnesbeck et al. (2004)</ref>), that appears to be equivalent to the Transitional Unit at Site M0077. The sorted suevite in Yax-1 is ~29 m thick and contains abundant reworked Cretaceous foraminifers <ref type="bibr">(Arz et al., 2004)</ref> and nannofossils and generally fines upward <ref type="bibr">(Goto et al., 2004)</ref> as at Site M0077 <ref type="bibr">(Gulick et al., 2019;</ref><ref type="bibr">Orm&#246; et al., 2020)</ref>. <ref type="bibr">Goto et al. (2004)</ref> interpreted the sorted suevite as deposited by resurge. The upper portion of the suevite in Yax-1 (823-795 m) contains 10 normally or inversely graded packages dominated by melt rock fragments but with increasing carbonate lithics up section <ref type="bibr">(Goto et al., 2004)</ref>. These graded packages are similar to middle portion of the suevite at Site M0077 <ref type="bibr">(Gulick et al., 2017;</ref><ref type="bibr">Gulick et al., 2019)</ref>. The uppermost suevite (795-798 m) in Yax-1 contains clasts up to 8 mm in diameter <ref type="bibr">(Goto et al., 2004)</ref>, and is directly overlain by the Transitional Unit equivalent.</p><p>The Transitional Unit equivalent in Yax-1 is slightly thinner than at Site M0077 (~50 cm, 794.10-794.64 m, Fig. <ref type="figure">3</ref>), and comprises a series of normally graded beds near the base, with clasts of altered impact glass, overlain by cross laminated silty to fine sandy dolostone and laminated lime mud-wackestone <ref type="bibr">(Figs. 3 and 10) (Goto et al., 2004;</ref><ref type="bibr">Smit et al., 1992)</ref>. The cross laminated dolostone (3 units between 794.41 and 794.48 m) locally displays climbing ripple cross lamination <ref type="bibr">(Figs. 3 and 10), interpreted by Goto et al. (2004)</ref> as indicating very rapid deposition. This feature was incorrectly identified as "oblique bedding" deposited by weak bottom currents when the structure was described based on an upside-down core piece <ref type="bibr">(Stinnesbeck et al., 2004)</ref>. Our interpretation departs from that of <ref type="bibr">Stinnesbeck et al. (2004)</ref> and <ref type="bibr">Bahlburg et al., 2010</ref> who imply that the fine grain size of the Transitional Unit equivalent in Yax-1 indicates deposition from slowly moving currents. Climbing ripples in Yax-1 (Figs. <ref type="figure">3</ref> and<ref type="figure">10</ref>) argue against this interpretation as they require high rates of suspended load fallout <ref type="bibr">(Jobe et al., 2012)</ref>. Several intervals record changes in the dip of cross beds indicating oscillatory flow, exemplified by well-developed herringbone cross bedding at 794.56 m (Fig. <ref type="figure">10</ref>). The occurrence of graded beds, cross-bedding, and multiple levels indicating oscillatory flow in the Transitional Unit equivalent of Yax-1 (Fig. <ref type="figure">10</ref>) support our interpretation that the unit was deposited by tsunami and seiches and we tentatively correlate the base of the cross beds in Yax-1 with the cross bedded suevite at the top of Unit 2A at Site M0077 (Fig. <ref type="figure">3</ref>).</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.5.">Comparison with other marine impact craters</head><p>Comparison of the Transitional Unit at Site M0077 with the uppermost impact-related deposits within other impact structures points toward waning impact and seismic energy as the dominant control on deposition. There are on the order of 15 to 25 known or inferred marine target impact craters documented worldwide <ref type="bibr">(Dypvik &amp; Jansa, 2003;</ref><ref type="bibr">Orm&#246; &amp; Lindstr&#246;m, 2000;</ref><ref type="bibr">Shuvalov et al., 2008)</ref>. Many of these craters are buried and are known only from geophysical studies or boreholes <ref type="bibr">(Dypvik &amp; Jansa, 2003;</ref><ref type="bibr">Orm&#246; &amp; Lindstr&#246;m, 2000)</ref>. Of those with cored intervals, only the Chesapeake Bay Impact Structure (CBIS) <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2008;</ref><ref type="bibr">Poag, 1997;</ref><ref type="bibr">Poag, 2002)</ref>, and the Mj&#248;lnir <ref type="bibr">(Dypvik et al., 2004)</ref>, Kaluga <ref type="bibr">(Masaitis, 2002)</ref>, Lockne, and Tv&#228;ren craters <ref type="bibr">(Frisk &amp; Orm&#246;, 2007;</ref><ref type="bibr">Orm&#246; et al., 2007;</ref><ref type="bibr">Orm&#246; et al., 2010b)</ref> have resurge and other post impact deposits sufficiently well documented for direct comparison with the deposits at Site M0077.</p><p>The 15-km wide Kaluga crater, located about 150 km south of Moscow, Russia formed in a &gt; 300 m deep Middle Devonian epicontinental sea and is now buried below 800 m of younger strata <ref type="bibr">(Masaitis, 2002)</ref>. It has been extensively drilled as well as investigated with geophysical methods. <ref type="bibr">Masaitis (2002)</ref> describes a complete succession from fractured and brecciated basement, allogenic breccia and suevite, resurge deposits, and post-impact marine sediments. The resurge deposits are approximately 200 m thick and are micrite matrix-supported with up to 5 cm diameter sedimentary and crystalline clasts. The resurge breccia lacks any sign of repeated beds and seems to have been deposited in one single event <ref type="bibr">(Masaitis, 2002)</ref> similar to lower suevite at Chicxulub's peak ring <ref type="bibr">(Gulick et al., 2019)</ref>. Based on a composition dominated by sedimentary clasts it is assumed the material mainly originated from rip-up of the surrounding seafloor, which has also been suggested as the main contributor to the resurge deposits at Tv&#228;ren, Lockne, and the CBIS <ref type="bibr">(Orm&#246; et al., 2007;</ref><ref type="bibr">Orm&#246; et al., 2009)</ref>. The Kaluga resurge deposit grades upwards into a claystone, the thickness of which is not reported <ref type="bibr">(Masaitis, 2002)</ref>.</p><p>The Mj&#248;lnir impact structure formed in the paleo-Barents sea about 142 Ma and is about 20-40 km across <ref type="bibr">(Dypvik et al., 2004;</ref><ref type="bibr">Werner &amp; Torsvik, 2010)</ref>. The impact-related stratigraphy documented from a core taken along the slope of the crater's central uplift includes chaotically organized slabs of preimpact sediments, a diamict interpreted as a debris flow, brecciated graded mudstone interpreted to represent tsunami and resurge deposits, and additional debris flow and turbidites prior to resumption of normal marine sedimentation <ref type="bibr">(Dypvik et al., 2004)</ref>. The breccias are about 14 m thick with multiple fining upward beds <ref type="bibr">(Dypvik et al., 2004)</ref>. The uppermost meter of the breccia contains conglomerates, parallel and cross laminated sandstones, and matrix and grain supported pebbly mudstone that are interpreted as debris flow or turbidity current deposits <ref type="bibr">(Dypvik et al., 2004)</ref>. Fossiliferous postimpact sedimentary rocks directly overlie these impact-related rocks and no finer grained counterpart of the Transitional Unit in Chicxulub was documented <ref type="bibr">(Dypvik et al., 2004</ref>). The 7.5 km diameter Lockne (458 Ma) and the 2 km diameter Tv&#228;ren (460 Ma) impact craters formed within the Ordovician epicontinental Baltoscandian Sea <ref type="bibr">(Lindstr&#246;m and Sturkell, 1992;</ref><ref type="bibr">Orm&#246; et al., 2007;</ref><ref type="bibr">Orm&#246; et al., 2010b)</ref>. Impactites at Tv&#228;ren were documented from two drilling sites, whereas Lockne was drilled at 11 locations and most of the impactites are exposed in outcrop. In both craters, impact breccias overlie target rocks and are overlain by a generally fining upward package of polymict gravel to sand-sized breccia grading into siltstones and claystones, the totality interpreted as resurge deposits <ref type="bibr">(Lindstr&#246;m et al., 1994;</ref><ref type="bibr">Orm&#246; et al., 2007;</ref><ref type="bibr">Orm&#246; et al., 2010a;</ref><ref type="bibr">Orm&#246; et al., 2010b)</ref>. Resurge deposits are up to 125 m thick in Lockne and 70 m thick in Tv&#228;ren. The upper part of the resurge succession in both craters is described as a medium-grained to fine-grained arenite <ref type="bibr">(Orm&#246; et al., 2007)</ref>. At Lockne, this unit may contain up to 20% volume of melt rock fragments, which are interpreted as proximal ejecta that landed in the sea and were transported back into the crater <ref type="bibr">(Lindstr&#246;m et al., 2005)</ref>. In outcrop on the inner flanks of the crater rim, the lower coarse-grained parts of the resurge arenite commonly show graded beds whereas the upper fine-grained parts display current lineation, cross-bedding, and dewatering structures <ref type="bibr">(Dalwigk &amp; Orm&#246;, 2001)</ref>. Similar features are seen in the equivalent deposits in drill core from Tv&#228;ren <ref type="bibr">(Lindstr&#246;m et al., 1994)</ref>. These deposits appear similar to the upper suevite at Site M0077 in Chicxulub that is cross-bedded with dewatering structures <ref type="bibr">(Gulick et al., 2019)</ref>. Resurge sands in the cores from Lockne and Tv&#228;ren fine up into siltstone and silty claystone (up to 32 m thick at Lockne). The contact between the resurge and overlying normal marine facies appears gradual but a sharp boundary was identified chemostratigraphically <ref type="bibr">(Orm&#246; et al., 2010b)</ref>. The expanded thickness of finegrained facies at Lockne and Tv&#228;ren compared to other craters could be a result of the depth of unconsolidated sediment at the time of impact but otherwise the generally fining upward pattern is indicative of a transition from impact related to post-impact sedimentation as we observe at Site M0077.</p><p>The CBIS is an 85 km diameter, Late Eocene (ca. 36 Ma) impact structure that is well documented with seismic reflection data and over 15 cored boreholes <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2008;</ref><ref type="bibr">Poag, 1997;</ref><ref type="bibr">Powars &amp; Bruce, 1999)</ref>. Water depth at the impact site varied from 0 to 340 m <ref type="bibr">(Horton Jr. et al., 2005)</ref>. Above crystalline basement, the CBIS impact-related deposits are locally over 1000 m thick and include suevite and lithic breccia, granite slabs, sediment-clast dominated breccia, and a thin stratified member (~1-14 m thick) overlain by post-impact sediments <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2009;</ref><ref type="bibr">Poag, 1997)</ref>. The breccias and granite slabs are interpreted as slump deposits. The upper part of the breccia (Exmore Formation, ~425 m in the Eyreville core) contains a basal slump deposit and an upper unit (~87 m) that generally fines upward and is interpreted as a debris flow deposited during resurge <ref type="bibr">(Gohn et al., 2009)</ref>. The stratified member is broken into two subunits with the lower subunit interpreted as a package of turbidites and the upper subunit as finer-grained turbidites and normal marine suspension deposits <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2008;</ref><ref type="bibr">Gohn et al., 2009;</ref><ref type="bibr">Poag, 2002)</ref>.</p><p>The succession of impact-related facies in the CBIS shares some interesting features with the deposits recorded at Chicxulub at Site M0077 while also differing significantly. The target rocks of the CBIS, consisting of water-saturated, well indurated Cretaceous and less indurated Paleogene siliciclastic sedimentary rocks overlying Proterozoic and Paleozoic crystalline basement <ref type="bibr">(Gohn et al., 2009;</ref><ref type="bibr">Poag, 1997)</ref>, differ significantly from the largely carbonate sediments and sedimentary target rocks at Chicxulub. The breccias in the CBIS are highly variable due to a mix of crystalline, consolidated and unconsolidated material involved in the impact <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Gohn et al., 2009)</ref>. The lower stratified interval has sub-horizontal, thick-walled burrows that do not extend into the uppermost stratified interval <ref type="bibr">(Dypvik et al., 2018)</ref>. The upper stratified member varies between 27 cm and 1.76 m and consists of repetitive submillimeter laminae of very fine to fine sand, silt, and clay <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Edwards et al., 2009;</ref><ref type="bibr">Gohn et al., 2009;</ref><ref type="bibr">Poag, 2002)</ref>. Sand occurs locally as submillimeter to millimeter thick lenses and there are microspherules (&lt; 1 mm diameter) at the base of the laminated unit that are interpreted as fallout ejecta from the impact <ref type="bibr">(Poag, 2002)</ref>. The upper stratified interval in the CBIS contains no indigenous fauna but impact altered and stratigraphically mixed preimpact microfossils <ref type="bibr">(Poag, 2002;</ref><ref type="bibr">Poag &amp; Norris, 2005;</ref><ref type="bibr">Self-Trail, 2003)</ref>. This is similar to the largely reworked nature of Cretaceous foraminifers documented in the Transitional Unit at Site M0077 <ref type="bibr">(Lowery et al., 2018)</ref>. However, some of these taxa were survivors that became more common in the upper 20 cm of Transitional Unit, prompting Lowery et al. <ref type="bibr">(Lowery et al., 2018)</ref> to interpret them as a depauperate survivor fauna that was not reworked.</p><p>The upper stratified unit in the CBIS appears to share some characteristics with the Transitional Unit at Site M0077. The laminated sand, silt and clay is reminiscent of the laminae in the Transitional Unit, but at Chicxulub instead of the quartz, mica, and clay observed in the CBIS <ref type="bibr">(Poag, 2002;</ref><ref type="bibr">Poag &amp; Norris, 2005)</ref>, the laminae comprise altered impact glass, carbonate grains, and micrite. These compositional variations are directly related to the different target rocks at the two different structures but the textural similarity points toward similar depositional processes.</p><p>Whereas the stratified unit at the top of the CBIS breccia succession was interpreted as a "dead zone" <ref type="bibr">(Poag, 2002;</ref><ref type="bibr">Poag, 2017;</ref><ref type="bibr">Poag &amp; Norris, 2005)</ref>, sand filled vertical burrows penetrate into it from the overlying unit <ref type="bibr">(Dypvik et al., 2018)</ref>. Similarly, Chondrites burrows in the uppermost Transitional Unit at site M0077 are filled with material from the overlying green marlstone (Fig. <ref type="figure">5</ref>). There is additional evidence of life in the form of Planolites trace fossils in the upper 20 cm of the Transitional Unit at Site M0077 <ref type="bibr">(Lowery et al., 2018;</ref><ref type="bibr">Whalen et al., 2017)</ref>. These burrows are flattened and locally infilled with lighter colored overlying micrite that was deposited prior to the first Danian foraminifers indicating the syndepositional nature of the burrows <ref type="bibr">(Lowery et al., 2018)</ref>. <ref type="bibr">Poag (2002)</ref> interpreted the "dead zone" interval as having been deposited from &lt;1 kyr up to 10 kyr post-impact, whereas the Transitional Unit in Chicxulub was likely deposited over the course of several years thus recording a very rapid return of life to the crater <ref type="bibr">(Lowery et al., 2018)</ref>. A key difference between the two craters is the connection of Chicxulub to the open ocean <ref type="bibr">(Gulick et al., 2008)</ref> while the CBIS was at least partially isolated resulting in low oxygen conditions within the post-impact basin that likely delayed the return of life <ref type="bibr">(Dypvik et al., 2018;</ref><ref type="bibr">Poag, 2002)</ref>.</p><p>The above discussion illustrates that the transition from impactrelated to post-impact sediment deposition in marine-target craters have some general similarities such as an overall fining upward nature, a transition from sand-sized or coarser-grained impact breccia to laminated fine-grained deposits, and a mix of pre-impact biota, but these impact deposits also vary greatly. The reasons for these variations may be factors such as the relative amount of available water which would affect resurge processes, the morphology of the crater, the location of the core with respect to the crater (e.g. on the rim, in the annular trough, on the peak ring, or in the central crater), the paleogeography of the area (e. g. semi-enclosed basin, open sea), and the general depositional environment (e.g. low vs. high sedimentation rate, energy of the environment).</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="6.">Conclusions</head><p>The transition from impact-related to post-impact deposition is recorded in the uppermost cross bedded suevite and a series of graded beds, slumps, and oscillatory flow deposits in the micrite-dominated Transitional Unit at IODP-ICDP Site M0077. This succession shares similarities with other marine-target impact craters including the largely fining upward character of impact breccia with a transition to muddy deposits as the energy from impact-related and seismic events subsided.</p><p>The Transitional Unit at Site M0077 thus records the waning of energetic processes initiated by the Chicxulub impact event showing a continuum of deposition with the underlying upper suevite which largely fines upward with dominantly normal and some reverse graded beds. The lower Transitional Unit records at least 39 mm-to cm-scale graded beds with maximum grains of sand size (Figs. <ref type="figure">3</ref> and<ref type="figure">4</ref>). Maximum grain size and inferred velocity generally decrease upward in the Transitional Unit (Fig. <ref type="figure">6</ref>).</p><p>The cross bedded uppermost suevite (Fig. <ref type="figure">3</ref>) is interpreted as a tsunami deposit while the graded beds in the lower Transitional Unit likely record seiches following this and/or additional tsunami generated by seismic or platform margin collapse events. Influence of terrestrial input in the upper cross bedded suevite and lower Transitional Unit include perylene, charcoal, and &#948; 13 C org values interpreted to represent transported terrigenous organic matter.</p><p>Soft sediment deformation in the middle and uppermost portions of the Transitional Unit (Fig. <ref type="figure">3</ref>) likely indicates either continued seismicity and/or additional tsunami (Fig. <ref type="figure">9</ref>). Sedimentary structures indicative of scouring are documented throughout the Transitional Unit but the most prominent scour is above the slump interval (Fig. <ref type="figure">5</ref>) where several beds record evidence of oscillatory flow (Fig. <ref type="figure">6</ref>) likely generated by seiches.</p><p>The uppermost Transitional Unit contains Planolites and Chondrites burrows (Fig. <ref type="figure">5</ref>) and elevated numbers of survivor planktic foraminifera and estimates of the timing of deposition indicate a rapid return of life to the crater. Enrichments of highly siderophile elements in the uppermost Transitional Unit and basal overlying green marlstone are interpreted as distal ejecta that likely took several years to settle from the atmosphere and through the water column. This implies that the energy imparted by the impact event and additional water column disturbance related to seismic and platform margin collapse events likely continued for up to several years after the impact but subsided afterwards leading to the resumption of normal marine sedimentation recorded in the overlying Paleocene facies.</p><p>The upper suevite, Transitional Unit, and overlying green marlstone on the peak ring of the Chicxulub impact structure at Site M0077 appear to record a complete transition from resurge deposits into post-impact sediments. Several marine-target impact craters record similar successions but the Transitional Unit in Chicxulub appears most similar to the record in the Chesapeake Bay impact structure. This is likely because they are relatively large craters with target materials consisting of water saturated sedimentary rocks overlying crystalline basement. Other craters such as Lockne record a more gradual transition over tens of meters of deposits with tremendous variation depending on location within the crater <ref type="bibr">(Orm&#246; et al., 2009;</ref><ref type="bibr">Orm&#246; et al., 2010a)</ref>. Thus, we find that the Transitional Unit at Site M0077 records the waning energy related to post-impact seismic and mass-wasting events and the tsunami and seiches these induced eventually giving way to normal marine Paleogene sedimentation. Such a sequence may be indicative of marine impacts.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head>Declaration of Competing Interest</head><p>None.</p></div></body>
		</text>
</TEI>
