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1. Influence of polymer modification on intra-MOF self-diffusion in MOF-based mixed matrix membranes

   https://doi.org/10.1016/j.micromeso.2023.112648  

   Baniani, Amineh ; Rivera, Matthew P. ; Marreiros, João ; Lively, Ryan P. ; Vasenkov, Sergey ( September 2023 , Microporous and Mesoporous Materials)
2. Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues

   https://doi.org/10.1021/acscentsci.5b00247  

   Brozek, Carl K. ; Michaelis, Vladimir K. ; Ong, Ta-Chung ; Bellarosa, Luca ; López, Núria ; Griffin, Robert G. ; Dincă, Mircea ( August 2015 , ACS Central Science)
3. Transforming an Insulating Metal–Organic Framework (MOF) into Semiconducting MOF/Gold Nanoparticle (AuNP) and MOF/Polymer/AuNP Composites to Gain Electrical Conductivity

   https://doi.org/10.1021/acsanm.2c03643  

   Gordillo, Monica A. ; Benavides, Paola A. ; Ma, Kaikai ; Saha, Sourav ( October 2022 , ACS Applied Nano Materials)
4. Diffusion-Controlled Rotation of Triptycene in a Metal–Organic Framework (MOF) Sheds Light on the Viscosity of MOF-Confined Solvent

   https://doi.org/10.1021/acscentsci.6b00168  

   Jiang, Xing ; Duan, Hai-Bao ; Khan, Saeed I. ; Garcia-Garibay, Miguel A. ( September 2016 , ACS Central Science)
5. Nylon–MOF Composites through Postsynthetic Polymerization

   https://doi.org/10.1002/ange.201812655  

   Kalaj, Mark ; Denny, Jr., Michael S. ; Bentz, Kyle C. ; Palomba, Joseph M. ; Cohen, Seth M. ( January 2019 , Angewandte Chemie)

   Hybridization of metal–organic frameworks (MOFs) and polymers into composites yields materials that display the exceptional properties of MOFs with the robustness of polymers. However, the realization of MOF–polymer composites requires efficient dispersion and interactions of MOF particles with polymer matrices, which remains a significant challenge. Herein, we report a simple, scalable, bench‐top approach to covalently tethered nylon–MOF polymer composite materials through an interfacial polymerization technique. The copolymerization of a modified UiO‐66‐NH₂MOF with a growing polyamide fiber (PA‐66) during an interfacial polymerization gave hybrid materials with up to around 29 weight percent MOF. The covalent hybrid material demonstrated nearly an order of magnitude higher catalytic activity for the breakdown of a chemical warfare simulant (dimethyl‐4‐nitrophenyl phosphate, DMNP) compared to MOFs that are non‐covalently, physically entrapped in nylon, thus highlighting the importance of MOF–polymer hybridization.

    

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