Protein fold and slow relaxation times impose constraints on configurations sampled by the protein. Incomplete sampling leads to the violation of fluctuation-dissipation relations underlying the traditional theories of electron transfer. The effective reorganization energy of electron transfer is strongly reduced thus leading to lower barriers and faster rates (catalytic effect). Electrochemical kinetic measurements support low activation barriers for protein electron transfer. The distance dependence of the rate constant displays a crossover from a plateau at short distances to a long-distance exponential decay. The transition between these two regimes is controlled by the protein dynamics.
more »
« less
Reply to comment on Effective Confining Potential of Quantum States in Disordered Media
The amplitude of localized quantum states in random or disordered media may exhibit long range exponential decay. We present here a theory that unveils the existence of an effective potential which finely governs the confinement of these states. In this picture, the boundaries of the localization subregions for low energy eigenfunctions correspond to the barriers of this effective potential, and the long range exponential decay characteristic of Anderson localization is explained as the consequence of multiple tunneling in the dense network of barriers created by this effective potential. Finally, we show that the Weyl's formula based on this potential turns out to be a remarkable approximation of the density of states for a large variety of one-dimensional systems, periodic or random.
more »
« less
- Award ID(s):
- 1839077
- NSF-PAR ID:
- 10294717
- Date Published:
- Journal Name:
- Physical review letters
- Volume:
- 124
- Issue:
- 219702
- ISSN:
- 1092-0145
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
A gapped ground state of a quantum spin system has a natural length scale set by the gap. This length scale governs the decay of correlations. A common intuition is that this length scale also controls the spatial relaxation towards the ground state away from impurities or boundaries. The aim of this article is to take a step towards a proof of this intuition. We assume that the ground state is frustration-free and invertible, i.e. it has no long-range entanglement. Moreover, we assume the property that we are aiming to prove for one specific kind of boundary condition; namely open boundary conditions. This assumption is also known as the "local topological quantum order" (LTQO) condition. With these assumptions we can prove stretched exponential decay away from boundaries or impurities, for any of the ground states of the perturbed system. In contrast to most earlier results, we do not assume that the perturbations at the boundary or the impurity are small. In particular, the perturbed system itself can have long-range entanglement.more » « less
-
null (Ed.)Abstract We study an effective Hamiltonian for the standard $$\nu =1/3$$ ν = 1 / 3 fractional quantum Hall system in the thin cylinder regime. We give a complete description of its ground state space in terms of what we call Fragmented Matrix Product States, which are labeled by a certain family of tilings of the one-dimensional lattice. We then prove that the model has a spectral gap above the ground states for a range of coupling constants that includes physical values. As a consequence of the gap we establish the incompressibility of the fractional quantum Hall states. We also show that all the ground states labeled by a tiling have a finite correlation length, for which we give an upper bound. We demonstrate by example, however, that not all superpositions of tiling states have exponential decay of correlations.more » « less
-
more » « less
Abstract A pair-density-wave (PDW) is a superconducting state with an oscillating order parameter. A microscopic mechanism that can give rise to it has been long sought but has not yet been established by any controlled calculation. Here we report a density-matrix renormalization-group (DMRG) study of an effective
t -J -V model, which is equivalent to the Holstein-Hubbard model in a strong-coupling limit, on long two-, four-, and six-leg triangular cylinders. While a state with long-range PDW order is precluded in one dimension, we find strong quasi-long-range PDW order with a divergent PDW susceptibility as well as the spontaneous breaking of time-reversal and inversion symmetries. Despite the strong interactions, the underlying Fermi surfaces and electron pockets around theK and$${K}^{\prime}$$ c ≈ 1 are consistent with an unusual realization of a Luther-Emery liquid. -
We study the one-dimensional discrete Schr\"odinger operator with the skew-shift potential $2\lambda \cos\2π(j^2\omega+jy+x)$. This potential is long conjectured to behave like a random one, i.e., it is expected to produce Anderson localization for arbitrarily small coupling constants $\lambda>0$. In this paper, we introduce a novel perturbative approach for studying the zero-energy Lyapunov exponent $L(\lambda)$ at small $\lambda$. Our main results establish that, to second order in perturbation theory, a natural upper bound on $L(\lambda)$ is fully consistent with $L(\lambda)$ being positive and satisfying the usual Figotin-Pastur type asymptotics $L(\lambda)\sim C\lambda^2$ as $\lambda\to 0$. The analogous quantity behaves completely differently in the Almost-Mathieu model, whose zero-energy Lyapunov exponent vanishes for $\lambda<1$. The main technical work consists in establishing good lower bounds on the exponential sums (quadratic Weyl sums) that appear in our perturbation series.more » « less
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- The DOI is not currently available.
