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Title: Tunable Redox Activity at Fe 3+ Centers in Colloidal ATiO 3 (A = Sr and Ba) Nanocrystals
Award ID(s):
1747593 1726578 1659266
PAR ID:
10299412
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Chemistry of Materials
Volume:
33
Issue:
11
ISSN:
0897-4756
Page Range / eLocation ID:
4196 to 4203
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    The crystal structure of the product of the neutralization reaction between 3-nitrobenzoic acid and pyridine is reported. The entities that crystallized are a pyridinium cation, a 3-nitrobenzoate anion and a 3-nitrobenzoic acid molecule in a 1:1:1 molar ratio, C 5 H 6 N + ·C 7 H 4 NO 4 − ·C 7 H 5 NO 4 . Distinct sets of hydrogen bonds link the pyridinium and benzoate ions (N—H...O) and the acid and benzoate moieties (O—H...O). The hydrogen bonding along with π–π stacking between the acid and benzoate moieties accounts for the long-range ordering of the crystal. 
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