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Title: pyUserCalc: A Revised Jupyter Notebook Calculator for Uranium-Series Disequilibria in Basalts
Meaningful analysis of uranium-series isotopic disequilibria in basaltic lavas relies on the use of complex forward numerical models like dynamic melting (McKenzie, 1985, https://doi.org/10.1016/0012- 821x(85)90001-9) and equilibrium porous flow (Spiegelman & Elliott, 1993, https://doi.org/10.1016/0012- 821x(93)90155-3). Historically, such models have either been solved analytically for simplified scenarios, such as constant melting rate or constant solid/melt trace element partitioning throughout the melting process, or have relied on incremental or numerical calculators with limited power to solve problems and/or restricted availability. The most public numerical solution to reactive porous flow, UserCalc (Spiegelman, 2000, https:// doi.org/10.1029/1999gc000030) was maintained on a private institutional server for nearly two decades, but that approach has been unsustainable in light of modern security concerns. Here, we present a more long-lasting solution to the problems of availability, model sophistication and flexibility, and long-term access in the form of a cloud-hosted, publicly available Jupyter notebook. Similar to UserCalc, the new notebook calculates U-series disequilibria during time-dependent, equilibrium partial melting in a one-dimensional porous flow regime where mass is conserved. In addition, we also provide a new disequilibrium transport model which has the same melt transport model as UserCalc, but approximates rate-limited diffusive exchange of nuclides between solid and melt using linear kinetics. The degree of disequilibrium during transport is controlled by a Damköhler number, allowing the full spectrum of equilibration models from complete fractional melting (Da = 0) to equilibrium transport (Da = ∞).  more » « less
Award ID(s):
1658011
PAR ID:
10317610
Author(s) / Creator(s):
;
Date Published:
Journal Name:
Earth and space science
Volume:
8
ISSN:
2333-5084
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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