The syntheses and crystal structures of two bimetallic molecular compounds, namely, bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridozirconate(IV) 1.134-hydrate, [Cu(dmbpy) 2 ] 2 [ZrF 6 ]·1.134H 2 O (dmbpy = 6,6′-dimethyl-2,2′-bipyridyl, C 12 H 12 N 2 ), (I), and bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridohafnate(IV) 0.671-hydrate, [Cu(dmbpy) 2 ] 2 [HfF 6 ]·0.671H 2 O, (II), are reported. Apart from a slight site occupany difference for the water molecule of crystallization, compounds (I) and (II) are isostructural, featuring isolated tetrahedral cations of copper(I) ions coordinated by two dmbpy ligands and centrosymmetric, octahedral anions of fluorinated early transition metals. The tetrahedral environments of the copper complexes are distorted owingmore »
Superhalogens Among 3 d -Metal Compounds: M F 4 , M F 6 , M F 12 , and M F 18 ( M = Sc–Zn)
- Award ID(s):
- 1946231
- Publication Date:
- NSF-PAR ID:
- 10319526
- Journal Name:
- The Journal of Physical Chemistry A
- Volume:
- 125
- Issue:
- 20
- ISSN:
- 1089-5639
- Sponsoring Org:
- National Science Foundation
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