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1. Determination of F_v / F_m from Chlorophyll a Fluorescence without Dark Adaptation by an LSSVM Model

   https://doi.org/10.34133/plantphenomics.0034  

   Xia, Qian; Tang, Hao; Fu, Lijiang; Tan, Jinglu; Govindjee, Govindjee; Guo, Ya (January 2023, Plant Phenomics)

   Evaluation of photosynthetic quantum yield is important for analyzing the phenotype of plants. Chlorophyll a fluorescence (ChlF) has been widely used to estimate plant photosynthesis and its regulatory mechanisms. The ratio of variable to maximum fluorescence, F v / F m , obtained from a ChlF induction curve, is commonly used to reflect the maximum photochemical quantum yield of photosystem II (PSII), but it is measured after a sample is dark-adapted for a long time, which limits its practical use. In this research, a least-squares support vector machine (LSSVM) model was developed to explore whether F v / F m can be determined from ChlF induction curves measured without dark adaptation. A total of 7,231 samples of 8 different experiments, under diverse conditions, were used to train the LSSVM model. Model evaluation with different samples showed excellent performance in determining F v / F m from ChlF signals without dark adaptation. Computation time for each test sample was less than 4 ms. Further, the prediction performance of test dataset was found to be very desirable: a high correlation coefficient (0.762 to 0.974); a low root mean squared error (0.005 to 0.021); and a residual prediction deviation of 1.254 to 4.933. These results clearly demonstrate that F v / F m , the widely used ChlF induction feature, can be determined from measurements without dark adaptation of samples. This will not only save experiment time but also make F v / F m useful in real-time and field applications. This work provides a high-throughput method to determine the important photosynthetic feature through ChlF for phenotyping plants. 

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2. Ultracompact 4H-silicon carbide optomechanical resonator with f _m  ·  Q _m exceeding 10 ¹³   Hz

   https://doi.org/10.1364/PRJ.567674  

   Liu, Yuncong; Sun, Wenhan; Abiri, Hamed; Feng, Philip_X-L; Li, Qing (August 2025, Photonics Research)

   Silicon carbide (SiC) has great potential for optomechanical applications due to its outstanding optical and mechanical properties. However, challenges associated with SiC nanofabrication have constrained its adoption in optomechanical devices, as embodied by the considerable optical loss or lack of integrated optical access in existing mechanical resonators. In this work, we overcome such challenges and demonstrate a low-loss, ultracompact optomechanical resonator in an integrated 4H-SiC-on-insulator (4H-SiCOI) photonic platform for the first time, to our knowledge. Based on a suspended 4.3-μm-radius microdisk, the SiC optomechanical resonator features low optical loss (<1  dB/cm), a high mechanical frequencyf_mof 0.95×10⁹  Hz, a mechanical quality factorQ_mof 1.92×10⁴, and a footprint of <1×10⁻⁵  mm². The correspondingf_m·Q_mproduct is estimated to be 1.82×10¹³  Hz, which is among the highest reported values of optomechanical cavities tested in ambient environment at room temperature. In addition, the strong optomechanical coupling in the SiC microdisk enables coherent regenerative optomechanical oscillations at a threshold optical dropped power of 14 μW, which also supports efficient harmonic generation at increased power levels. With such competitive performance, we envision a range of chip-scale optomechanical applications to be enabled by the low-loss 4H-SiCOI platform. 

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3. Crystal structures of two copper(I)–6,6′-dimethyl-2,2′-bipyridyl (dmbpy) compounds, [Cu(dmbpy) ₂ ] ₂ [ M F ₆ ]· x H ₂ O ( M = Zr, Hf; x = 1.134, 0.671)

   https://doi.org/10.1107/S2056989021007295  

   Wang, Yiran; Nisbet, Matthew L.; Poeppelmeier, Kenneth R. (August 2021, Acta Crystallographica Section E Crystallographic Communications)

   The syntheses and crystal structures of two bimetallic molecular compounds, namely, bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridozirconate(IV) 1.134-hydrate, [Cu(dmbpy) 2 ] 2 [ZrF 6 ]·1.134H 2 O (dmbpy = 6,6′-dimethyl-2,2′-bipyridyl, C 12 H 12 N 2 ), (I), and bis[bis(6,6′-dimethyl-2,2′-bipyridine)copper(I)] hexafluoridohafnate(IV) 0.671-hydrate, [Cu(dmbpy) 2 ] 2 [HfF 6 ]·0.671H 2 O, (II), are reported. Apart from a slight site occupany difference for the water molecule of crystallization, compounds (I) and (II) are isostructural, featuring isolated tetrahedral cations of copper(I) ions coordinated by two dmbpy ligands and centrosymmetric, octahedral anions of fluorinated early transition metals. The tetrahedral environments of the copper complexes are distorted owing to the steric effects of the dmbpy ligands. The extended structures are built up through Coulombic interactions between cations and anions and π–π stacking interactions between heterochiral Δ- and Λ-[Cu(dmbpy) 2 ] + complexes. A comparison between the title compounds and other [Cu(dmbpy) 2 ] + compounds with monovalent and bivalent anions reveals a significant influence of the cation-to-anion ratio on the resulting crystal packing architectures, providing insights for future crystal design of distorted tetrahedral copper compounds. 

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4. VOA[ M ₄ ]

   https://doi.org/10.1063/1.5100059  

   Feigin, Boris; Gukov, Sergei (January 2020, Journal of Mathematical Physics)
5. Synthesis, Characterization, and Electrochemistry of the Homoleptic f Element Ketimide Complexes [Li] ₂ [M(N═C ^t BuPh) ₆ ] (M = Ce, Th)

   https://doi.org/10.1021/acs.inorgchem.9b01428  

   Assefa, Mikiyas K.; Sergentu, Dumitru-Claudiu; Seaman, Lani A.; Wu, Guang; Autschbach, Jochen; Hayton, Trevor W. (September 2019, Inorganic Chemistry)