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Title: Evidence for surface effects on the intermolecular interactions in Fe( ii ) spin crossover coordination polymers
From X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS), it is evident that the spin state transition behavior of Fe( ii ) spin crossover coordination polymer crystallites at the surface differs from the bulk. A comparison of four different coordination polymers reveals that the observed surface properties may differ from bulk for a variety of reasons. There are Fe( ii ) spin crossover coordination polymers with either almost complete switching of the spin state at the surface or no switching at all. Oxidation, differences in surface packing, and changes in coordination could all contribute to making the surface very different from the bulk. Some Fe( ii ) spin crossover coordination polymers may be sufficiently photoactive so that X-ray spectroscopies cannot discern the spin state transition.  more » « less
Award ID(s):
2003057 1827690
NSF-PAR ID:
10328048
Author(s) / Creator(s):
; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Physical Chemistry Chemical Physics
Volume:
24
Issue:
2
ISSN:
1463-9076
Page Range / eLocation ID:
883 to 894
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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