Abstract Heat capacities and enthalpies of formation of BaGd2O4were determined by high‐temperature differential scanning calorimetry and high‐temperature oxide melt solution calorimetry, respectively. Thermodynamic stability of BaLn2O4compounds increases with decreasing Ln3+ionic radius. Previously reported data on BaNd2O4and BaSm2O4corroborate this trend. Missing data for compounds in BaO–Ln2O3(Ln = La, Pr, Eu, Er) systems were estimated from established relations, thermodynamic assessment was performed, and binary phase diagrams were calculated.
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Hydrothermal Synthesis of New Iodates Ln 2 (IO 3 ) 3 (IO 4 ) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb
- Award ID(s):
- 1806279
- PAR ID:
- 10329311
- Date Published:
- Journal Name:
- Crystal Growth & Design
- Volume:
- 21
- Issue:
- 8
- ISSN:
- 1528-7483
- Page Range / eLocation ID:
- 4707 to 4712
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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