skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Plasmonic sensors based on graphene and graphene hybrid materials
Abstract The past decade has witnessed a rapid growth of graphene plasmonics and their applications in different fields. Compared with conventional plasmonic materials, graphene enables highly confined plasmons with much longer lifetimes. Moreover, graphene plasmons work in an extended wavelength range, i.e., mid-infrared and terahertz regime, overlapping with the fingerprints of most organic and biomolecules, and have broadened their applications towards plasmonic biological and chemical sensors. In this review, we discuss intrinsic plasmonic properties of graphene and strategies both for tuning graphene plasmons as well as achieving higher performance by integrating graphene with plasmonic nanostructures. Next, we survey applications of graphene and graphene-hybrid materials in biosensors, chemical sensors, optical sensors, and sensors in other fields. Lastly, we conclude this review by providing a brief outlook and challenges of the field. Through this review, we aim to provide an overall picture of graphene plasmonic sensing and to suggest future trends of development of graphene plasmonics.  more » « less
Award ID(s):
1904216 2035584 2201054 2135734 1720633
PAR ID:
10338075
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Nano Convergence
Volume:
9
Issue:
1
ISSN:
2196-5404
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Graphene can support surface plasmons with higher confinement, lower propagation loss, and substantially more tunable response compared to usual metal-based plasmonic structures. Interestingly, plasmons in graphene can strongly couple with nanostructures and gratings placed in its vicinity to form new hybrid systems that can provide a platform to investigate more complicated plasmonic phenomena. In this Perspective, an analysis on the excitation of highly confined graphene plasmons and their strong coupling with metallic or dielectric gratings is performed. We emphasize the flexibility in the efficient control of light–matter interaction by these new hybrid systems, benefiting from the interplay between graphene plasmons and other external resonant modes. The hybrid graphene-plasmon grating systems offer unique tunable plasmonic resonances with enhanced field distributions. They exhibit a novel route to realize practical emerging applications, including nonreciprocal devices, plasmonic switches, perfect absorbers, nonlinear structures, photodetectors, and optical sensors. 
    more » « less
  2. Performance of photonic devices critically depends upon their efficiency on controlling the flow of light therein. In the recent past, the implementation of plasmonics, two-dimensional (2D) materials and metamaterials for enhanced light-matter interaction (through concepts such as sub-wavelength light confinement and dynamic wavefront shape manipulation) led to diverse applications belonging to spectroscopy, imaging and optical sensing etc. While 2D materials such as graphene, MoS2 etc., are still being explored in optical sensing in last few years, the application of plasmonics and metamaterials is limited owing to the involvement of noble metals having a constant electron density. The capability of competently controlling the electron density of noble metals is very limited. Further, due to absorption characteristics of metals, the plasmonic and metamaterial devices suffer from large optical loss. Hence, the photonic devices (sensors, in particular) require that an efficient dynamic control of light at nanoscale through field (electric or optical) variation using substitute low-loss materials. One such option may be plasmonic metasurfaces. Metasurfaces are arrays of optical antenna-like anisotropic structures (sub-wavelength size), which are designated to control the amplitude and phase of reflected, scattered and transmitted components of incident light radiation. The present review put forth recent development on metamaterial and metastructure-based various sensors. 
    more » « less
  3. Abstract Covalent functionalization of pristine graphene can modify its properties, enabling applications in optoelectronics, biomedical fields, environmental science, and energy. However, the chemical reactivity of pristine graphene is relatively low, and as such, methods have been developed to increase the reactivity of graphene. This review focuses on substrate engineering as an effective strategy to enhance the reactivity of graphene through strain and charge doping. Nanoparticles, metals with different crystal orientations, and stretchable polymers are employed to introduce strains in graphene, leading to enhanced chemical reactivity and increased degree of functionalization. Charge doping through orbital hybridization with metals and charge puddles induced by oxide substrates generally enhance the reactivity of graphene, while alkyl‐modified surfaces and 2D materials often reduce graphene reactivity via charge screening and van der Waals interactions that increase the stability of the graphene layer, respectively. This review summarizes methods for creating and characterizing strains and charge doping in graphene and discusses their effects on the chemical functionalization of graphene in various reactions. 
    more » « less
  4. Graphene is a promising materials platform for metasurface flat optics at terahertz wavelengths, with the important advantage of active tunability. Here we review recent work aimed at the development of tunable graphene metasurfaces for THz wavefront shaping (including beam-steering metamirrors and metalenses) and light emission. Various design strategies for the constituent meta-units are presented, ranging from metallic phase-shifting elements combined with a nearby graphene sheet for active tuning to graphene plasmonic resonators providing the required phase control or radiation mechanism. The key challenge in the development of these devices, related to the limited radiative coupling of graphene plasmonic excitations, is discussed in detail together with recently proposed solutions. The resulting metasurface technology can be expected to have a far-reaching impact on a wide range of device applications for THz imaging, sensing, and future wireless communications. 
    more » « less
  5. null (Ed.)
    Abstract Surface plasmons, collective electromagnetic excitations coupled to conduction electron oscillations, enable the manipulation of light–matter interactions at the nanoscale. Plasmon dispersion of metallic structures depends sensitively on their dimensionality and has been intensively studied for fundamental physics as well as applied technologies. Here, we report possible evidence for gate-tunable hybrid plasmons from the dimensionally mixed coupling between one-dimensional (1D) carbon nanotubes and two-dimensional (2D) graphene. In contrast to the carrier density-independent 1D Luttinger liquid plasmons in bare metallic carbon nanotubes, plasmon wavelengths in the 1D-2D heterostructure are modulated by 75% via electrostatic gating while retaining the high figures of merit of 1D plasmons. We propose a theoretical model to describe the electromagnetic interaction between plasmons in nanotubes and graphene, suggesting plasmon hybridization as a possible origin for the observed large plasmon modulation. The mixed-dimensional plasmonic heterostructures may enable diverse designs of tunable plasmonic nanodevices. 
    more » « less