In weathered bedrock aquifers, groundwater is stored in pores and fractures that open as rocks are exhumed and minerals interact with meteoric fluids. Little is known about this storage because geochemical and geophysical observations are limited to pits, boreholes, or outcrops or to inferences based on indirect measurements between these sites. We trained a rock physics model to borehole observations in a well-constrained ridge and valley landscape and then interpreted spatial variations in seismic refraction velocities. We discovered that P-wave velocities track where a porosity-generating reaction initiates in shale in three boreholes across the landscape. Specifically, velocities of 2.7 ± 0.2 km/s correspond with growth of porosity from dissolution of chlorite, the most reactive of the abundant minerals in the shale. In addition, sonic velocities are consistent with the presence of gas bubbles beneath the water table under valley and ridge. We attribute this gas largely to CO2produced by 1) microbial respiration in soils as meteoric waters recharge into the subsurface and 2) the coupled carbonate dissolution and pyrite oxidation at depth in the rock. Bubbles may nucleate below the water table because waters depressurize as they flow from ridge to valley and because pores have dilated as the deepmore »
- Award ID(s):
- 2012353
- Publication Date:
- NSF-PAR ID:
- 10342456
- Journal Name:
- Frontiers in Water
- Volume:
- 3
- ISSN:
- 2624-9375
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
Abstract As bedrock weathers to regolith – defined here as weathered rock, saprolite, and soil – porosity grows, guides fluid flow, and liberates nutrients from minerals. Though vital to terrestrial life, the processes that transform bedrock into soil are poorly understood, especially in deep regolith, where direct observations are difficult. A 65-m-deep borehole in the Calhoun Critical Zone Observatory, South Carolina, provides unusual access to a complete weathering profile in an Appalachian granitoid. Co-located geophysical and geochemical datasets in the borehole show a remarkably consistent picture of linked chemical and physical weathering processes, acting over a 38-m-thick regolith divided into three layers: soil; porous, highly weathered saprolite; and weathered, fractured bedrock. The data document that major minerals (plagioclase and biotite) commence to weather at 38 m depth, 20 m below the base of saprolite, in deep, weathered rock where physical, chemical and optical properties abruptly change. The transition from saprolite to weathered bedrock is more gradational, over a depth range of 11–18 m. Chemical weathering increases steadily upward in the weathered bedrock, with intervals of more intense weathering along fractures, documenting the combined influence of time, reactive fluid transport, and the opening of fractures as rock is exhumed and transformed near Earth’s surface.
-
Unaweep Canyon (Western Colorado, US) is an enigmatic alpine landform and hypothesized to represent a partially exhumed paleo valley which was glacially over-deepened in the late Paleozoic. Processing and interpretation of recently acquired 2D seismic reflection and refraction data support the concept of glacial over-deepening and indicate maximum bedrock depths of about 550 meters. Additionally, pronounced reflectors are observed within the sedimentary infill. The seismic data have also been subjected to surface wave analysis revealing a significant increase of the Vp/Vs ratio below a shallow (50 - 150 m depth) intra-sedimentary reflector. A large Vp/Vs ratio can be caused by both saturation and poor consolidation of dry low-porosity materials (e.g. dry sands).To investigate the potential occurrence of an aquifer associated with this interface, a high-density/long-offset electrical resistivity survey was conducted in fall 2019 along the seismic line. The maximum offset is 915 m at an electrode spacing of 5 meters, aiming at reaching depths of investigations between 150 and 200 meters. Inversion of the ERT data was initially conducted by means of smoothness-constrained algorithms. The imaging results revealed consistent structures with those resolved through seismic methods, at least within the required depth of investigation between 150 - 200 m. Furthermore,more »
-
Despite progress in tomographic imaging of Earth’s interior, a number of critical questions regarding the large-scale structure and dynamics of the mantle remain outstanding. One of those questions is the impact of phase-boundary undulations on global imaging of mantle heterogeneity and on geodynamic (i.e. convection-related) observables. To address this issue, we developed a joint seismic-geodynamic-mineral physical tomographic inversion procedure that incorporates lateral variations in the depths of the 410- and 660-km discontinuities. This inversion includes S-wave traveltimes, SS precursors that are sensitive to transition-zone topography, geodynamic observables/data (free-air gravity, dynamic surface topography, horizontal divergence of tectonic plates and excess core-mantle boundary ellipticity) and mineral physical constraints on thermal heterogeneity. Compared to joint tomography models that do not include data sensitivity to phase-boundary undulations in the transition zone, the inclusion of 410- and 660-km topography strongly influences the inference of volumetric anomalies in a depth interval that encompasses the transition zone and mid-mantle. It is notable that joint tomography inversions, which include constraints on transition-zone discontinuity topography by seismic and geodynamic data, yield more pronounced density anomalies associated with subduction zones and hotspots. We also find that the inclusion of 410- and 660-km topography may improve the fit to the geodynamicmore »
-
SUMMARY Despite progress in tomographic imaging of Earth's interior, a number of critical questions regarding the large-scale structure and dynamics of the mantle remain outstanding. One of those questions is the impact of phase-boundary undulations on global imaging of mantle heterogeneity and on geodynamic (i.e. convection-related) observables. To address this issue, we developed a joint seismic-geodynamic-mineral physical tomographic inversion procedure that incorporates lateral variations in the depths of the 410- and 660-km discontinuities. This inversion includes S-wave traveltimes, SS precursors that are sensitive to transition-zone topography, geodynamic observables/data (free-air gravity, dynamic surface topography, horizontal divergence of tectonic plates and excess core-mantle boundary ellipticity) and mineral physical constraints on thermal heterogeneity. Compared to joint tomography models that do not include data sensitivity to phase-boundary undulations in the transition zone, the inclusion of 410- and 660-km topography strongly influences the inference of volumetric anomalies in a depth interval that encompasses the transition zone and mid-mantle. It is notable that joint tomography inversions, which include constraints on transition-zone discontinuity topography by seismic and geodynamic data, yield more pronounced density anomalies associated with subduction zones and hotspots. We also find that the inclusion of 410- and 660-km topography may improve the fit to themore »