The Quaternary Big Pine (BP) volcanic field in eastern California is notable for the occurrence of mantle xenoliths in several flows. This points to rapid ascent of basalt through the crust and precludes prolonged storage in a crustal reservoir. In this study, the hypothesis of phenocryst growth during ascent is tested for several basalts (13–7 wt% MgO) and shown to be viable. Phenocrysts of olivine and clinopyroxene frequently display diffusion‐limited growth textures, and clinopyroxene compositions are consistent with polybaric crystallization. When the most Mg‐rich olivine in each sample is paired with the whole‐rock composition, resulting
- Award ID(s):
- 2125941
- NSF-PAR ID:
- 10343603
- Date Published:
- Journal Name:
- GSA Bulletin
- ISSN:
- 0016-7606
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract (olivine‐melt) values (0.31–0.36) match those calculated from literature models (0.32–0.36). Application of a Mg‐ and a Ni‐based olivine‐melt thermometer from the literature, both calibrated on the same experimental data set, leads to two sets of temperatures that vary linearly with whole‐rock MgO wt%. Because the Ni thermometer is independent of water content, it provides the actual temperature at the onset of olivine crystallization (1247–1097°C), whereas the Mg thermometer gives the temperature under anhydrous conditions and thus allows Δ T (=T Mg −T Ni = depression of liquidus due to water) to be obtained. The average ΔT for all samples is ~59°C, which is consistent with analyzed water contents of 1.5–3.0 wt% in olivine‐hosted melt inclusions from the literature. Because the application of olivine‐melt thermometry/hygrometry at the liquidus only requires microprobe analyses of olivine combined with whole‐rock compositions, it can be used to obtain large global data sets of the temperature and water contents of basalts from different tectonic settings. -
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Abstract High‐frequency harmonic regression (2.0–4.0‐Hz cutoff) of receiver functions at two long‐running seismic observatories at mid‐Pacific hot spot islands confirms earlier detections of underplated material with seismic velocities intermediate to crust and mantle, and reveals it to be multilayered and anisotropic within ~30 km of the surface. Magmatic underplating beneath the oceanic Moho has been proposed to accompany basaltic melt that erupts at the seafloor and (eventually) atop a subaerial volcano. An alternate hypothesis is “metasomatic underplating” whereby crustal fractures developed during magma ascent allow seawater to infiltrate and to serpentinize the sub‐Moho mantle partially. Metasomatic underplating would lower seismic wave speeds, promote the buoyancy of the hot spot swell, and induce textural anisotropy as metamorphic expansion of olivine‐rich peridotite promotes a crack network along which serpentinization spreads. Differential expansion of mantle peridotite and crustal gabbro promotes cracks in the crust that offer new pathways for seawater to descend to the Moho, allowing metasomatic underplating to expand laterally and to contribute anisotropy to the underplated layer. Rare serpentinized mantle xenoliths confirm that crack textures can develop during serpentinization at depth. The discovery of iron‐oxidizing microbial mats on the seafloor flank of the Loihi volcano, and many locations of diffuse low‐temperature venting worldwide, is consistent with the circulation of metasomatic fluids with reducing chemistry, sourced from serpentinization at depth. Posteruptive uplift of Santa Maria Island (Azores), and asymmetry of the Hawaiian swell, suggests that underplating requires 2–4 Myr to complete, suggesting that fluid infiltration is slow, subject to cycles of blockage and fresh fracturing.
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Bulk-rock data are commonly used in geochemical studies as a proxy for melt compositions in order to understand the evolution of crustal melts. However, processes of crystal accumulation and melt migration out of deep-crustal, crystal-rich mush zones to shallower storage regions raise questions about how faithfully bulk-rock compositions in plutons approximate melt compositions. This problem is particularly acute in the lower crust of arcs, where melt reservoirs are subject to periodic melt extraction that leaves behind a cumulate residue. Here, we examine bulk-rock data from the perspective of high-Sr/Y plutonic rocks in the lower crust of a well-exposed Early Cretaceous cordilleran-arc system in Fiordland, New Zealand. We test the validity of using high-Sr/Y bulk-rock compositions as proxies for melts by comparing bulk-rock compositions to melts modeled from >100 major- and trace-element analyses of 23 magmatic clinopyroxene grains from the same samples. The sampling locations of the igneous clinopyroxenes and encompassing bulk rocks are distributed across ~550 km2 of exhumed lower crust and are representative of Mesozoic lower-crustal arc rocks in the Median batholith. We confirm that bulk-rock data have characteristics of high-Sr/Y plutons (Sr/Y >50, Na2O >3.5 wt%, Sr >1000 ppm, and Y <20 ppm), features that have been previously interpreted to indicate the presence of garnet as a residual or fractionating phase. In contrast to bulk rocks, igneous clinopyroxenes have low Sr (<100 ppm), high Y (25–100 ppm), and low molar Mg# [100 × Mg/(Mg + Fe)] values (60–70), which are consistent with derivation from fractionated, low-Sr/Y melts. Chondrite-normalized rare-earth-element patterns and Sm/Yb values in clinopyroxenes also show little to no evidence for involvement of garnet in the source or in differentiation processes. Fe-Mg partitioning relationships indicate that clinopyroxenes are not in equilibrium with their encompassing bulk rocks but could have been in equilibrium with melt compositions determined from chemometry of coexisting igneous hornblendes. Moho-depth calculations based on bulk-rock Sr/Y values also yield Moho depths (average = 69 km) that are inconsistent with Moho depths based on bulk-rock Ce/Y, contact aureole studies, Al-in-horn- blende crystallization pressures, and our modeled clinopyroxene crystallization pressures. These data indicate that most Mesozoic high-Sr/Y bulk rocks in the lower crust of Fiordland are cumulates formed by plagioclase + amphibole + clinopyroxene accumulation and interstitial melt loss from crystal-rich mush zones. Our data do not support widespread fractionation of igneous garnet nor partial melting of a garnet-bearing source in the petrogenesis of these melts. We speculate that melt extraction and the production of voluminous cumulates in the lower crust were aided by unusually high heat flow and high magma addition rates associated with an Early Cretaceous arc flareup. We conclude that bulk-rock compositions are poor proxies for melt compositions in the lower crust of the Median batholith, and geochemical modeling of these high-Sr/Y bulk rocks would overemphasize the role of garnet in their petrogenesis.more » « less
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Abstract A collection of quaternary, high-MgO (≤13.4 wt%) basanite and minette cinder and lava cones, with an enhanced arc geochemical signature, are located along the northern margin of the N–S Colima rift in western Mexico. The Colima rift overlies the lithospheric suture between the Jalisco block and Guerrero terrane, as well as the tear between the Rivera and Cocos subducting oceanic plates. From the literature, volatile analyses of olivine-hosted melt inclusions in the Colima cone samples document notably high concentrations of dissolved H2O in the melt (≤ 7.0 wt%) as well as degassing-induced phenocryst growth over a range of depths ≤25 km. In this study, it is shown that the high-MgO character of the Colima suite reflects liquid compositions, consistent with evidence for their rapid transit to the surface, without stalling in a crustal magma chamber. The most Mg-rich olivine analyzed in each sample matches the equilibrium composition at the liquidus based on olivine-melt Mn–Mg and Fe2+–Mg exchange coefficients. Application of both a Mg- and Ni-based olivine-melt thermometer, calibrated on the same experimental data set, to the Colima cone suite provides the temperature and dissolved H2O content at the liquidus. Because the Ni thermometer is insensitive to dissolved H2O in the melt, it gives the actual temperature at the onset of olivine phenocryst growth. For the nine Colima samples that range from 13.4–9.2 wt% MgO, resulting temperatures range from 1221°C to 1056°C (± 6–11°C). In contrast, the Mg thermometer is sensitive to dissolved H2O in the melt, and its application (without a correction of H2O) gives the temperature of olivine crystallization under anhydrous conditions. When the Mg- and Ni-based temperatures are paired, the depression of the liquidus (∆T = TMg–TNi) due to dissolved H2O can be obtained. For the high-MgO (>9 wt%) Colima samples, ∆T values range from 188°C to 109°C. Corrections for the effect of pressure (i.e. evidence that phenocryst growth began at ~700 MPa), increase ∆T by ~21°C. An updated model calibration (on experiments from the literature) that relates ∆T with dissolved H2O in the melt shows that the best fit (R2 = 0.95) is linear, wt% H2O = 0.047*∆T, with a standard error of ±0.5 wt%. Although the experimental data set spans a wide range of melt composition (e.g. 47–58 wt% SiO2, 4.4–10.2 wt% MgO, 1.3–4.9 wt% Na2O, 0.1–5.0 wt% K2O, 0.3–5.3 wt% H2O), no dependence on anhydrous melt composition is resolved. Application of this updated model to the Colima suite gives H2O contents of 5.1–8.8 wt% H2O, consistent with those analyzed in olivine-hosted MIs from the literature. When the thermometry and hygrometry results for the Colima cone suite are compared to those for the adjacent calc–alkaline basalts from the Tancítaro Volcanic Field (TVF) in Michoacán, two distinct linear trends in a plot of wt% H2O vs. temperature are found, indicative of different mantle sources. It is proposed that the high-MgO (>11 wt%) Colima cone melts were derived from a phlogopite-bearing harzburgitic mantle at the base of the Jalisco block lithosphere, whereas both TVF and Colima melts with ≤10 wt% MgO were derived from the asthenosphere (i.e. arc mantle wedge). In both mantle sources, slab-derived fluids were an important source of H2O.
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Rejuvenated volcanism is a worldwide phenomena occurring on many volcanic oceanic islands in all of the major ocean basins (e.g., Samoa, Madeira, Mauritius). This plume-related volcanism follows the main edifice-building stage after a hiatus of variable duration (e.g., 0.6–2 Myrs in Hawai‘i). Hawaiian rejuvenated basalts typically have high MgO contents (>10 wt%) and carry upper mantle xenoliths. Thus, these magmas are assumed to have ascended rapidly through the crust. The basalts erupted along the Koko Rift in Honolulu, Hawai‘i are unusual in their large range in MgO (5.4–11.4 wt%), absence of mantle xenoliths and history of magma mixing. The Koko Rift is the youngest area of rejuvenated volcanism in Hawai‘i (67 ± 2 ka) and its best developed rejuvenation-stage rift system (15-km long rift with 12 major and several minor subaerial and submarine eruptive centers). Here we report on the first systematic petrologic investigation of the Koko Rift basalts to better understand this most recent example of Hawaiian rejuvenated volcanism. New textural and mineral chemical evidence indicates magma was stored along the rift and later mixed to produce the subaerial lavas with 10–11 wt% MgO. The lower MgO (5–6 wt%) subaerial lavas were probably byproducts of the initial hybrid magma, subsequent crystal fractionation and then a second magma mixing event. The absence of mantle xenoliths in Koko Rift lavas and the relatively moderate forsterite contents (84–85%) in the higher MgO lavas may be related to the development of a crustal magma system within the rift. The record of crustal magma storage and crystal fractionation, and two magma mixing episodes in the Koko Rift lavas is unique among Hawaiian rejuvenated volcanism.more » « less
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1130/B36390.1
