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Title: Electrosynthesis of amino acids from biomass-derived α-hydroxyl acids
Electrochemical conversion of biomass-derived intermediate compounds to high-value products has emerged as a promising approach in the field of biorefinery. Biomass upgrading allows for the production of chemicals from non-fossil-based carbon sources and capitalization on electricity as a green energy input. Amino acids, as products of biomass upgrading, have received relatively little attention. Pharmaceutical and food industries will benefit from an alternative strategy for the production of amino acids that does not rely on inefficient fermentation processes. The use of renewable biomass resources as starting materials makes this proposed strategy more desirable. Herein, we report an electrochemical approach for the selective oxidation of biomass-derived α-hydroxyl acids to α-keto acids, followed by electrochemical reductive amination to yield amino acids as the final products. Such a strategy takes advantage of both reactions at the anode and cathode and produces amino acids under ambient conditions with high energy efficiency. A flow electrolyzer was also successfully employed for the conversion of α-hydroxyl acids to amino acids, highlighting its great potential for large-scale application.  more » « less
Award ID(s):
2102220
PAR ID:
10348787
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Green Chemistry
Volume:
24
Issue:
13
ISSN:
1463-9262
Page Range / eLocation ID:
5320 to 5325
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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