skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.

Explore Research Products in the PAR
It may take a few hours for recently added research products to appear in PAR search results.


  • NSF Public Access
  • Search Results
  • Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII]
Title: Synthesis of Ba(II) analogs of Ln(II)-in-(2.2.2-cryptand) and layered hexagonal net Ln(II) complexes, [(THF)Cs(µ–η5:η5–C5H4SiMe3)3LnII]
Award ID(s):
1855328
PAR ID:
10349292
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Polyhedron
Volume:
210
Issue:
C
ISSN:
0277-5387
Page Range / eLocation ID:
115493
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; ; ; ; ; ; (, Angewandte Chemie International Edition)
    Abstract Lanthanide triflates have been used to incorporate NdIIIand SmIIIions into the 2.2.2‐cryptand ligand (crypt) to explore their reductive chemistry. The Ln(OTf)3complexes (Ln=Nd, Sm; OTf=SO3CF3) react with crypt in THF to form the THF‐soluble complexes [LnIII(crypt)(OTf)2][OTf] with two triflates bound to the metal encapsulated in the crypt. Reduction of these LnIII‐in‐crypt complexes using KC8in THF forms the neutral LnII‐in‐crypt triflate complexes [LnII(crypt)(OTf)2]. DFT calculations on [NdII(crypt)]2+], the first NdIIcryptand complex, assign a 4f4electron configuration to this ion. 
    more » « less
  2. ; ; (, Inorganic Chemistry)
  3. ; ; ; ; (, Inorganic Chemistry)
  4. ; ; ; ; ; (, Organometallics)
  5. ; ; ; ; (, Inorganic Chemistry)
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email