More Like this

1. Mixed‐Valence Manganese Carboxylate Clusters, {Mn III 6 Mn II 4 }, {Mn III 7 Mn II 5 Na}, and {Mn III 7 Mn II 5 }, Derived from the Combined Use of Di‐2‐pyridyl Ketone with Selected Aliphatic Diols

   https://doi.org/10.1002/ejic.202300735  

   Skordi, Katerina ; Alexandropoulos, Dimitris I. ; Fournet, Adeline D. ; Panagiotou, Nikos ; Perlepes, Spyros P. ; Christou, George ; Tasiopoulos, Anastasios J. ( February 2024 , European Journal of Inorganic Chemistry)

   Three new polynuclear clusters with the formulae [Mn₁₀O₄(OH)(OMe){(py)₂C(O)₂}₂{(py)₂C(OMe)(O)}₄(MeCO₂)₆](ClO₄)₂(1), Na[Mn₁₂O₂(OH)₃(OMe){(py)₂C(O)₂}₆{(py)₂C(OH)(O)}₂(MeCO₂)₂(H₂O)₁₀](ClO₄)₈(2) and [Mn₁₂O₄(OH)₂{(py)₂C(O)₂}₆{(py)₂C(OMe)(O)}(MeCO₂)₃(NO₃)₃(H₂O)(DMF)₂](NO₃)₂(3) were prepared from the combination of di‐2‐pyridyl ketone, (py)₂CO, with the aliphatic diols (1,3‐propanediol (pdH₂) or 1,4‐butanediol (1,4‐bdH₂)) in Mn carboxylate chemistry. The reported compounds do not include the aliphatic diols employed in this reaction scheme; however, their use is essential for the formation of1–3. The crystal structures of1–3are based on multilayer cores which, to our knowledge, are reported for the first time in Mn cluster chemistry. Direct current (dc) magnetic susceptibility studies showed the presence of dominant antiferromagnetic exchange interactions within1–3. Alternating current (ac) magnetic susceptibility studies revealed the presence of out‐of‐phase signals below 3.0 K for2and3indicating the slow relaxation of the magnetization vector, characteristic of single‐molecule magnets; theU_effvalue of2was found to be 23 K and the preexponential factorτ₀~7.6×10⁻⁹ s.

    

   more » « less
2. New Synthetic Route for Cobalt(III) Dissymmetric Bisalkynyl Complexes Based on Cobalt(III)(cyclam)(C 2 NAP Mes ): New Synthetic Route for Cobalt(III) Dissymmetric Bisalkynyl Complexes Based on Cobalt(III)(cyclam)(C 2 NAP Mes )

   https://doi.org/10.1002/ejic.201901070  

   Banziger, Susannah D. ; Zeller, Matthias ; Ren, Tong ( November 2019 , European Journal of Inorganic Chemistry)
3. First Structurally Characterized Tricyanomanganate(III) and its Magnetic {Mn III 2 M II 2 } Complexes (M II = Mn, Ni)

   https://doi.org/10.1021/ic1006605  

   Tang, Minao ; Li, Dongfeng ; Mallik, Uma Prasad ; Withers, Jeffrey R. ; Brauer, Shari ; Rhodes, Michael R. ; Clérac, Rodolphe ; Yee, Gordon T. ; Whangbo, Myung-Hwan ; Holmes, Stephen M. ( June 2010 , Inorganic Chemistry)
4. Structural and Magnetic Variations in a Family of Isoskeletal, Oximate-Bridged {Mn IV 2 M III } Complexes (M III =Mn, Gd, Dy)

   https://doi.org/10.1002/chem.201706098  

   Alaimo, Alysha A. ; Worrell, Anne ; Gupta, Sayak Das ; Abboud, Khalil A. ; Lampropoulos, Christos ; Christou, George ; Stamatatos, Theocharis C. ( February 2018 , Chemistry - A European Journal)
5. Solid-State End-On to Side-On Isomerization of (N═N) 2– in {[(R 2 N) 3 Nd] 2 N 2 } 2– (R = SiMe 3 ) Connects In Situ Ln III (NR 2 ) 3 /K and Isolated [Ln II (NR 2 ) 3 ] 1– Dinitrogen Reduction

   https://doi.org/10.1021/jacs.2c06716  

   Chung, Amanda B. ; Rappoport, Dmitrij ; Ziller, Joseph W. ; Cramer, Roger E. ; Furche, Filipp ; Evans, William J. ( September 2022 , Journal of the American Chemical Society)