Two generations of dikes and sills (earlier granodiorite, later leucogranite) have intruded quartzofeldspathic to semi-pelitic hornfels in the innermost ~200 meters of the southern contact aureole of the Alta stock. Both zircon and monazite are present in the older granodiorite intrusions, and monazite alone is present in the younger leucogranite intrusions, and in biotite-rich reaction selvages formed by hydrothermal contact metamorphism in hornfels adjacent to these dikes and sills. U-Pb dates for zircon (n=532) range from ~38 to 32 Ma, with error on individual measurements of ±1–1.5 Ma, and define a KDE peak at 34.5 Ma. These zircon dates are slightly older than, but consistent with, existing zircon data from the Alta stock (35 to 32 Ma; Stearns et al., 2020), suggesting that the construction of the Alta stock began by emplacement of these granodiorite sills and dikes. Monazite Th-Pb dates (n = 888) range from ~41 to 28 Ma with error on individual measurements of ± 1–1.5 Ma. These dates are complicated by disturbances to the U/Th-Pb systematics by common Pb (Pbc) and excess 206Pb due to 230Th. Dates >38 Ma are disturbed by significant Pbc and do not represent crystallization ages. Dates from the granodiorites range from ~38–32 Ma. In individual samples of granodiorite where the disturbance from excess 206Pb can be rigorously evaluated, the monazite data sets yield concordant 232Th-208Pb and 207Pb/206Pb-corrected dates centered at ~35 Ma, consistent with zircon dates from these same samples. Monazite dates from the leucogranites are younger (<33 Ma), consistent with cross-cutting relationships (leucogranites cross-cut granodiorites). The monazite data from the leucogranite sills and dikes do not record magmatic or hydrothermal activity after ~29 Ma, in contrast to the titanite record of hydrothermal activity to as late as ~23 Ma in the border zone of the Alta stock and its endoskarns (Stearns et al., 2020). This absence suggests that once magma injection and associated contact metamorphism in the hornfels ceased, permeability in the hornfels decreased sufficiently by ~29 Ma to prevent subsequent infiltration of significant fluxes of hydrothermal fluid into these hornfels lithologies in the aureole.
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Uncertainty and sensitivity analysis for spatial and spectral processing of Pb isotopes in zircon by atom probe tomography
Measuring 207Pb/206Pb ratios by atom probe tomography (APT) has provided new insight into the nanoscale behavior of trace components in zircon, and their relationship to time, temperature and structure. Here, we analyze three APT data sets for a 3.77 Ga zircon from the Beartooth Mountains, USA, and apply systematic ranging approaches to understand the spatial and spectral uncertainties inherent in 207Pb/206Pb analysis by APT. This zircon possesses two, 100% concordant U-Pb analyses by secondary ion mass spectrometry (SIMS), indicative of closed U-Pb systematics on the micron scale since crystallization. APT data sets contain sub-spherical Pb-rich (>0.25% atomic) domains with diameter <15 nm. Broadly consistent Pb-rich regions are defined in applying six different permutations of the two most common cluster identification algorithms. Measured 207Pb/206Pb ratios within Pb-rich domains vary between 0.794±0.15 (±2σ) and 0.715±0.052 depending on the ranging approach, cluster definition protocol and number of clusters interrogated. For the bulk APT data sets, 207Pb/206Pb = 0.353±0.18; this is indistinguishable from the bulk 207Pb/206Pb ratio by SIMS (0.367±0.0037), and statistically distinct from the 207Pb/206Pb ratio within clusters. Bulk and clustered 207Pb/206Pb ratios are consistent with Pb clustering at ~2.8 Ga, during protracted metamorphism and magmatism in the Beartooth Mountains. 10.1002/9781119227250.ch16
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- Award ID(s):
- 1658823
- NSF-PAR ID:
- 10352132
- Editor(s):
- Moser, DE; Corfu, F; Darling, J; Reddy, SM; Tait, K
- Date Published:
- Journal Name:
- Geography monograph series
- ISSN:
- 1037-7158
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- https://doi.org/10.1002/9781119227250.ch16
