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			<titleStmt><title level='a'>Lithium and Beryllium in NGC 752—an Open Cluster Twice the Age of the Hyades</title></titleStmt>
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				<publisher></publisher>
				<date>03/01/2022</date>
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				<bibl> 
					<idno type="par_id">10353267</idno>
					<idno type="doi">10.3847/1538-4357/ac4eef</idno>
					<title level='j'>The Astrophysical Journal</title>
<idno>0004-637X</idno>
<biblScope unit="volume">927</biblScope>
<biblScope unit="issue">1</biblScope>					

					<author>Ann Merchant Boesgaard</author><author>Michael G. Lum</author><author>Ashley Chontos</author><author>Constantine P. Deliyannis</author>
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			<abstract><ab><![CDATA[Abstract            The surface abundances of the light elements lithium (Li) and beryllium (Be) reveal information about the physical processes taking place in stellar interiors. The investigation of the amount of these two elements in stars in open clusters shows the effect of age on those mechanisms. We have obtained spectra of both Li and Be in main-sequence stars in NGC 752 at high spectral resolution and high signal-to-noise ratios with HIRES on the Keck I telescope. In order to make meaningful comparisons with other clusters, we have determined the stellar parameters on a common scale. We have found abundances of Li and Be by spectral synthesis techniques. NGC 752 is twice the age of the well-studied Hyades. We find that (1) the Li dip centered near 6500 K is wider in NGC 752, having expanded toward cooler temperatures; (2) the Be dip is deeper in the older NGC 752; (3) the Li “peak” near 6200 K is lower by about 0.3 dex; (4) although there is little Be depletion in the cooler stars, it is possible that Be may be lower in NGC 752 than in the Hyades; and (5) the Li content in both clusters declines with decreasing temperature, but there is less Li in NGC 752 at a given temperature by ∼0.4 dex. These differences are consistent with the transport of the light-element nuclei below the surface convection zone as predicted by theory. That connection to rotational spin-down is indicated by the pattern of rotation with temperature in the two clusters.]]></ab></abstract>
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<div xmlns="http://www.tei-c.org/ns/1.0"><head n="1.">Introduction</head><p>Open clusters provide laboratories for studying many aspects of stellar structure and evolution because of the common origin, age, and composition of the stars in a given cluster. The changes with time are especially revealed by a comparison of properties in clusters of an array of ages. The surface abundances of Li, Be, and B in clusters enable exploration of the otherwise unobservable interiors of stars. These elements reveal the internal structure of stars because they are easily destroyed inside stars by thermonuclear reaction, particularly (p, &#945;) type. The three elements are susceptible to destruction at different interior temperatures, with Li being most fragile and B being more robust. The destruction of Li occurs above T = 2.5 &#215; 10 6 K, Be above 3.5 &#215; 10 6 K, and B above 5 &#215; 10 6 K. Thus, observations of the surface abundances reflect the depth and mechanisms of the mixing process(es) inside a star.</p><p>Cluster stars can show changes resulting from stellar mass, age, evolutionary stage, composition, rotation, and magnetism. Abundances of Li and Be can illuminate the effect of rotation and magnetic fields on stars and how stars evolve. When stars are formed, they have angular momentum. A comprehensive approach to modeling stellar evolution with rotation was pioneered by <ref type="bibr">Endal &amp; Sofia (1976</ref><ref type="bibr">, 1981)</ref> and includes effects of angular momentum loss from the surface and the action of a number of rotation-related instabilities in the interior. As stars evolve beyond the fully convective deuterium birthline along the Hayashi track, they contract and spin up. But a magnetically driven wind causes the surface layers to spin down <ref type="bibr">(Kawaler 1987</ref><ref type="bibr">(Kawaler , 1988))</ref>, causing a gradient of rotation with depth to increase as stars age. In the outer layers, when this gradient becomes too large, a secular shear instability is triggered <ref type="bibr">(Zahn 1974</ref>) that requires redistribution of angular momentum and causes mixing <ref type="bibr">(Pinsonneault et al. 1989</ref>). As a result, the surface abundances of Li, Be, and B decline as mixing brings these elements to depths where they are destroyed <ref type="bibr">(Chaboyer et al. 1995;</ref><ref type="bibr">Sills &amp; Deliyannis 2000;</ref><ref type="bibr">Somers &amp; Pinsonneault 2016)</ref>. Since these elements survive to different depths, observations of two or more of them can provide very powerful means to evaluate the effects of physical mechanisms that depend on depth. For example, since the efficiency of the shear-induced mixing described above decreases with depth, rotational models incorporating this shear predict a very different ratio of surface Li to Be to B than other mechanisms that have been proposed to explain Li depletion. Such observations of two or more of these elements in the same stars have produced strong evidence that rotational mixing is the dominant cause of light-element depletion in main-sequence stars <ref type="bibr">(Stephens et al. 1997;</ref><ref type="bibr">Boesgaard et al. 1998</ref><ref type="bibr">Boesgaard et al. , 2001</ref><ref type="bibr">Boesgaard et al. , 2004</ref><ref type="bibr">Boesgaard et al. , 2005</ref><ref type="bibr">Boesgaard et al. , 2016;;</ref><ref type="bibr">Deliyannis et al. 1998)</ref>. For some recent reviews of these and related observational discriminators, see <ref type="bibr">Cummings et al. (2017)</ref> and <ref type="bibr">Boesgaard et al. (2020)</ref>. With this study, NGC 752 joins studies of Li and Be in other key open clusters (e.g., <ref type="bibr">Boesgaard et al. 2001)</ref>.</p><p>Lithium abundances have been studied in main-sequence stars in NGC 752 first by <ref type="bibr">Hobbs &amp; Pilachowski (1986)</ref> in 18 stars; later <ref type="bibr">Pilachowski &amp; Hobbs (1988)</ref> added six more. They confirmed the F star Li dip that had been found in the Hyades by <ref type="bibr">Boesgaard &amp; Tripicco (1986)</ref>. Pilachowski and Hobbs commented that "the dip may extend to slightly cooler temperatures" in this older cluster than was found in the Hyades.</p><p>Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.</p><p>In her study of Li in M67 <ref type="bibr">Balachandran (1995)</ref>  A population census and membership analysis of NGC 752 has been done by <ref type="bibr">Daniel et al. (1994)</ref>. They distinguish cluster members from field stars by proper motions, radial velocities, and photometry. Some more recent studies of NGC 752 are by <ref type="bibr">Maderak et al. (2013)</ref>, <ref type="bibr">Castro et al. (2016</ref><ref type="bibr">), Sestito et al. (2004)</ref>, <ref type="bibr">Agueros et al. (2018), and</ref><ref type="bibr">Lum &amp;</ref><ref type="bibr">Boesgaard (2019)</ref>. The papers by <ref type="bibr">Sestito et al. (2004)</ref> and <ref type="bibr">Castro et al. (2016)</ref> focus on Li.</p><p>The open cluster, NGC 752, has an important place in cluster studies because it is twice the age of the very well-studied Hyades and about one-third the age of the Sun.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.">Observations</head><p>We use the work of <ref type="bibr">Daniel et al. (1994)</ref> to make the colormagnitude diagram of NGC 752 shown in Figure <ref type="figure">1</ref>. The stars we observed for Li are circled in red, and those for Be are indicated by blue squares.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.1.">Beryllium</head><p>Observations were made of 14 dwarf stars in NGC 752 over four observing runs between 2014 and 2019 with HIRES <ref type="bibr">(Vogt et al. 1994</ref>) on the Keck I telescope. The Be II resonance doublet is at 3130.42 and 3131.06 &#197; close to the atmospheric cutoff. Atmospheric absorption and dispersion are strong in the ultraviolet region, and so long exposure times are needed to obtain spectra with good signal-to-noise ratios (S/Ns). We tried to observe our stars as close to the meridian as possible to minimize the atmospheric effects. The decl. of NGC 752 is near +38&#176;, which helped to reduce those effects. There are three CCDs in the HIRES detector, and the blue one has a quantum efficiency of 93% at 3130 &#197;. This is an important factor in lowering the exposure times at these short wavelengths. Our spectra covered the region of 3000-5800 &#197; and have a spectral resolution of 0.027 &#197; pixel -1 near the Be lines and a resolution element of 2 pixels.</p><p>Table <ref type="table">1</ref> shows the properties of the stars we have observed and the details of our Keck/HIRES Be observations. The stars are designated by both their Heinemann numbers (H; Heinemann 1926) and their Platais numbers (Pla; Platais 1991) in all the tables. We have used the value of E(B -V ) = 0.035 from <ref type="bibr">Daniel et al. (1994)</ref>.</p><p>An example of the Be II region in one of our stars, H216, is shown in Figure <ref type="figure">2</ref>. We indicate the positions of the two resonance lines of Be II and the identifications of several other features in that 4 &#197; region. With a temperature of 6182 K, this star is representative of several stars in our Be selection. It has a v sin i value of 4.2 km s -1 .</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.2.">Lithium</head><p>As part of a larger abundance study of main-sequence stars in NGC 752 <ref type="bibr">(Lum &amp; Boesgaard 2019)</ref> we obtained spectra in the Li I region of 10 stars. The details of the observations for Li in those stars are given in Table <ref type="table">2</ref>. For the Li spectra our exposure times were short and resulted in higher S/Ns than achieved for the Be observations. These spectra cover approximately 5700-8120 &#197; with some interorder gaps. The spectral resolution is 0.046 &#197; pixel -1 near the Li I doublet, with a 2-pixel resolution element.</p><p>We show a 10 &#197; spectral region of the Li I resonance doublet in Figure <ref type="figure">3</ref> with the nearly Fe I lines indicated; this is the same star as in Figure <ref type="figure">2</ref>. This spectral region is quite uncrowded in comparison to the Be II region. There is, however, a line of Fe I that is found on the shortward side of the Li line and becomes stronger with decreasing temperature.</p><p>We have observed Li in eight stars in common with <ref type="bibr">Sestito et al. (2004)</ref>. Our results for A(Li) are in excellent agreement.  <ref type="bibr">(1994)</ref>. The 14 stars we observed for Be have blue squares, and the 10 for Li have red circles. We observed both Li and Be in six stars. They range from -0.09 to +0.01, with a mean difference of 0.015.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.">Abundances</head></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.1.">Stellar Parameters</head><p>To determine stellar abundances, it is necessary to characterize the stellar atmospheres with effective temperature, gravity, and microturbulent velocity. For NGC 752 we evaluated the parameters in much the same way as done by <ref type="bibr">Maderak et al. (2013)</ref>. The (B -V ) photometry of <ref type="bibr">Daniel et al. (1994)</ref> was used along with their value of E(B -V ) = -0.035. We used the value of [Fe/H] = -0.01 from <ref type="bibr">Lum &amp; Boesgaard (2019)</ref>. The derived temperature does depend on [Fe/H], and <ref type="bibr">Maderak et al. (2013)</ref> used -0.06, so our derived temperatures are slightly different from theirs. In particular, for the nine stars in common our temperatures are higher by 6-8 K. We used the values of log g from <ref type="bibr">Maderak et al. (2013)</ref> for the nine stars in common; for others we used the linear relationship between temperature and log g to find log g. We also made use of the microturbulent velocity relationship found empirically by <ref type="bibr">Edvardsson et al. (1993)</ref>; all of our stars were within the boundaries of their parameters for the equation for &#958;.</p><p>Table <ref type="table">3</ref> gives the stellar parameters for both our Li and Be stars. For 15 of the 18 stars observed it also includes values for v sin i as listed by <ref type="bibr">Mermilliod et al. (2009)</ref>. We used the program MOOG <ref type="bibr">(Sneden 1973;</ref><ref type="bibr">Sobeck et al. 2011</ref>) in synthe mode with interpolated <ref type="bibr">Kurucz (1993)</ref> model atmospheres to find both Li and Be abundances.</p><p>We have made comparisons for temperature with other recent published work. The agreement is satisfactory: <ref type="bibr">Lum &amp; Boesgaard (2019)</ref>, 10 stars, +15 &#177; 45; <ref type="bibr">Castro et al. (2016)</ref>, 5 stars, +33 &#177; 71; <ref type="bibr">Maderak et al. (2013)</ref>, 9 stars, +6 &#177; 1; <ref type="bibr">Sestito et al. (2004)</ref>, 9 stars, -38 &#177; 14. We also made log g comparisons, but only those first two references give log g values. There is excellent agreement: <ref type="bibr">Lum &amp; Boesgaard (2019)</ref>, 10 stars, +0.02 &#177; 0.04; <ref type="bibr">Castro et al. (2016)</ref>, 5 stars, 0.02 &#177; 0.02.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.2.">Beryllium</head><p>Our synthesis covered the spectral region from 3129.5 to 3132.5 &#197; with a line list of over 300 spectral features and includes atomic lines and molecular features due to CH, NH, OH, CN, and CO. As can be seen in Figure <ref type="figure">2</ref>, the longward Be II line at 3131 &#197; is relatively free of blends, so we relied primarily on that line to determine the amount of Be.</p><p>Examples of the Be spectrum synthesis fits can be seen in Figure <ref type="figure">4</ref> for two stars. The star H216 has v sin i = 4.2 km s -1 , while H185 in the bottom panel shows rotation of more than double that at 9.2. This figure shows that for the more rapidly rotating stars, it is more difficult to be confident of the fit for the shortward, more blended Be II line. The results for A(Be) are given in Table <ref type="table">4</ref>. A(Be) = log N(Be)/N(H) + 12.00.</p><p>Unfortunately, the stars in the Li dip are the hotter ones, and thus they are more likely to be rotating rapidly. There is a dichotomy in stellar rotation rates that was first shown by <ref type="bibr">Kraft (1967)</ref> such that stars hotter than &#8764;6200 K are rotating rapidly. That larger rotation rate results in severe blending in this spectral region. Five of the stars we observed for Be are in the Li dip. Three of the Li-dip stars-H197, T = 6633 K; H264, T = 6635 K; H302, T = 6703 K-have low upper limits on A (Li) (=log N(Li)/N(H) + 12.00). For these stars we could only determine upper limits on the Be abundance also. There are two stars in the Li dip that have measurable but depleted Li. One star, H293 (T = 6452 K), shows measurable but depleted Be with A(Be) = 0.82. The other, H259 (T = 6724 K), is on the hot side of the Li dip and may show mild Be depletion with A (Be) = 1.12. For one of the hotter stars, H10, we were unable to synthesize a spectrum that matched the observed in spite of a respectable S/N. This star is brighter by a magnitude than the other stars in our sample. It is classed as a spectroscopic binary in SIMBAD, which would account for its brightness and complicated spectrum.  </p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.3.">Lithium</head><p>In the Li region we synthesized 8 &#197; from 6703.3 to 6711.0. Our line list had 95 lines that included some 40 CN features. Figure <ref type="figure">5</ref> shows the synthesis for two stars. The Li abundance is sensitive to temperature, and cooler stars show stronger Li lines for the same Li abundance. Here our coolest star, H146, has weak Li lines owing to its Li depletion compared to the hotter star, Pla 1012. The blending feature at 6707.432 is due to Fe I and can be seen clearly in the spectrum of H146 and in the synthesis fit; this is clear in the fit containing no Li (red dotted line), which does have Fe. Our A(Li) results are also given in Table <ref type="table">4</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.4.">Error Estimates</head><p>It is possible to use MOOG to find abundance errors resulting from stellar parameter uncertainties. We have used models on the Kurucz-model grid with a range in temperature, log g, and [Fe/H]. We used MOOG in the "blends" mode with 13 lines blending with the Be II lines at 3131 &#197;. A summary of those results follows. A change in temperature of &#177;80 K gives a change in A(Be) of &#177;0.01, except there is no change in the range from 6000 to 6250 K. The largest error stems from log g, where an uncertainty of +0.1 leads to an uncertainty in A(Be) from 0.036 to 0.052, increasing with decreasing temperature from 6500 to 5750 K. As [Fe/H] increases by +0.05, A(Be) increases by &#8764;+0.02. For each star for which we determine a Be abundance we have assessed errors due to each of the parameters and found the total error by summing them in quadrature. Those range from &#177;0.042 to &#177;0.057, with the coolest stars having the largest errors.</p><p>Another uncertainty in the determination of Be abundances actually comes from the "goodness of fit" in the line profile matching (sigma calculated by MOOG) and from the relative reliance of the two Be II lins. The line at 3131 &#197; has substantially fewer blending features as can be seen in Figures <ref type="figure">2</ref> and<ref type="figure">4</ref>. For three of the stars the rotational broadening prevented a determination of the Be abundance and only upper limits could be found: H197, H264, and H302. For nine others the fit for the &#955;3131 line was excellent, while the blend at the &#955;3130 line gave a slightly lower Be abundance; we relied on the &#955;3131 line. The fit of a continuum in this spectral region produces another uncertainty that is difficult to evaluate; experience suggests that this can be done to &#177;5%, although this varies depending on the S/N of the exposure and the rotational velocity of the star. An error estimate is presented in Table <ref type="table">4</ref>.</p><p>We have determined the Li abundances by spectrum synthesis also using the "synthe" routine in MOOG. The error in the Li abundance is almost entirely from the error in the effective temperature. A temperature difference of &#177;75 K translates to &#177;0.06 in A(Li). We synthesized a region of 8 &#197; that includes two Fe I lines with differing excitation potentials; the fits are excellent for both of those lines, and that provides another check on the temperature. The Fe I line at 6707.432 &#197; blends with the Li feature at cooler temperatures but is well accounted for in the spectrum synthesis analysis and is not a factor in the error evaluation. The Li region spectra and the syntheses can be seen in Figures <ref type="figure">3</ref> and<ref type="figure">5</ref>.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.">Discussion</head></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.1.">Lithium and Beryllium in NGC 752</head><p>We have determined Be abundances in 13 stars and Li abundances in 10 stars. Abundances of Li have been determined for an additional 29 stars in previous research. We have noted above that there are some temperature differences with those previous studies of NGC 752. In order to make useful comparisons, we put those investigations of Li abundances on the temperature scale used here and by <ref type="bibr">Maderak et al. (2013)</ref> and recalculated the values of the Li abundances. Our values and these revised results for T eff and A(Li)  abundance are given in Table <ref type="table">5</ref> for 39 main-sequence stars in NGC 752, along with the original references.</p><p>Figure <ref type="figure">6</ref> shows those results for Li, together with an approximate fit through the points. This fit is modeled after the fit through the Li-temperature relation for the Hyades showing an unmeasurably deep Li dip near 6500 K, a peak in Li near 6200 K, followed by a steep decline to vanishingly small amounts of Li near 5200 K.</p><p>The results for Be can be added to our diagram in Figure <ref type="figure">6</ref> with the outcome for Li on the same vertical scaling but referenced to their individual meteoritic abundances from <ref type="bibr">Anders &amp; Grevesse (1989)</ref>. (See the discussion about Be in the solar system by Lodders 2003, who promotes the need to clarify the solar Be and the need for more Be analyses in Ci chondrites.) This is shown in Figure <ref type="figure">7</ref>. Our Be values for the stars in NGC 752 are connected by vertical dotted lines to their Li values for easier reference.</p><p>The four stars in the Li-dip region are clearly depleted in Be, with three showing only upper limits for both Li and Be and the fourth (H293) showing A(Li) = 2.22 and measurable but depleted A(Be) at 0.82. They show strong evidence for a Be dip. A fifth star, H259, at T = 6724 K, with measurable Li depletion shows marginal Be depletion with A(Be) = 1.12.</p><p>For the solar-like stars with effective temperatures below &#8764;6400 K there is little Be depletion. The data in Table <ref type="table">4</ref> give a mean value for A(Be) in those eight stars of 1.20 &#177; 0.06. This is comparable to the solar Be value of 1.15 &#177; 0.20 from the careful study of solar Be by <ref type="bibr">Chmielewski et al. (1975)</ref> and of the 1.15 value found by <ref type="bibr">Boesgaard &amp; King (2002)</ref> from a daytime sky Be spectrum with the same telescope and instrument as our data for NGC 752. <ref type="bibr">King et al. (1997)</ref> found a probable Be abundance in the Sun in the range A (Be) = 0.91-1.26, corresponding to a probable Be depletion of 0.16-0.50. In a recent paper <ref type="bibr">Asplund et al. (2021)</ref> use a 3D hydrodynamic model of the Sun to determine the chemical makeup of the Sun. They give the solar Be as 1.38 &#177; 0.09 but suggest further analysis with a careful reassessment of the blends.</p><p>Figure <ref type="figure">7</ref> also shows how small the Be depletions in NGC 752 are relative to their Li depletions in the three coolest stars. Those Li depletions are substantial in the cooler stars.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.2.">Comparison with the Hyades</head><p>In order to make comparisons with the younger Hyades, we need to ensure that the stellar parameter scales are alike. For NGC 752 the temperature scale is consistent with what was used for the Hyades in the Li, Be, and B research by <ref type="bibr">Boesgaard et al. (2016)</ref>. They followed the study of <ref type="bibr">de Bruijne et al. (2001)</ref>, who used the results from multiple measurements of (B -V ) from Hipparcos for 92 "high-fidelity" Hyades members. They used the calibrations of <ref type="bibr">Bessell et al. (1998)</ref> to convert measured (B -V ) values to T eff ; they correct for the Hyades metallicity of +0.14 following <ref type="bibr">Alonso et al. (1996)</ref>.</p><p>The values for T eff in the Hyades are given in Table <ref type="table">3</ref> in <ref type="bibr">Boesgaard et al. (2016)</ref>.</p><p>Another large study that included Li abundance in the Hyades was done by <ref type="bibr">Cummings et al. (2017)</ref>. They used many (ground-based) color indices to find stellar temperatures. They converted each color index to an effective B -V index and used the calibration described in <ref type="bibr">Deliyannis et al. (2002)</ref> to find temperatures for their 90 Hyades stars. The temperature agreement with the 79 Hyades stars from <ref type="bibr">Boesgaard et al. (2016)</ref> is remarkably good; for the 73 stars in common the slope of the relationship of the temperatures is 1.0094.</p><p>Those two Hyades Li studies have the same temperature scale. The <ref type="bibr">Cummings et al. (2017)</ref> method for the Hyades temperature determination is the same one used by <ref type="bibr">Maderak et al. (2013)</ref> for NGC 752. Here we have used that same method for temperature determination with the exception of the value for [Fe/H] for NGC 752; this was discussed in  Section 3.1. The log g scales are identical. We can conclude that the scales for NGC 752 and the Hyades are as similar as possible.</p><p>The counterpart diagram to Figure <ref type="figure">7</ref> for Li and Be in the Hyades in shown in Figure <ref type="figure">8</ref>, which is based on the Li and Be results of <ref type="bibr">Boesgaard et al. (2016)</ref>. The younger Hyades shows a deep Li dip centered at &#8764;6650 K and a clear matching Be dip. In the cooler dwarfs there is little Be depletion; we have found little cool star depletion of Be for the older NGC 752. This is similar to the earlier Hyades findings of <ref type="bibr">Boesgaard &amp; King (2002)</ref>, who reported a mean A(Be) = 1.33 &#177; 0.06 for the 10 coolest stars, and to the more recent result of <ref type="bibr">Boesgaard et al. (2016)</ref> for the mean of the 31 stars below 6400 K of A (Be) = 1.31 &#177; 0.12. The benchmark Be abundance for the solar system, as measured in meteorites, is 1.42 &#177; 0.04 <ref type="bibr">(Anders &amp; Grevesse 1989</ref>).</p><p>The Hyades is younger than the Sun and mildly metal-rich at [Fe/H] = +0.13, so one might ask if it has initial values of Li and Be that are higher than the solar system values: A (Li) = 3.31 and A(Be) = 1.42. The stars in the Hyades and its sister cluster, Praesepe, have been well studied for Li abundances: <ref type="bibr">Boesgaard &amp; Budge (1988)</ref>  <ref type="figure">8</ref>. We can conclude that the meteoritic abundances provide a useful comparison as initial abundances for Li and Be. Furthermore, there are virtually no F, G, and K field stars with higher Li values than 3.31. <ref type="bibr">Ram&#237;rez et al. (2012)</ref> present Li abundances for 1381 FGK dwarfs and subgiants; only 10 of those stars had A(Li) &gt; 3.3.</p><p>Although more than half the stars with T &lt; 6400 K show no apparent Be depletion, the Hyades mean value of 1.33 &#177; 0.06 is above the mean of 1.20 &#177; 0.06 found for eight stars in NGC 752. The Hyades is &#8764;680 Myr <ref type="bibr">(Gossage et al. 2018)</ref>, while NGC 752 is about twice that age at &#8764;1.34 Gyr <ref type="bibr">(Agueros et al. 2018)</ref>, and the difference in the mean Be abundances in the G   dwarfs in the two clusters could be due to the age difference; there has been more time for the larger depletion of Be to have occurred in NGC 752. Both values are below the original solar system value yet higher than the depleted solar content of Be of 1.15.</p><p>The comparison of Figures <ref type="figure">7</ref> and<ref type="figure">8</ref> shows that the Be dip in the older NGC 752 is deeper than the Be dip in Hyades. The Hyades Be depletion is measurable; Be is depleted by a factor of 6-7 from the meteoritic value and from the Hyades Be value in the cooler G dwarfs. In NGC 752, two Be detections and three upper limits on Be were found. The upper limits indicate Be depletions of more than an order of magnitude. In both clusters Li is severely depleted and unmeasurably low in the center of the dip. For the Hyades in the temperature region around 6200-6400 K there is an Li "peak." Those stars have A(Li) not far below the meteoritic abundance. However, in NGC 752 those stars are Li depleted by about a factor of 3. The older age of NGC 752 contributes to this difference in Li.</p><p>In the cooler stars, the G dwarfs, Be seems uniformly depleted in NGC 752 and more depleted than in the Hyades stars relative to the meteoritic value. In the cooler stars, the Li content is decreasing with decreasing temperature in both the Hyades and NGC 752, but there are larger Li depletions at a given temperature in the older NGC 752. Recall that the Be abundances appear similarly constant in this temperature range in both clusters with an apparently reduced level in NGC 752.</p><p>In Figure <ref type="figure">9</ref> we show the fits for both NGC 752 and the Hyades for the Li-temperature relationship, along with the Li data points for NGC 752. This figure makes the Li differences between the young Hyades and the older NGC 752 stand out. Although the hot sides of the Li dip seem similar in the two clusters, it is clear that the Li gap is broader in NGC 752, i.e., the cool side of the dip has advanced to cooler temperatures in the older cluster. When the breadth of the dip is measured at A(Li) = 2.5, it is 295 K in the Hyades and 480 K in NGC 752, or 185 K wider in NGC 752. We thus quantify the suspicion by <ref type="bibr">Hobbs &amp; Pilachowski (1986)</ref> of "growth of the gap with age."</p><p>Figure <ref type="figure">9</ref> also makes it clear that the peak Li values near 6200-6300 K are lower in NGC 752. For the Hyades the peak A(Li) is 3.20, compared to 2.85 for NGC 752, or a factor of &#8764;2 greater depletion in NGC 752. Although the fall-off of A(Li) toward cooler temperatures has a similar pattern in the two clusters, there is greater Li depletion at each temperature in NGC 752.</p><p>For NGC 752 we find (1) a greater width of the Li dip toward cooler stars, (2) a deeper Be dip, (3) a lower Li peak, (4) a Be mean for the three coolest stars that may be lower than the meteoritic Be and may be lower than the Hyades mean, and (5) a greater Li depletion in the stars cooler than &#8764;6200 K at each temperature. All five of these phenomena can be attributed, at least in part, to the older age of NGC 752. In addition to the age difference between the two clusters, there is a difference in the metallicity, with the older NGC 752 having only 70% of the metal content of the Hyades. The greater amount of the heavy elements in the Hyades stars would lead to a greater opacity, which, in turn, creates a deeper convection zone down to hotter temperatures. This effect could lessen the impact of the age difference.</p><p>The most successful theory to account for the simultaneous depletions of the light elements in the Li-Be dip appears to be extra mixing below the surface convection zone caused by stellar rotation and spin-down of that rotation with time (e.g., <ref type="bibr">Charbonnell et al. 1994;</ref><ref type="bibr">Deliyannis &amp; Pinsonneault 1997;</ref><ref type="bibr">Somers &amp; Pinsonneault 2016;</ref><ref type="bibr">Dumont et al. 2021)</ref>.</p><p>These models predict the dependences of Li and Be with temperature that we observe in these two clusters, and that an older cluster should be more depleted in both elements. The models take into account that stars spin down during the main sequence, which triggers a shear instability that causes mixing and thus surface depletion of Li, Be, and B. The degree of depletion depends on how much angular momentum is lost and continues with age as stars continue to spin down. In going from G dwarfs to F dwarfs (increasing in mass), stars form with an increasing amount of initial angular momentum and lose more as they age <ref type="bibr">(Barnes 2007;</ref><ref type="bibr">Reinhold &amp; Gizon 2015)</ref>. This creates the F-dwarf Li and Be dips and the Li peak (less depletion) in late F/early G dwarfs. However, in increasingly cooler G dwarfs the surface convection zone occupies an increasingly substantial fraction of the Li preservation region, so increasingly less rotational mixing is needed to deplete Li. Thus, the Li abundances decline steeply, in spite of the smaller initial angular momenta in these stars. However, the predicted pattern for Be is different. Since the surface convection zone is tiny in F dwarfs compared to the (Li and) Be preservation region(s), rotational mixing does nearly all the mixing, creating a Be dip. However, in going to cooler stars, the Be preservation region remains substantially deeper than the surface convection zone, so there is no Be peak, just a flattening of the Be-temperature relation, with little Be depletion in the cooler G dwarfs. One of the five interesting results enumerated above is that the Be abundances in the cooler stars in NGC 752 appear to be lower than those in the Hyades in stars of similar temperature; compare Figures <ref type="figure">7</ref> and<ref type="figure">8</ref>. In fact, this agrees with previous published results. In particular, <ref type="bibr">Stephens et al. (1997)</ref> show calculations of both Li and Be deletions in their Figures <ref type="figure">11</ref> and<ref type="figure">12</ref>. The depletions are due to rotationally induced mixing. They were calculated for initial equatorial rotation speeds of 30 and 10 km s -1 and for ages of 0.1, 1.7, and 4.0 Gyr.</p><p>Their calculations are relevant for our clusters and were done for solar metallicity. Figure <ref type="figure">10</ref> shows our Be abundances in NGC 752, along with the calculated abundances for initial velocities of 10 and 30 km s -1 for the younger two ages. This shows that it would not be unexpected for NGC 752, at an age of 1.34 Gyr <ref type="bibr">(Agueros et al. 2018)</ref>, to show some Be depletion. The younger Hyades at 0.65 Gyr might have little or no Be depletion caused by extra mixing from rotational spin-down effects. A distribution of initial rotational velocities and so a spread in Be abundances would be expected.</p><p>We have assembled data on present-day stellar rotation rates for these two clusters from <ref type="bibr">Mermilliod et al. (2009)</ref>. These data are in the form of v sin i, the readily measurable parameter. Figure <ref type="figure">11</ref> is a plot of v sin i with temperature over our range of main-sequence stars. At a given temperature the points for NGC 752 are typically below the upper envelope for the Hyades points. If both clusters started out with similar distributions of rotation velocities, it appears that the stars in NGC 752 have spun down more, as would be expected for an older cluster. The rotationally induced mixing would have acted to reduce both Li and Be in that cluster more than it would in the Hyades, as observed. Stars in both clusters show evidence of the "Kraft break" where the surface rotation has slowed down.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.">Summary and Conclusions</head><p>We have made observations of Be in 14 F and G dwarfs in the open cluster NGC 752 with the Keck I telescope and HIRES. These were added to our Keck/HIRES spectra of Li in 10 stars. Six of our stars were observed for both Li and Be. Both Li and Be abundances were determined by spectral synthesis using the program MOOG.</p><p>Our Li results and those of other studies reported in the literature have been put on a common scale for the atmospheric parameters; we now have consistent results for Li in 39 stars. We find a deep and broad Li dip in NGC 752 that extends down to cool temperatures near 6400 K. Lithium abundances reach a cool star peak near 6200 K. They then fall off rapidly toward 5500 K, a signature of the deepening surface convection zone. Our Be abundance results show a deep dip across the Li dip, but no falloff in the cooler stars. This indicates that convection does not extend deep enough to reach temperatures near 3.6 &#215; 10 6 needed to destroy Be.</p><p>Our parameter scale is the same as that of the Hyades, so that direct comparisons could be made of the two clusters in their light-element content. NGC 752 is twice the age of the Hyades and has 70% of its metal content. The well-studied Hyades was discovered to have substantial Li depletion in main-sequence stars in the temperature range &#8764;6400-6800 K by <ref type="bibr">Boesgaard &amp; Tripicco (1986)</ref> and has been studied more thoroughly since then, most recently by <ref type="bibr">Boesgaard et al. (2016)</ref> and <ref type="bibr">Cummings et al. (2017)</ref>. For the stars cooler than the Li dip in the Hyades, there is an "Li peak" at roughly 6100-6400 K before the Li abundance declines sharply toward 5000 K as can be seen in Figure <ref type="figure">8</ref>.</p><p>The abundances of Be in the Hyades were first studied by <ref type="bibr">Boesgaard &amp; King (2002)</ref> and later by <ref type="bibr">Boesgaard et al. (2016)</ref>. Those Hyades Be abundances as a function of temperature can be seen in Figure <ref type="figure">8</ref>. There is a dip in the Be abundances that corresponds to that in the Li abundances, but the Be dip is not nearly as deep as the Li dip. Additionally, there is no decline in the Be abundances at the cooler temperatures as seen for Li.</p><p>In this work we have found intriguing differences in the light-element abundances of the two clusters. There is an Li dip in NGC 752 that is wider than the one in the Hyades, extending down to temperatures &#8764;200 K cooler.</p><p>There is also a Be dip that corresponds to the one in the Hyades. However, the Be dip in NGC 752 appears to be deeper than the Be dip in the Hyades. When these depletions are measured relative to the meteoritic Be abundances, for NGC 752 Be is lower by at least a factor of 20, compared to a factor of 6 for the Hyades.</p><p>In the distribution of Li with temperature in the Hyades there is a peak in A(Li) near 6300 K close to 3.2 (see Figure <ref type="figure">8</ref>). This is close to the value on the hot side of the dip. The corresponding peak for NGC 752 (Figure <ref type="figure">6</ref>) is closer to 6200 K and reaches only 2.85, a factor of &#8764;2 lower in Li content. There is a further decline in Li toward cooler stars in both clusters. Lithium declines steadily toward lower temperatures, but there is less Li at a given temperature in NGC 752 as shown in Figure <ref type="figure">9</ref>.</p><p>The pattern for the Be abundances in cooler stars is different from that of Li. As seen in Figure <ref type="figure">8</ref>, there is no decline in Be in the Hyades for stars between &#8764;5400 and &#8764;6300 K, with an average value for A(Be) of 1.33 &#177; 0.06. For NGC 752, however, the average Be content in those G stars appears to be uniformly lower than that in the Hyades. The mean value for those eight stars is A(Be) = 1.20 &#177; 0.06. This is a decrease of 75% compared to the Hyades. Such a difference could be due to age in the sense that there has been a slow decline in Be for cool stars in the older cluster as the calculations show in Figure <ref type="figure">10</ref>. There is also the possibility that the older NGC 752 had lower Be initially.</p><p>The cause of the light-element depletions has been linked to many physical characteristics in stellar interiors. The most successful has been mixing driven by rotation and spin-down effects. Figure <ref type="figure">11</ref> shows that the stars in NGC 752 are rotating more slowly than their Hyades counterparts. The mixing of surface material into the interior resulting from the rotational spindown produces the reduction of both Li and Be. The Li and Be abundance differences between the Hyades and NGC 752 could be attributed to age via the influence of rotational mixing.</p><p>We are grateful to the Keck Observatory support astronomers for their knowledgeable assistance during our observing runs. We thank C. J. Ma for help with the Li spectra. This work has been supported by the National Science Foundation through AST-1909456 to C.P.D.</p></div><note xmlns="http://www.tei-c.org/ns/1.0" place="foot" xml:id="foot_0"><p>The Astrophysical Journal, 927:118 (10pp), 2022 March 1 Boesgaard et al.</p></note>
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