Abstract Carbon micro/nanolattice materials, defined as three-dimensional (3D) architected metamaterials made of micro/nanoscale carbon constituents, have demonstrated exceptional mechanical properties, including ultrahigh specific strength, stiffness, and extensive deformability through experiments and simulations. The ductility of these carbon micro/nanolattices is also important for robust performance. In this work, we present a novel design of using reversible snap-through instability to engineer energy dissipation in 3D graphene nanolattices. Inspired by the shell structure of flexible straws, we construct a type of graphene counterpart via topological design and demonstrate its associated snap-through instability through molecular dynamics (MD) simulations. One-dimensional (1D) straw-like carbon nanotube (SCNT) and 3D graphene nanolattices are constructed from a unit cell. These graphene nanolattices possess multiple stable states and are elastically reconfigurable. A theoretical model of the 1D bi-stable element chain is adopted to understand the collective deformation behavior of the nanolattice. Reversible pseudoplastic behavior with a finite hysteresis loop is predicted and further validated via MD. Enhanced by these novel energy dissipation mechanisms, the 3D graphene nanolattice shows good tolerance of crack-like flaws and is predicted to approach a specific energy dissipation of 233 kJ/kg in a loading cycle with no permanent damage (one order higher than the energy absorbed by carbon steel at failure, 16 kJ/kg). This study provides a novel mechanism for 3D carbon nanolattice to dissipate energy with no accumulative damage and improve resistance to fracture, broadening the promising application of 3D carbon in energy absorption and programmable materials.
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Anelasticity in thin-shell nanolattices
In this work, we investigate the anelastic deformation behavior of periodic three-dimensional (3D) nanolattices with extremely thin shell thicknesses using nanoindentation. The results show that the nanolattice continues to deform with time under a constant load. In the case of 30-nm-thick aluminum oxide nanolattices, the anelastic deformation accounts for up to 18.1% of the elastic deformation for a constant load of 500 μN. The nanolattices also exhibit up to 15.7% recovery after unloading. Finite element analysis (FEA) coupled with diffusion of point defects is conducted, which is in qualitative agreement with the experimental results. The anelastic behavior can be attributed to the diffusion of point defects in the presence of a stress gradient and is reversible when the deformation is removed. The FEA model quantifies the evolution of the stress gradient and defect concentration and demonstrates the important role of a wavy tube profile in the diffusion of point defects. The reported anelastic deformation behavior can shed light on time-dependent response of nanolattice materials with implication for energy dissipation applications.
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- Award ID(s):
- 1929646
- NSF-PAR ID:
- 10356341
- Date Published:
- Journal Name:
- Proceedings of the National Academy of Sciences
- Volume:
- 119
- Issue:
- 38
- ISSN:
- 0027-8424
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Three-dimensional (3D) nanostructures play a crucial role in nanophotonics, lasers, and optical systems. This article reports on the fabrication of 3D nanostructures consisting of opal structures that are spatially aligned to an array of holes defined in the photoresist. The proposed method uses colloidal lithography to pattern a hexagonal array of holes, which are then used to direct the subsequent 3D assembly of colloidal particles. This approach allows the 3D opal structures to be aligned with the 2D array of holes, which can enhance spatial-phase coherence and reduce defects. The polymer patterns can be used as a sacrificial template for atomic layer deposition and create free-standing nanolattices. The final structure consists of a combination of nanolattice, upon which controlled deposition of opal structures is achieved. These structures result in nanostructured materials with high porosity, which is essential to create low-index materials for nanophotonics. A thick layer of titanium oxide with high refractive index is deposited over nanolattices to demonstrate the mechanical stability of underlying structures. These nanolattice structures with precisely controlled height can serve as a low-index layer and can find applications in Bragg reflectors, nanophotonics, and optical multilayers.
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Abstract The fabrication of periodic 3D nanostructures with uniform material properties has been widely investigated and is important for applications in photonics, mechanics, and energy storage. However, creating nanostructures with spatially varying lattice geometry and material composition is still largely an unexplored challenge in nanofabrication. This work presents the fabrication of non‐uniform nanolattices by patterning multiple layers of 3D nanostructures using phase shift lithography and atomic layer deposition. By controlling the processing parameters, the lattice geometry and material composition of each individual nanolattice layer can be tailored to create arbitrary material property profiles. Using the proposed method, a five‐layer nanolattice with spatially varying porosity and oxide materials has been demonstrated. This process can be used to create gradient‐index antireflection nanostructures, and a fabricated four‐layer nanolattice structure consisting of TiO2and Al2O3with gradually varying porosity reduces more than 90% of the specular reflectance from a silicon substrate. By enabling nanolattices with arbitrary profiles in physical properties, the demonstrated technique can find broad applications in nanophotonics, graded filters, energy storage systems, and nanoarchitected films.
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Basal slip along glaciers and ice streams can be significantly modified by external time-dependent forcing, although it is not clear why some systems are more sensitive to tidal stresses. We have conducted a series of laboratory experiments to explore the effect of time varying load point velocity on ice-on-rock friction. Varying the load point velocity induces shear stress forcing, making this an analogous simulation of aspects of ice stream tidal modulation. Ambient pressure, double-direct shear experiments were conducted in a cryogenic servo-controlled biaxial deformation apparatus at temperatures between −2°C and −16°C. In addition to a background, median velocity (1 and 10 μm/s), a sinusoidal velocity was applied to the central sliding sample over a range of periods and amplitudes. Normal stress was held constant over each run (0.1, 0.5 or 1 MPa) and the shear stress was measured. Over the range of parameters studied, the full spectrum of slip behavior from creeping to slow-slip to stick-slip was observed, similar to the diversity of sliding styles observed in Antarctic and Greenland ice streams. Under conditions in which the amplitude of oscillation is equal to the median velocity, significant healing occurs as velocity approaches zero, causing a high-amplitude change in friction. The amplitude of the event increases with increasing period (i.e. hold time). At high normal stress, velocity oscillations force an otherwise stable system to behave unstably, with consistently-timed events during every cycle. Rate-state friction parameters determined from velocity steps show that the ice-rock interface is velocity strengthening. A companion paper describes a method of analyzing the oscillatory data directly. Forward modeling of a sinusoidally-driven slider block, using rate-and-state dependent friction formulation and experimentally derived parameters, successfully predicts the experimental output in all but a few cases.more » « less
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1073/pnas.2201589119
