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Title: Theoretical and Experimental Study of Current from Non-Disintegrable Suspended Particles at a Rotating Disk Electrode

Understanding the current response at an electrode from suspended solid particles in an electrolyte is crucial for developing materials to be used in semi-solid electrodes for energy storage applications. Here, an analytical model is proposed to predict and understand the current response from non-disintegrable solid particles at a rotating disk electrode. The current is shown to be limited by a combination of ion diffusion within the solid particle and the mean residence time of the particle at the rotating disk electrode. This results in a relationship between current and angular frequency ofIω3/4,instead of the classicalIω1/2predicted by Levich theory. Specifically, the current response of Li4Ti5O12(LTO) microparticles suspended in a non-aqueous electrolyte of lithium hexafluorophosphate (LiPF6) in ethylene carbonate: diethyl carbonate (EC:DEC) was determined experimentally and compared favorably with predictions from the proposed analytical model using fitting parameters consistent with the experimental conditions.

 
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NSF-PAR ID:
10361648
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
The Electrochemical Society
Date Published:
Journal Name:
Journal of The Electrochemical Society
Volume:
169
Issue:
1
ISSN:
0013-4651
Page Range / eLocation ID:
Article No. 010519
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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