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1. On the Metallicities and Kinematics of the Circumgalactic Media of Damped Lyα Systems at z ∼ 2.5*

   https://doi.org/10.3847/1538-4357/acd34a  

   Urbano Stawinski, Stephanie M. ; Rubin, Kate H. R. ; Prochaska, J. Xavier ; Hennawi, Joseph F. ; Tejos, Nicolas ; Fumagalli, Michele ; Rafelski, Marc ; Kirby, Evan N. ; Lusso, Elisabeta ; Hafen, Zachary ( July 2023 , The Astrophysical Journal)

   We use medium- and high-resolution spectroscopy of close pairs of quasars to analyze the circumgalactic medium (CGM) surrounding 32 damped Lyαabsorption systems (DLAs). The primary quasar sightline in each pair probes an intervening DLA in the redshift range 1.6 <z_abs< 3.5, such that the secondary sightline probes absorption from Lyαand a large suite of metal-line transitions (including Oi, Cii, Civ, Siii, and Siiv) in the DLA host galaxy’s CGM at transverse distances 24 kpc ≤R_⊥≤ 284 kpc. Analysis of Lyαin the CGM sightlines shows an anticorrelation betweenR_⊥and Hicolumn density (N_HI) with 99.8% confidence, similar to that observed around luminous galaxies. The incidences of Ciiand SiiiwithN> 10¹³cm⁻²within 100 kpc of DLAs are larger by 2σthan those measured in the CGM of Lyman break galaxies (C_f(N_CII) > 0.89 and${\mathrm{C}}_f(N_{\mathrm{Si}\mathrm{II}})={0.75}_{-0.17}^{+0.12}$). Metallicity constraints derived from ionic ratios for nine CGM systems with negligible ionization corrections andN_HI> 10^18.5cm⁻²show a significant degree of scatter (with metallicities/limits across the range$-2.06\lesssim \log Z/Z_{\odot }\lesssim -0.75$), suggesting inhomogeneity in the metal distribution in these environments. Velocity widths of Civλ1548 and low-ionization metal species in the DLA versus CGM sightlines are strongly (>2σ) correlated, suggesting that they trace the potential well of the host halo overR_⊥≲ 300 kpc scales. At the same time, velocity centroids for Civλ1548 differ in DLA versus CGM sightlines by >100 km s⁻¹for ∼50% of velocity components, but few components have velocities that would exceed the escape velocity assuming dark matter host halos of ≥10¹²M_⊙.

    

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2. High pressure raman spectroscopy and X-ray diffraction of K2Ca(CO3)2 bütschliite: multiple pressure-induced phase transitions in a double carbonate

   https://doi.org/10.1007/s00269-023-01262-5  

   Zeff, G. ; Kalkan, B. ; Armstrong, K. ; Kunz, M. ; Williams, Q. ( January 2024 , Physics and Chemistry of Minerals)

   The crystal structure and bonding environment of K₂Ca(CO₃)₂bütschliite were probed under isothermal compression via Raman spectroscopy to 95 GPa and single crystal and powder X-ray diffraction to 12 and 68 GPa, respectively. A second order Birch-Murnaghan equation of state fit to the X-ray data yields a bulk modulus,$${K}_{0}=46.9$$$K_0=46.9$GPa with an imposed value of$${K}_{0}^{\prime}= 4$$$K_0^{\prime }=4$for the ambient pressure phase. Compression of bütschliite is highly anisotropic, with contraction along thec-axis accounting for most of the volume change. Bütschliite undergoes a phase transition to a monoclinicC2/mstructure at around 6 GPa, mirroring polymorphism within isostructural borates. A fit to the compression data of the monoclinic phase yields$${V}_{0}=322.2$$$V_0=322.2$ Å³$$,$$$,$$${K}_{0}=24.8$$$K_0=24.8$GPa and$${K}_{0}^{\prime}=4.0$$$K_0^{\prime }=4.0$using a third order fit; the ability to access different compression mechanisms gives rise to a more compressible material than the low-pressure phase. In particular, compression of theC2/mphase involves interlayer displacement and twisting of the [CO₃] units, and an increase in coordination number of the K⁺ion. Three more phase transitions, at ~ 28, 34, and 37 GPa occur based on the Raman spectra and powder diffraction data: these give rise to new [CO₃] bonding environments within the structure.

    

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3. Dataset of theoretical multinary perovskite oxides

   https://doi.org/10.1038/s41597-023-02127-w  

   Bare, Zachary J. ; Morelock, Ryan J. ; Musgrave, Charles B. ( December 2023 , Scientific Data)

   Perovskite oxides (ternary chemical formula ABO₃) are a diverse class of materials with applications including heterogeneous catalysis, solid-oxide fuel cells, thermochemical conversion, and oxygen transport membranes. However, their multicomponent (chemical formula$${A}_{x}{A}_{1-x}^{\text{'}}{B}_{y}{B}_{1-y}^{\text{'}}{O}_{3}$$$A_x{A}_{1-x}^{\text{'}}{B}_y{B}_{1-y}^{\text{'}}{O}_3$) chemical space is underexplored due to the immense number of possible compositions. To expand the number of computed$${A}_{x}{A}_{1-x}^{{\prime} }{B}_{y}{B}_{1-y}^{{\prime} }{O}_{3}$$$A_x{A}_{1-x}^{\prime }{B}_y{B}_{1-y}^{\prime }{O}_3$compounds we report a dataset of 66,516 theoretical multinary oxides, 59,708 of which are perovskites. First, 69,407$${A}_{0.5}{A}_{0.5}^{{\prime} }{B}_{0.5}{B}_{0.5}^{{\prime} }{O}_{3}$$$A_{0.5}{A}_{0.5}^{\prime }{B}_{0.5}{B}_{0.5}^{\prime }{O}_3$compositions were generated in thea⁻b⁺a⁻Glazer tilting mode using the computationally-inexpensive Structure Prediction and Diagnostic Software (SPuDS) program. Next, we optimized these structures with density functional theory (DFT) using parameters compatible with the Materials Project (MP) database. Our dataset contains these optimized structures and their formation (ΔH_f) and decomposition enthalpies (ΔH_d) computed relative to MP tabulated elemental references and competing phases, respectively. This dataset can be mined, used to train machine learning models, and rapidly and systematically expanded by optimizing more SPuDS-generated$${A}_{0.5}{A}_{0.5}^{{\prime} }{B}_{0.5}{B}_{0.5}^{{\prime} }{O}_{3}$$$A_{0.5}{A}_{0.5}^{\prime }{B}_{0.5}{B}_{0.5}^{\prime }{O}_3$perovskite structures using MP-compatible DFT calculations.

    

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4. Forming molecular states with hadronic rescattering

   https://doi.org/10.1140/epja/s10050-021-00650-1  

   Ilten, Philip ; Utheim, Marius ( January 2022 , The European Physical Journal A)

   A method for modelling the prompt production of molecular states using the hadronic rescattering framework of the general-purpose Pythia event generator is introduced. Production cross sections of possible exotic hadronic molecules via hadronic rescattering at the LHC are calculated for the$$\chi _{c1}(3872)$$${\chi }_{c1}\left(3872\right)$resonance, a possible tetraquark state, as well as three possible pentaquark states,$$P_c^+(4312)$$$P_c^{+}\left(4312\right)$,$$P_c^+(4440)$$$P_c^{+}\left(4440\right)$, and$$P_c^+(4457)$$$P_c^{+}\left(4457\right)$. For the$$P_c^+$$$P_c^{+}$states, the expected cross section from$$\Lambda _b$$${\Lambda }_b$decays is compared to the hadronic-rescattering production. The$$\chi _{c1}(3872)$$${\chi }_{c1}\left(3872\right)$cross section is compared to the fiducial$$\chi _{c1}(3872)$$${\chi }_{c1}\left(3872\right)$cross-section measurement by LHCb and found to contribute at a level of$${\mathcal {O}({1\%})}$$$O\left(1\%\right)$. Finally, the expected yields of$$\mathrm {P_c^{+}}$$$P_c^{+}$production from hadronic rescattering during Run 3 of LHCb are estimated. The prompt background is found to be significantly larger than the prompt$$\mathrm {P_c^{+}}$$$P_c^{+}$signal from hadronic rescattering.

    

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5. The Direct-method Oxygen Abundance of Typical Dwarf Galaxies at Cosmic High Noon∗

   https://doi.org/10.3847/1538-4357/acb153  

   Gburek, Timothy ; Siana, Brian ; Alavi, Anahita ; Emami, Najmeh ; Richard, Johan ; Freeman, William R. ; Stark, Daniel P. ; Snapp-Kolas, Christopher ( May 2023 , The Astrophysical Journal)

   We present a Keck/MOSFIRE rest-optical composite spectrum of 16 typical gravitationally lensed star-forming dwarf galaxies at 1.7 ≲z≲ 2.6 (z_mean= 2.30), all chosen independent of emission-line strength. These galaxies have a median stellar mass of$\log {(M_{*}/M_{\odot })}_{\mathrm{med}}={8.29}_{-0.43}^{+0.51}$and a median star formation rate of${\mathrm{S}\mathrm{F}\mathrm{R}}_{\mathrm{H}\alpha }^{\mathrm{m}\mathrm{e}\mathrm{d}}={2.25}_{-1.26}^{+2.15}{M}_{\odot }{\mathrm{y}\mathrm{r}}^{-1}$. We measure the faint electron-temperature-sensitive [Oiii]λ4363 emission line at 2.5σ(4.1σ) significance when considering a bootstrapped (statistical-only) uncertainty spectrum. This yields a direct-method oxygen abundance of$12+\log {(\mathrm{O}/\mathrm{H})}_{\mathrm{direct}}={7.88}_{-0.22}^{+0.25}$(${0.15}_{-0.06}^{+0.12}{Z}_{\odot }$). We investigate the applicability at highzof locally calibrated oxygen-based strong-line metallicity relations, finding that the local reference calibrations of Bian et al. best reproduce (≲0.12 dex) our composite metallicity at fixed strong-line ratio. At fixedM_*, our composite is well represented by thez∼ 2.3 direct-method stellar mass—gas-phase metallicity relation (MZR) of Sanders et al. When comparing to predicted MZRs from the IllustrisTNG and FIRE simulations, having recalculated our stellar masses with more realistic nonparametric star formation histories$(\log {(M_{*}/M_{\odot })}_{\mathrm{med}}={8.92}_{-0.22}^{+0.31})$, we find excellent agreement with the FIRE MZR. Our composite is consistent with no metallicity evolution, at fixedM_*and SFR, of the locally defined fundamental metallicity relation. We measure the doublet ratio [Oii]λ3729/[Oii]λ3726 = 1.56 ± 0.32 (1.51 ± 0.12) and a corresponding electron density of$n_e=1_{-0}^{+215}{\mathrm{cm}}^{-3}$($n_e=1_{-0}^{+74}{\mathrm{cm}}^{-3}$) when considering the bootstrapped (statistical-only) error spectrum. This result suggests that lower-mass galaxies have lower densities than higher-mass galaxies atz∼ 2.

    

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