The structure and bonding of a Pr‐doped boron cluster (PrB7−) are investigated using photoelectron spectroscopy and quantum chemistry. The adiabatic electron detachment energy of PrB7−is found to be low [1.47(8) eV]. A large energy gap is observed between the first and second detachment features, indicating a highly stable neutral PrB7. Global minimum searches and comparison between experiment and theory show that PrB7−has a half‐sandwich structure with C6vsymmetry. Chemical bonding analyses show that PrB7−can be viewed as a PrII[η7‐B73−] complex with three unpaired electrons, corresponding to a Pr (4f26s1) open‐shell configuration. Upon detachment of the 6s electron, the neutral PrB7cluster is a highly stable PrIII[η7‐B73−] complex with Pr in its favorite +3 oxidation state. The B73−ligand is found to be highly stable and doubly aromatic with six delocalized π and six delocalized σ electrons and should exist for a series of lanthanide MIII[η7‐B73−] complexes.
The absolute total cross sections for the charge exchange between highly charged ions15N7+, O7+, and atomic H have been measured with the ion-atom merged-beams apparatus at Oak Ridge National Laboratory. The collision energy range is from 1224 down to 2 eV u−1, which covers outflowing hot components of astrophysical charge exchange plasmas like stellar-wind and supernova remnants. Good agreement with the previous measurements and theory is found for the collision energies above 100 eV u−1, while below 100 eV u−1limited agreement is achieved with the available calculations. These cross-section data are useful for modeling X-ray emission resulting from the charge exchange at the interface of hot plasma interacting with ambient neutral gas.
more » « less- PAR ID:
- 10367192
- Publisher / Repository:
- DOI PREFIX: 10.3847
- Date Published:
- Journal Name:
- The Astrophysical Journal
- Volume:
- 931
- Issue:
- 1
- ISSN:
- 0004-637X
- Format(s):
- Medium: X Size: Article No. 1
- Size(s):
- Article No. 1
- Sponsoring Org:
- National Science Foundation
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