With the aim of constructing hydrogen‐bonding networks in synthetic complexes, two new ligands derived from
Two‐coordinate carbene Cu(Ι) amide complexes with sterically bulky groups such as the diisopropyl phenyl (dipp) on the carbenes have been shown to have comparable performance to the phosphorescent emitters bearing heavy atoms such as iridium and platinum. These bulky groups enforce a coplanar molecular structure and suppress the nonradiative decay rates. Here, three different two‐coordinate Cu(Ι) complexes were investigated that bear a common thiazole carbene, 3‐(2,6‐diisopropylphenyl)‐4,5‐dimethylthiazol‐2‐ylidene, with only a single dipp group, and carbazolyl ligands with substituents of varying steric bulk
- Award ID(s):
- 2018740
- NSF-PAR ID:
- 10367621
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Applied Organometallic Chemistry
- ISSN:
- 0268-2605
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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