Several Ba−Li−Ge ternary phases are known and structurally characterized, including the title compound Ba2LiGe3. Its structure is reported to contain [Ge6]10−anions that exhibit delocalized bonding with a Hückel‐like aromatic character. The Ge atoms are in the same plane with the Li atoms, and if both types of atoms are considered as covalently bonded, [LiGe3]4−honeycomb‐like layers will result. The latter are separated by slabs of Ba2+cations. However, based on the systematic work detailed herein, it is necessary to re‐evaluate the phase as Ba2Li1−
3‐Hydroxypiperidinium pentaiodide was synthesized by a facile reaction in concentrated aqueous HI. Its crystal structure comprises 3‐hydroxypiperidinium cations and pentaiodide anions, the latter having geometry of
- Award ID(s):
- 1955585
- NSF-PAR ID:
- 10369756
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Zeitschrift für anorganische und allgemeine Chemie
- Volume:
- 648
- Issue:
- 15
- ISSN:
- 0044-2313
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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