In this paper, we report the development of tailored 3D-structured (engineered) polymer-metal interfaces to create enhanced 'engineered ionic polymer metal composite' (eIPMC) sensors towards soft, self-powered, high sensitivity strain sensor applications. We introduce a novel advanced additive manufacturing approach to tailor the morphology of the polymer-electrode interfaces via inkjet-printed polymer microscale features. We hypothesize that these features can promote inhomogeneous strain within the material upon the application of external pressure, responsible for improved compression sensing performance. We formalize a minimal physics-based chemoelectromechanical model to predict the linear sensor behavior of eIPMCs in both open-circuit and short-circuit sensing conditions. The model accounts for polymer-electrode interfacial topography to define the inhomogeneous mechanical response driving electrochemical transport in the eIPMC. Electrochemical experiments demonstrate improved electrochemical properties of the inkjet-printed eIPMCs as compared to the standard IPMC sensors fabricated from Nafion polymer sheets. Similarly, compression sensing results show a significant increase in sensing performance of inkjet-printed eIPMC. We also introduce two alternative methods of eIPMC fabrication for sub-millimeter features, namely filament-based fused-deposition manufacturing and stencil printing, and experimentally demonstrate their improved sensing performance. Our results demonstrate increasing voltage output associated to increasing applied mechanical pressure and enhanced performance of the proposed eIPMC sensors against traditional IPMC based compression sensors.
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3D Printed MXene Aerogels with Truly 3D Macrostructure and Highly Engineered Microstructure for Enhanced Electrical and Electrochemical Performance
Assembling 2D materials such as MXenes into functional 3D aerogels using 3D printing technologies gains attention due to simplicity of fabrication, customized geometry and physical properties, and improved performance. Also, the establishment of straightforward electrode fabrication methods with the aim to hinder the restack and/or aggregation of electrode materials, which limits the performance of the electrode, is of great significant. In this study, unidirectional freeze casting and inkjet‐based 3D printing are combined to fabricate macroscopic porous aerogels with vertically aligned Ti3C2T
- NSF-PAR ID:
- 10375727
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Materials
- Volume:
- 34
- Issue:
- 2
- ISSN:
- 0935-9648
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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In this paper, we report the development of tailored 3D-structured (engineered) polymer-metal interfaces to create enhanced ‘engineered ionic polymer metal composite’ (eIPMC) sensors towards soft, self-powered, high sensitivity strain sensor applications. We introduce a novel advanced additive manufacturing approach to tailor the morphology of the polymer-electrode interfaces via inkjet-printed polymer microscale features. We hypothesize that these features can promote inhomogeneous strain within the material upon the application of external pressure, responsible for improved compression sensing performance. We formalize a minimal physics-based chemoelectromechanical model to predict the linear sensor behavior of eIPMCs in both open-circuit and short-circuit sensing conditions. The model accounts for polymer-electrode interfacial topography to define the inhomogeneous mechanical response driving electrochemical transport in the eIPMC. Electrochemical experiments demonstrate improved electrochemical properties of the inkjet-printed eIPMCs as compared to the standard IPMC sensors fabricated from Nafion polymer sheets. Similarly, compression sensing results show a significant increase in sensing performance of inkjet-printed eIPMC. We also introduce two alternative methods of eIPMC fabrication for sub-millimeter features, namely filament-based fused-deposition manufacturing and stencil printing, and experimentally demonstrate their improved sensing performance. Our results demonstrate increasing voltage output associated to increasing applied mechanical pressure and enhanced performance of the proposed eIPMC sensors against traditional IPMC based compression sensors.more » « less
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Abstract Aerogels are highly porous structures produced by replacing the liquid solvent of a gel with air without causing a collapse in the solid network. Unlike conventional fabrication methods, additive manufacturing (AM) has been applied to fabricate 3D aerogels with customized geometries specific to their applications, designed pore morphologies, multimaterial structures, etc. To date, three major AM technologies (extrusion, inkjet, and stereolithography) followed by a drying process have been proposed to additively manufacture 3D functional aerogels. 3D‐printed aerogels and porous scaffolds showed great promise for a variety of applications, including tissue engineering, electrochemical energy storage, controlled drug delivery, sensing, and soft robotics. In this review, the details of steps included in the AM of aerogels and porous scaffolds are discussed, and a general frame is provided for AM of those. Then, the different postprinting processes are addressed to achieve the porosity (after drying); and mechanical strength, functionality, or both (after postdrying thermal or chemical treatments) are provided. Furthermore, the applications of the 3D‐printed aerogels/porous scaffolds made from a variety of materials are also highlighted. The review is concluded with the current challenges and an outlook for the next generation of 3D‐printed aerogels and porous scaffolds.
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Abstract MXenes are 2D materials with relatively high surface areas, high electrical conductivities, functional transition metal surfaces, tunable surface chemistries, and solution processability. Due to these properties, 2D MXenes have attracted widespread attention as electrode materials for energy storage devices, including electrochemical capacitors, with high power and energy densities. However, many studies have shown that the electrochemical performance of MXene electrodes is considerably affected by their structure and morphology. These properties are, for the most part, controlled by the method used for the assembly of 2D MXene flakes and the electrode fabrication methods. A successful electrode assembly and fabrication method should address several challenges, such as the restacking of 2D flakes, to achieve electrode structures and morphologies that deliver high ionic transport properties, electrical conductivity, and mechanical stability. This review aims to provide insight into the current state‐of‐the‐art assembly and fabrication methods used to design and fabricate high performance electrodes based on MXenes. The major challenges to be addressed and possible future directions in the fabrication of MXene electrodes for practical energy storage applications are highlighted.
