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1. Resolving puzzles of the phase-transformation-based mechanism of the deep-focus earthquake

   Levitas, Valery I. (October 2021, ArXivorg)

   Deep-focus earthquakes that occur at 350–660 km, where pressures p =12-23 GPa and temperature T =1800-2000 K, are generally assumed to be caused by olivine→spinel phase transformation, see pioneering works [1–10]. However, there are many existing puzzles: (a) What are the mechanisms for jump from geological 10−17−10−15 s−1 to seismic 10−103s−1(see [3]) strain rates? Is it possible without phase transformation? (b) How does metastable olivine, which does not completely transform to spinel at high temperature and deeply in the region of stability of spinel for over the million years, suddenly transforms during seconds and generates seismic strain rates 10−103s−1 that produce strong seismic waves? (c) How to connect deviatorically dominated seismic signals with volume-change dominated transformation strain during phase transformations [9,11]? Here we introduce a combination of several novel concepts that allow us to resolve the above puzzles quantitatively. We treat the transformation in olivine like plastic strain-induced (instead of pressure/stress-induced) and find an analytical 3D solution for coupled deformation-transformation-heating processes in a shear band. This solution predicts conditions for severe (singular) transformation-induced plasticity (TRIP) and self-blown-up deformation-transformation-heating process due to positive thermomechanochemical feedback between TRIP and strain-induced transformation. In nature, this process leads to temperature in a band exceeding the unstable stationary temperature, above which the self-blown-up shear-heating process in the shear band occurs after finishing the phase transformation. Without phase transformation and TRIP, significant temperature and strain rate increase is impossible. Due to the much smaller band thickness in the laboratory, heating within the band does not occur, and plastic flow after the transformation is very limited. Our findings change the main concepts in studying the initiation of the deep-focus earthquakes and phase transformations during plastic flow in geophysics in general. The latter may change the interpretation of different geological phenomena, e.g., the possibility of the appearance of microdiamond directly in the cold Earth crust within shear-bands [12] during tectonic activities without subduction to the mantle and uplifting. Developed theory of the self-blown-up transformation-TRIP-heating process is applicable outside geophysics for various processes in materials under pressure and shear, e.g., for new routes of material synthesis [12,13], friction and wear, surface treatment, penetration of the projectiles and meteorites, and severe plastic deformation and mechanochemical technologies. 

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2. Severe Strain‐Induced Olivine‐Ringwoodite Transformation at Room Temperature: Key to Enigmas of Deep‐Focus Earthquake

   https://doi.org/10.1029/2024GL111281  

   Lin, F.; Levitas, V_I; Yesudhas, S.; Dhar, A.; Smith, J. (March 2025, Geophysical Research Letters)

   Abstract Deep‐focus earthquakes at 350–660 km are presumably caused by olivine‐spinel phase transformation (PT). This cannot, however, explain the observed high seismic strain rate, which requires PT to complete within seconds, while metastable olivine does not transform for over a million years. Recent theory quantitatively describes how severe plastic deformations (SPD) can solve this dilemma but lacking experimental proof. Here, we introduce dynamic rotational diamond anvil cell with rough diamond anvils to impose SPD on San Carlos olivine. While olivine never transformed to spinel at room temperature, we obtained reversible olivine‐ringwoodite PT under SPD at 15–28 GPa within tens of seconds. The PT pressure reduces with increasing dislocation density, microstrain, plastic strain, and decreasing crystallite size. Results demonstrate a new strain‐induced PT mechanism compared to a pressure/temperature‐induced one. Combined with SPD during olivine subduction, this mechanism can accelerate olivine‐ringwoodite PT from millions of years to timescales relevant to earthquakes. 

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3. In situ quantitative study of plastic strain-induced phase transformations under high pressure: Example for ultra-pure Zr.

   Pandey, K. K.; Levitas, V. I. (February 2020, ArXivorg)

   The first in situ quantitative synchrotron X-ray diffraction (XRD) study of plastic strain-induced phase transformation (PT) has been performed on $$\alpha-\omega$$ PT in ultra-pure, strongly plastically predeformed Zr as an example, under different compression-shear pathways in rotational diamond anvil cell (RDAC). Radial distributions of pressure in each phase and in the mixture, and concentration of $$\omega$$-Zr, all averaged over the sample thickness, as well as thickness profile were measured. The minimum pressure for the strain-induced $$\alpha-\omega$$ PT, $$p^d_{\varepsilon}$$=1.2 GPa, is smaller than under hydrostatic loading by a factor of 4.5 and smaller than the phase equilibrium pressure by a factor of 3; it is independent of the compression-shear straining path. The theoretically predicted plastic strain-controlled kinetic equation was verified and quantified; it is independent of the pressure-plastic strain loading path and plastic deformation at pressures below $$p^d_{\varepsilon}$$. Thus, strain-induced PTs under compression in DAC and torsion in RDAC do not fundamentally differ. The yield strength of both phases is estimated using hardness and x-ray peak broadening; the yield strength in shear is not reached by the contact friction stress and cannot be evaluated using the pressure gradient. Obtained results open a new opportunity for quantitative study of strain-induced PTs and reactions with applications to material synthesis and processing, mechanochemistry, and geophysics. 

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4. Evidence for a Deep Hydrologic Cycle on Oceanic Transform Faults

   https://doi.org/10.1029/2019JB017751  

   Kohli, Arjun H.; Warren, Jessica M. (February 2020, Journal of Geophysical Research: Solid Earth)

   Abstract Oceanic transform faults represent abundant yet relatively unexplored components of the hydrologic cycle in the mantle lithosphere. Current models limit fluid circulation to 600 °C, the thermal limit of earthquakes recorded by teleseismic surveys. However, recent ocean‐bottom seismic surveys have located earthquakes at depths corresponding to >1000 °C in modeled thermal structure. To constrain the depth extent of brittle deformation and fluid infiltration, we analyzed peridotite mylonites dredged from the Shaka Transform Fault, Southwest Indian Ridge. Samples range from high strain mylonites that preserve ductile microstructures to lower strain mylonites that are fractured and overprinted by hydrothermal alteration. Microstructural analysis of the high strain samples reveals brittle deformation of pyroxene concomitant with ductile deformation of olivine and growth of amphibole. Porphyroclasts preserve healed fractures filled with fluid inclusions, implying repeated episodes of fracture, fluid infiltration, and healing. The association of hydration features with brittle structures points to seawater, rather than melt, as the fluid source. Textural analysis indicates that strain localization was initiated by grain boundary pinning and that olivine grain size was reduced to ~1 μm in the presence of amphibole. Comparing the amphibole stability field to thermometry estimates for the limit of recrystallization suggests that fluid flow extended to ~650–850 °C. Our results indicate that the hydrologic cycle extends past the brittle‐ductile transition and promotes strain localization via hydrolytic weakening and hydration reactions. We propose that seawater infiltration on oceanic transform faults is driven by the seismic cycle and represents a first order control on the rheology of the oceanic lithosphere. 

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5. Numerical Investigation Into Mechanical Behavior of Metastable Olivine During Phase Transformation: Implications for Deep‐Focus Earthquakes

   https://doi.org/10.1029/2024JB030557  

   Sindhusuta, S; Chi, Sheng‐Wei; Foster, Craig; Officer, Timothy; Wang, Yanbin (February 2025, Journal of Geophysical Research: Solid Earth)

   Abstract One hypothesized mechanism that triggers deep‐focus earthquakes in oceanic subducting slabs below ∼300 km depth is transformational faulting due to the olivine‐to‐spinel phase transition. This study uses finite element modeling to investigate phase transformation‐induced stress redistribution and material weakening in olivine. A thermodynamically consistent constitutive model is developed to capture the evolution of phase transformation in olivine under different pressure and temperature conditions. The overall numerical model enables considering multiscale material features, including the polycrystalline structure, mesoscale heterogeneity, and various phases or variants of phases at the microscopic level, and accounts for viscoplastic behaviors with thermo‐mechanical coupling effects. The model is validated with several benchmarks, including a phase diagram of phase transformation from olivine to spinel. The validated model is used to study the interactive behaviors between defects (heterogeneity) and phase transformation. The simulation results reveal that spinel formation under pressure initiates near inclusions and along the grain boundaries, consistent with experimental observations. At lower temperatures, the transformation leads to the formation of thin conjugate bands of spinel diagonal to the compression loading direction. Local stress analysis along these bands also suggests the initiation of faulting. In contrast, the numerical results at higher transformation rates show that significant spinel formation occurs over a larger area at elevated temperatures, leading to ductile behavior, which agrees with experimental findings. Numerical simulation of multiple inclusions under confined pressure also shows the formation of a network of spinel bands resembling phase‐transformation patterns observed in the laboratory experiments. Additionally, stress softening patterns due to phase transformation are similar to experimental observations. 

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