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Title: Crosslinked organosulfur-based self-assembled monolayers: formation and applications
Self-assembled monolayers (SAMs) have found use in diverse applications that range from corrosion prevention to biosensing. However, for all of these applications, stability remains a key challenge for the utilization of SAMs. Over the last decade, intermolecular crosslinking as a method to enhance the thermal and chemical stability of SAMs has attracted increased attention from scientists and engineers. As such, this review introduces a variety of crosslinked SAMs: (1) aromatic thiol-based SAMs; (2) olefinic- and acetylenic-based alkanethiols; (3) other aliphatic alkanethiols; (4) silane-based alkanethiols; (5) boronic acid-based alkanethiols; and (6) crosslinked SAMs realized by hydrogen bonding. By offering insight into the structure-application relationships of the aforementioned SAMs, this review seeks to inspire researchers toward the development of new classes of SAMs with enhanced stabilities and working lifetimes.  more » « less
Award ID(s):
2109174
PAR ID:
10377938
Author(s) / Creator(s):
; ; ;
Publisher / Repository:
Soft Science
Date Published:
Journal Name:
Soft Science
Volume:
2
Issue:
2
ISSN:
2769-5441
Page Range / eLocation ID:
5
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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