skip to main content

Title: C60 cation as the carrier of the λ 9577 Å and λ 9632 Å diffuse interstellar bands: further support from the VLT/X-Shooter spectra
ABSTRACT

Ever since they were first detected over 100 yr ago, the mysterious diffuse interstellar bands (DIBs), a set of several hundred broad absorption features seen against distant stars in the optical and near-infrared wavelength range, largely remain unidentified. The close match, both in wavelengths and in relative strengths, recently found between the experimental absorption spectra of gas-phase buckminsterfullerene ions (C$_{60}^{+}$) and four DIBs at $\lambda 9632\, {\rm \mathring{\rm A}}$, $\lambda 9577\, {\rm \mathring{\rm A}}$, $\lambda 9428\, {\rm \mathring{\rm A}}$ and $\lambda 9365\, {\rm \mathring{\rm A}}$ (and, to a lesser degree, a weaker DIB at $\lambda 9348\, {\rm \mathring{\rm A}}$) suggests that C$_{60}^{+}$ is a promising carrier for these DIBs. However, arguments against the C$_{60}^{+}$ identification remain and are mostly concerned with the large variation in the intensity ratios of the $\lambda 9632\, {\rm \mathring{\rm A}}$ and $\lambda 9577\, {\rm \mathring{\rm A}}$ DIBs. In this work, we search for these DIBs in the X-shooter archival data of the European Southern Observatory’s Very Large Telescope, and we identify the $\lambda 9632\, {\rm \mathring{\rm A}}$, $\lambda 9577\, {\rm \mathring{\rm A}}$, $\lambda 9428\, {\rm \mathring{\rm A}}$ and $\lambda 9365\, {\rm \mathring{\rm A}}$ DIBs in a sample of 25 stars. While the $\lambda 9428\, {\rm more » \mathring{\rm A}}$ and $\lambda 9365\, {\rm \mathring{\rm A}}$ DIBs are too noisy to allow any reliable analysis, the $\lambda 9632\, {\rm \mathring{\rm A}}$ and $\lambda 9577\, {\rm \mathring{\rm A}}$ DIBs are unambiguously detected and, after correcting for telluric water vapour absorption, their correlation can be used to probe their origin. To this end, we select a subsample of nine hot, O- or B0-type stars of which the stellar Mg ii contamination to the $\lambda 9632\, {\rm \mathring{\rm A}}$ DIB is negligibly small. We find that their equivalent widths, after being normalized by reddening to eliminate their common correlation with the density of interstellar clouds, exhibit a tight, positive correlation, supporting C$_{60}^{+}$ as the carrier of the $\lambda 9632\, {\rm \mathring{\rm A}}$ and $\lambda 9577\, {\rm \mathring{\rm A}}$ DIBs.

« less
Authors:
; ;
Publication Date:
NSF-PAR ID:
10379843
Journal Name:
Monthly Notices of the Royal Astronomical Society
Volume:
509
Issue:
4
Page Range or eLocation-ID:
p. 4908-4915
ISSN:
0035-8711
Publisher:
Oxford University Press
Sponsoring Org:
National Science Foundation
More Like this
  1. Few anions exhibit electronically excited states, and, if they do, the one or two possible excitations typically transpire beyond the visible spectrum into the near-infrared. These few, red-shifted electronic absorption features make anions tantalizing candidates as carriers of the diffuse interstellar bands (DIBs), a series of mostly unknown, astronomically ubiquitous absorption features documented for over a century. The recent interstellar detection of benzonitrile implies that cyano-functionalized polycyclic aromatic hydrocarbon (PAH) anions may be present in space. The presently reported quantum chemical work explores the electronic properties of deprotonated benzene, naphthalene, and anthracene anions functionalized with a single cyano group. Both the absorption and emission properties of the electronically excited states are explored. The findings show that the larger anions absorption and emission energies possess both valence and dipole bound excitations in the 450–900 nm range with oscillator strengths for both types of >1×10−4. The valence and dipole bound excited state transitions will produce slightly altered substructure from one another making them appear to originate with different molecules. The known interstellar presence of related molecules, the two differing natures of the excited states for each, and the wavelength range of peaks for these cyano-functionalized PAH anions are coincident with DIB properties.more »Finally, the methods utilized appear to be able to predict the presence of dipole-bound excited states to within a 1.0 meV window relative to the electron binding energy.« less
  2. ABSTRACT

    We present an axi-symmetric model for the ultraviolet (UV)-to-submillimetre (submm) images of the nearly face-on spiral galaxy NGC 628. It was calculated using a radiative transfer (RT) code, accounting for the absorption and re-emission of starlight by dust in the interstellar medium of this galaxy. The code incorporates emission from Polycyclic Aromatic Hydrocarbons, anisotropic scattering, and stochastic heating of the grains. This is the second successful modelling of a face-on spiral galaxy with RT methods, whereby the large-scale geometry of stars and dust is self-consistently determined. The solution was obtained by fitting azimuthally averaged profiles in the UV, optical, and submm. The model predicts remarkably well all characteristics of the profiles, including the increase by a factor of 1.8 of the scale length of the infrared emissivity between 70 and 500 $\mu$m. We find that NGC 628 did not undergo an efficient inside-out disc growth, as predicted by semi-analytical hierarchical models for galaxy formation. We also find large amounts of dust grains at large radii, which could involve efficient transport mechanisms from the inner disc. Our results show that $71{{\ \rm per\ cent}}$ of the dust emission in NGC 628 is powered by the young stellar populations, with the old stellar populations frommore »the bulge contributing $65{{\ \rm per\ cent}}$ to the heating of the dust in the central region (R < 0.5 kpc). The derived star formation rate is $\rm SFR=2.00\pm 0.15\, {\rm M}_{\odot }{\rm yr}^{-1}$.

    « less
  3. ABSTRACT

    Current observations favour that the massive ultraviolet-bright clumps with a median stellar mass of $\sim 10^7\, {\rm M}_{\odot }$, ubiquitously observed in z ∼ 1–3 galaxies, are star-forming regions formed in situ in galaxies. It has been proposed that they result from gas fragmentation due to gravitational instability of gas-rich, turbulent, and high-redshift discs. We bring support to this scenario by reporting the new discovery of giant molecular clouds (GMCs) in the strongly lensed, clumpy, main-sequence galaxy, A521-sys1, at z = 1.043. Its CO(4–3) emission was mapped with the Atacama Large Millimetre/submillimetre Array (ALMA) at an angular resolution of 0.19 × 0.16 arcsec2, reading down to 30 pc, thanks to gravitational lensing. We identified 14 GMCs, most being virialized, with $10^{5.9}-10^{7.9}\, {\rm M}_{\odot }$ masses and a median $800\, {\rm M}_{\odot }~\mathrm{pc}^{-2}$ molecular gas mass surface density, that are, respectively, 100 and 10 times higher than for nearby GMCs. They are also characterized by 10 times higher supersonic turbulence with a median Mach number of 60. They end up to fall above the Larson scaling relations, similarly to the GMCs in another clumpy z ≃ 1 galaxy, the Cosmic Snake, although differences between the two sets of high-redshift GMCs exist. Altogether theymore »support that GMCs form with properties that adjust to the ambient interstellar medium conditions prevalent in the host galaxy whatever its redshift. The detected A521-sys1 GMCs are massive enough to be the parent gas clouds of stellar clumps, with a relatively high star formation efficiency per free-fall time of ∼11 per cent.

    « less
  4. Abstract

    We present the discovery of neutral gas detected in both damped Lyαabsorption (DLA) and Hi21 cm emission outside of the stellar body of a galaxy, the first such detection in the literature. A joint analysis between the Cosmic Ultraviolet Baryon Survey and the MeerKAT Absorption Line Survey reveals an Hibridge connecting two interacting dwarf galaxies (log (Mstar/M) = 8.5 ± 0.2) that host az= 0.026 DLA with log[N(Hi)/cm−2] = 20.60 ± 0.05 toward the QSO J2339−5523 (zQSO= 1.35). At impact parameters ofd= 6 and 33 kpc, the dwarf galaxies have no companions more luminous than ≈0.05L*within at least Δv= ±300 km s−1andd≈ 350 kpc. The Hi21 cm emission is spatially coincident with the DLA at the 2σ–3σlevel per spectral channel over several adjacent beams. However, Hi21 cm absorption is not detected against the radio-bright QSO; if the background UV and radio sources are spatially aligned, the gas is either warm or clumpy (with a spin temperature to covering factor ratioTs/fc> 1880 K). Observations with VLT-MUSE demonstrate that theα-element abundance of the ionized interstellar medium (ISM) is consistent with the DLA (≈10% solar), suggesting that the neutral gas envelope is perturbed ISM gas. This study showcases the impact of dwarf–dwarfmore »interactions on the physical and chemical state of neutral gas outside of star-forming regions. In the SKA era, joint UV and Hi21 cm analyses will be critical for connecting the cosmic neutral gas content to galaxy environments.

    « less
  5. ABSTRACT The detection of the 11.3$\, {\rm \mu m}$ emission feature characteristic of the Si–C stretch in carbon-rich evolved stars reveals that silicon carbide (SiC) dust grains are condensed in the outflows of carbon stars. SiC dust could be a significant constituent of interstellar dust since it is generally believed that carbon stars inject a considerable amount of dust into the interstellar medium (ISM). The presence of SiC dust in the ISM is also supported by the identification of pre-solar SiC grains of stellar origin in primitive meteorites. However, the 11.3$\,\mu {\rm m}$ absorption feature of SiC has never been seen in the ISM, and oxidative destruction of SiC is often invoked. In this work, we quantitatively explore the destruction of interstellar SiC dust through oxidation based on molecular dynamics simulations and density functional theory calculations. We find that the reaction of an oxygen atom with SiC molecules and clusters is exothermic and could cause CO-loss. Nevertheless, even if this is extrapolable to bulk SiC dust, the destruction rate of SiC dust through oxidation could still be considerably smaller than the (currently believed) injection rate from carbon stars. Therefore, the lack of the 11.3$\,\mu{\rm m}$ absorption feature of SiC dustmore »in the ISM remains a mystery. A possible solution may lie in the currently believed stellar injection rate of SiC (which may have been overestimated) and/or the size of SiC dust (which may actually be considerably smaller than submicron in size).« less