More Like this

1. Ligand‐Based Control of Single‐Site vs. Multi‐Site Reactivity by a Trichromium Cluster

   https://doi.org/10.1002/ange.201901599  

   Bartholomew, Amymarie K.; Juda, Cristin E.; Nessralla, Jonathon N.; Lin, Benjamin; Wang, SuYin Grass; Chen, Yu‐Sheng; Betley, Theodore A. (March 2019, Angewandte Chemie)

   Abstract The trichromium cluster (^tbsL)Cr₃(thf) ([^tbsL]⁶⁻=[1,3,5‐C₆H₉(NC₆H₄‐o‐NSi^tBuMe₂)₃]⁶⁻) exhibits steric‐ and solvation‐controlled reactivity with organic azides to form three distinct products: reaction of (^tbsL)Cr₃(thf) with benzyl azide forms a symmetrized bridging imido complex (^tbsL)Cr₃(μ³‐NBn); reaction with mesityl azide in benzene affords a terminally bound imido complex (^tbsL)Cr₃(μ¹‐NMes); whereas the reaction with mesityl azide in THF leads to terminal N‐atom excision from the azide to yield the nitride complex (^tbsL)Cr₃(μ³‐N). The reactivity of this complex demonstrates the ability of the cluster‐templating ligand to produce a well‐defined polynuclear transition metal cluster that can access distinct single‐site and cooperative reactivity controlled by either substrate steric demands or reaction media. 

   more » « less
2. Intercalating Helium into A-Site Vacant Perovskites

   https://doi.org/10.1021/acs.chemmater.3c00353  

   Racioppi, Stefano; Miao, Maosheng; Zurek, Eva (June 2023, Chemistry of Materials)
3. Toric Spines at a Site of Learning

   https://doi.org/10.1523/ENEURO.0197-19.2019  

   Sanculi, Daniel; Pannoni, Katherine E.; Bushong, Eric A.; Crump, Michael; Sung, Michelle; Popat, Vyoma; Zaher, Camilia; Hicks, Emma; Song, Ashley; Mofakham, Nikan; et al (January 2020, eneuro)

   null (Ed.)
4. Empirical Evidence for A-Site Order in Perovskites

   https://doi.org/10.1111/jace.14547  

   Tolman, Kevin; Ubic, Rick; Liu, Bing; Williamson, Izaak; Bedke, Katherine; Nelson, Eric B.; Li, Lan; Chen, Xiang Ming; Dickey, E. (January 2017, Journal of the American Ceramic Society)
5. Site U1473

   https://doi.org/10.14379/iodp.proc.360.103.2017  

   MacLeod, C; Dick, H; Blum, P; Abe, N; Blackman, D; Bowles, J; Cheadle, M; Cho, K; Ciazela, J; Deans, J; et al (January 2017, Proceedings of the International Ocean Discovery Program)

   null (Ed.)

   This is the site description for U1473 at Atlantis Bank 

   more » « less