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Title: CO organization at ambient pressure on stepped Pt surfaces: first principles modeling accelerated by neural networks
Step and kink sites at Pt surfaces have crucial importance in catalysis. We employ a high dimensional neural network potential (HDNNP) trained using first-principles calculations to determine the adsorption structure of CO under ambient conditions ( T = 300 K and P = 1 atm) on these surfaces. To thoroughly explore the potential energy surface (PES), we use a modified basin hopping method. We utilize the explored PES to identify the adsorbate structures and show that under the considered conditions several low free energy structures exist. Under the considered temperature and pressure conditions, the step edge (or kink) is totally occupied by on-top CO molecules. We show that the step structure and the structure of CO molecules on the step dictate the arrangement of CO molecules on the lower terrace. On surfaces with (111) steps, like Pt(553), CO forms quasi-hexagonal structures on the terrace with the top site preferred, with on average two top site CO for one multiply bonded CO, while in contrast surfaces with (100) steps, like Pt(557), present a majority of multiply bonded CO on their terrace. Short terraced surfaces, like Pt(643), with square (100) steps that are broken by kink sites constrain the CO arrangement parallel to the step edge. Overall, this effort provides detailed analysis on the influence of the step edge structure, kink sites, and terrace width on the organization of CO molecules on non-reconstructed stepped surfaces, yielding initial structures for understanding restructuring events driven by CO at high coverages and ambient pressure.  more » « less
Award ID(s):
1800601
PAR ID:
10380470
Author(s) / Creator(s):
;
Date Published:
Journal Name:
Chemical Science
Volume:
12
Issue:
47
ISSN:
2041-6520
Page Range / eLocation ID:
15543 to 15555
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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