Dioxetane intermediates readily decompose to chemiluminescent triplet carbonyls, giving rise to what has been paradoxically called photochemistry in the dark. In this issue of
Oxygen‐Sensing Chemiluminescent Iridium(III) 1,2‐Dioxetanes: Unusual Coordination and Activity
Next generation chemiluminescent iridium 1,2‐dioxetane complexes have been developed which consist of the Schaap's 1,2‐dioxetane scaffold directly attached to the metal center. This was achieved by synthetically modifying the scaffold precursor with a phenylpyridine moiety, which can act as a ligand. Reaction of this scaffold ligand with the iridium dimer [Ir(BTP)2(μ‐Cl)]2(BTP=2‐(benzo[
- Award ID(s):
- 2155170
- NSF-PAR ID:
- 10381341
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Analysis & Sensing
- Volume:
- 3
- Issue:
- 1
- ISSN:
- 2629-2742
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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