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1. Using Trace Elements in Olivine Phenocrysts to Test Models of Melt Differentiation at Convergent Margins: Constraints from Times Series in Monogenetic Volcanoes in the Central Transmexican Volcanic Belt

   Fleming, W. ; Straub, S.M. ; Gomez-Tuena, A. ; Espinasa-Pereña, R. ; Bindeman, I.N. ; Stuart, F.M. ; Batanova, V.G. ( December 2019 , AGU Fall Meeting 2019)

   Models of subduction zone magmatism ascribe the andesitic composition of arc magmas to crustal processes, such as crustal assimilation and/or fractional crystallization, that basaltic mantle melts experience during their ascent through the upper plate crust. However, results from time series study of olivine-phyric high-Nb basalts and basaltic andesites from two monogenetic arc volcanoes (V. Chichinautzin and Texcal Flow) that are constructed on the ~45 km thick continental basement of the central Transmexican Volcanic Belt (TMVB) are inconsistent with this model. Instead, ratios of radiogenic isotope and incompatible trace elements suggest that these volcanoes were constructed through multiple individual melt batches ascending from a progressively changing mantle source. Moreover, the high Ni contents of the olivine phenocrysts, together with their high mantle-like 3He/4Heoliv =7-8 Ra with high crustal δ18O oliv = +5.5 to +6.5‰ (n=12) point to the presence of secondary ‘reaction pyroxenites’ in the mantle source that create primary silicic arc magmas through melt-rock reaction processes in the mantle [1, 2] . Here we present additional trace element concentration of the high-Ni olivines by electron microprobe (Mn, Ca) and laser-ablation ICPMS (Li, Cr and V) analysis in order to test this model. Olivine Li (2-7 ppm) and Mn (1170- 2810 ppm) increase with decreasing fosterite (Fo89 to Fo75), while Cr (29-364 ppm), V (4-11 ppm) and Ca (825-2390 ppm) decrease. Quantitative modeling shows that these trends in their entirety cannot be controlled by fractional crystallization under variable melt water H2O or oxygen fugacity (fO2), or co-crystallization of Cr-spinel. Instead, the variations support the existence of compositionally distinct melt batches during earliest melt evolution. Moreover, the trace element trends are qualitatively consistent with a model of progressive source depletion by serial melting (shown in olivine Ca, V and Cr) that is triggered by the repetitive addition of silicic slab components (shown by olivine Li). These findings suggest mantle source variations are not eliminated despite the thick crust these magmas pass during ascent. [1] Straub et al. (2013) J Petrol 54 (4): 665-701; [2] Straub et al. (2015) Geochim Cosmochim Acta 166: 29-52. 

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2. Architectural and Tectonic Control on the Segmentation of the Central American Volcanic Arc

   https://doi.org/10.1146/annurev-earth-082420-055108  

   Gazel, Esteban ; Flores, Kennet E. ; Carr, Michael J. ( May 2021 , Annual Review of Earth and Planetary Sciences)

   null (Ed.)

   Central America has a rich mix of conditions that allow comparisons of different natural experiments in the generation of arc magmas within the relatively short length of the margin. The shape of the volcanic front and this margin's architecture derive from the assemblage of exotic continental and oceanic crustal slivers, and later modification by volcanism and tectonic activity. Active tectonics of the Cocos-Caribbean plate boundary are strongly influenced by oblique subduction, resulting in a narrow volcanic front segmented by right steps occurring at ∼150-km intervals. The largest volcanic centers are located where depths to the slab are ∼90–110 km. Volcanoes that develop above deeper sections of the subducting slab are less voluminous and better record source geochemical heterogeneity. Extreme variations in isotopic and trace element ratios are derived from different components of thesubducted oceanic lithosphere. However, the extent that volcanoes sample these signatures is also influenced by lithospheric structures that control the arc segmentation. ▪  The architecture of Central America derives from the assemblage of exotic continental and oceanic crustal slivers modified by arc magmatism and tectonic processes. ▪  Active tectonics in Central America are controlled by oblique subduction. ▪  The lithospheric architecture and tectonics define the segmentation of the volcanic front, and thus the depth to the slab below a volcanic center. ▪  The composition of the subducted material is the main control of the along arc geochemical variations observed in Central American volcanoes. ▪  Geochemical heterogeneity in each segment is highlighted by extreme compositions representing the smaller centers with variations up to 65% of the total observed range. 

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3. Architectural and Tectonic Control on the Segmentation of the Central American Volcanic Arc

   https://doi.org/doi.org/10.1146/annurev-earth-082420-055108  

   Gazel, E. ; Flores, K.E. ; Carr, M.J. ( January 2021 , Annual review of earth and planetary sciences)

   null (Ed.)

   Central America has a rich mix of conditions that allow comparisons of different natural experiments in the generation of arc magmas within the relatively short length of the margin. The shape of the volcanic front and this margin's architecture derive from the assemblage of exotic continental and oceanic crustal slivers, and later modification by volcanism and tectonic activity. Active tectonics of the Cocos-Caribbean plate boundary are strongly influenced by oblique subduction, resulting in a narrow volcanic front segmented by right steps occurring at ?150-km intervals. The largest volcanic centers are located where depths to the slab are ?90?110 km. Volcanoes that develop above deeper sections of the subducting slab are less voluminous and better record source geochemical heterogeneity. Extreme variations in isotopic and trace element ratios are derived from different components of thesubducted oceanic lithosphere. However, the extent that volcanoes sample these signatures is also influenced by lithospheric structures that control the arc segmentation. ?? The architecture of Central America derives from the assemblage of exotic continental and oceanic crustal slivers modified by arc magmatism and tectonic processes. ?? Active tectonics in Central America are controlled by oblique subduction. ?? The lithospheric architecture and tectonics define the segmentation of the volcanic front, and thus the depth to the slab below a volcanic center. ?? The composition of the subducted material is the main control of the along arc geochemical variations observed in Central American volcanoes. ?? Geochemical heterogeneity in each segment is highlighted by extreme compositions representing the smaller centers with variations up to 65% of the total observed range. 

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4. Expedition 366 Preliminary Report: Mariana Convergent Margin and South Chamorro Seamount

   https://doi.org/10.14379/iodp.pr.366.2017  

   Fryer, P. ; Wheat, G. ; Williams, T. ( November 2017 , Preliminary report)

   null (Ed.)

   Geologic processes at convergent plate margins control geochemical cycling, seismicity, and deep biosphere activity in subduction zones and suprasubduction zone lithosphere. International Ocean Discovery Program (IODP) Expedition 366 was designed to address the nature of these processes in the shallow to intermediate depth of the Mariana subduction channel. Although no technology is available to permit direct sampling of the subduction channel of an intraoceanic convergent margin at depths up to 18 km, the Mariana forearc region (between the trench and the active volcanic arc) provides a means to access this zone. Active conduits, resulting from fractures in the forearc, are prompted by along- and across-strike extension that allows slab-derived fluids and materials to ascend to the seafloor along associated faults, resulting in the formation of serpentinite mud volcanoes. Serpentinite mud volcanoes of the Mariana forearc are the largest mud volcanoes on Earth. Their positions adjacent to or atop fault scarps on the forearc are likely related to the regional extension and vertical tectonic deformation in the forearc. Serpentinite mudflows at these volcanoes include serpentinized forearc mantle clasts, crustal and subducted Pacific plate materials, a matrix of serpentinite muds, and deep-sourced formation fluid. Mud volcanism on the Mariana forearc occurs within 100 km of the trench, representing a range of depths and temperatures to the downgoing plate and the subduction channel. These processes have likely been active for tens of millions of years at this site and for billions of years on Earth. At least 10 active serpentinite mud volcanoes have been located in the Mariana forearc. Two of these mud volcanoes are Conical and South Chamorro Seamounts, which are the furthest from the Mariana Trench at 86 and 78 km, respectively. Both seamounts were cored during Ocean Drilling Program (ODP) Legs 125 and 195, respectively. Data from these two seamounts represent deeper, warmer examples of the continuum of slab-derived materials as the Pacific plate subducts, providing a snapshot of how slab subduction affects fluid release, the composition of ascending fluids, mantle hydration, and the metamorphic paragenesis of subducted oceanic lithosphere. Data from the study of these two mud volcanoes constrain the pressure, temperature, and composition of fluids and materials within the subduction channel at depths of about 18 to 19 km. Understanding such processes is necessary for elucidating factors that control seismicity in convergent margins, tectonic and magma genesis processes in the forearc and volcanic arc, fluid and material fluxes, and the nature and variability of environmental conditions that impact subseafloor microbial communities. Expedition 366 centered on data collection from cores recovered from three serpentinite mud volcanoes that define a continuum of subduction-channel processes defined by the two previously cored serpentinite mud volcanoes and the trench. Three serpentinite mud volcanoes (Yinazao, Fantangisña, and Asùt Tesoro) were chosen at distances 55 to 72 km from the Mariana Trench. Cores were recovered from active sites of eruption on their summit regions and on the flanks where ancient flows are overlain by more recent ones. Recovered materials show the effects of dynamic processes that are active at these sites, bringing a range of materials to the seafloor, including materials from the lithosphere of the Pacific plate and from subducted seamounts (including corals). Most of the recovered material consists of serpentinite mud containing lithic clasts, which are derived from the underlying forearc crust and mantle and the subducting Pacific plate. Cores from each of the three seamounts drilled during Expedition 366, as well as those from Legs 125 and 195, include material from the underlying Pacific plate. A thin cover of pelagic sediment was recovered at many Expedition 366 sites, and at Site U1498 we cored through serpentinite flows to the underlying pelagic sediment and volcanic ash deposits. Recovered serpentinites are largely uniform in major element composition, with serpentinized ultramafic rocks and serpentinite muds spanning a limited range in SiO2 , MgO, and Fe2 O3 compositions. However, variation in trace element composition reflects pore fluid composition, which differs as a function of the temperature and pressure of the underlying subduction channel. Dissolved gases H2 , CH4 , and C2 H6 are highest at the site furthest from the trench, which also has the most active fluid discharge of the Expedition 366 serpentinite mud volcanoes. These dissolved gases and their active discharge from depth likely support active microbial communities, which were the focus of in-depth subsampling and preservation for shore-based analytical and culturing procedures. The effects of fluid discharge were also registered in the porosity and GRA density data indicated by higher than expected values at some of the summit sites. These higher values are consistent with overpressured fluids that minimize compaction of serpentinite mud deposits. In contrast, flank sites have significantly greater decreases in porosity with depth, suggesting that processes in addition to compaction are required to achieve the observed data. Thermal measurements reveal higher heat flow values on the flanks (~31 mW/m2) than on the summits (~17 mW/m2) of the seamounts. The new 2G Enterprises superconducting rock magnetometer (liquid helium free) revealed relatively high values of both magnetization and bulk magnetic susceptibility of discrete samples related to ultramafic rocks, particularly in dunite. Magnetite, a product of serpentinization, and authigenic carbonates were observed in the mudflow matrix materials. In addition to coring operations, Expedition 366 focused on the deployment and remediation of borehole casings for future observatories and set the framework for in situ experimentation. Borehole work commenced at South Chamorro Seamount, where the original-style CORK was partially removed. Work then continued at each of the three summit sites following coring operations. Cased boreholes with at least three joints of screened casing were deployed, and a plug of cement was placed at the bottom of each hole. Water samples were collected from two of the three boreholes, revealing significant inputs of formation fluids. This suggests that each of the boreholes tapped a hydrologic zone, making these boreholes suitable for experimentation with the future deployment of a CORK-lite. An active education and outreach program connected with many classrooms on shore and with the general public through social media. 

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5. Mariana Convergent Margin and South Chamorro Seamount

   https://doi.org/10.14379/iodp.proc.366.2018  

   Fryer, P. ; Wheat, C.G. ; Williams, T. ( February 2018 , Proceedings of the International Ocean Discovery Program)

   null (Ed.)

   Geologic processes at convergent plate margins control geochemical cycling, seismicity, and deep biosphere activity in subduction zones and suprasubduction zone lithosphere. International Ocean Discovery Program Expedition 366 was designed to address the nature of these processes in the shallow to intermediate depth of the Mariana subduction channel. Although no technology is available to permit direct sampling of the subduction channel of an intraoceanic convergent margin at depths up to 19 km, the Mariana forearc region (between the trench and the active volcanic arc) provides a means to access materials from this zone. Active conduits, resulting from fractures in the forearc, are prompted by along- and across-strike extension that allows slab-derived fluids and materials to ascend to the seafloor along associated faults, resulting in the formation of serpentinite mud volcanoes. Serpentinite mud volcanoes of the Mariana forearc are the largest mud volcanoes on Earth. Their positions adjacent to or atop fault scarps on the forearc are likely related to the regional extension and vertical tectonic deformation in the forearc. Serpentinite mudflows at these volcanoes include serpentinized forearc mantle clasts, crustal and subducted Pacific plate materials, a matrix of serpentinite muds, and deep-sourced formation fluid. Mud volcanism on the Mariana forearc occurs within 100 km of the trench, representing a range of depths and temperatures to the downgoing plate and the subduction channel. These processes have likely been active for tens of millions of years at the Mariana forearc and for billions of years on Earth. At least 19 active serpentinite mud volcanoes have been located in the Mariana forearc. Two of these mud volcanoes are Conical and South Chamorro Seamounts, which are the farthest from the Mariana Trench at 86 and 78 km, respectively. Both seamounts were cored during Ocean Drilling Program Legs 125 and 195, respectively. Data from these two seamounts represent deeper, warmer examples of the continuum of slab-derived materials as the Pacific plate subducts, providing a snapshot of how slab subduction affects fluid release, the composition of ascending fluids, mantle hydration, and the metamorphic paragenesis of subducted oceanic lithosphere. Data from the study of these two mud volcanoes constrain the pressure, temperature, and composition of fluids and materials within the subduction channel at depths of up to 19 km. Understanding such processes is necessary for elucidating factors that control seismicity in convergent margins, tectonic and magma genesis processes in the volcanic arc and backarc areas, fluid and material fluxes, and the nature and variability of environmental conditions that impact subseafloor microbial communities. Expedition 366 focused on data collection from cores recovered from three serpentinite mud volcanoes that define a continuum of subduction-channel processes to compare with results from drilling at the two previously cored serpentinite mud volcanoes and with previously collected gravity, piston, and remotely operated vehicle push cores across the trench-proximal forearc. Three serpentinite mud volcanoes (Yinazao, Fantangisña, and Asùt Tesoro) were chosen at distances 55 to 72 km from the Mariana Trench. Cores were recovered from active sites of eruption on their summit regions and on the flanks where ancient flows are overlain by more recent ones. Recovered materials show the effects of dynamic processes that are active at these sites, bringing a range of materials to the seafloor, including materials from the crust of the Pacific plate, most notably subducted seamounts (even corals). Most of the recovered material consists of serpentinite mud containing lithic clasts, which are derived from the underlying forearc crust and mantle and the subducting Pacific plate. A thin cover of pelagic sediment was recovered at many Expedition 366 sites, and at Site U1498 we cored through distal serpentinite mudflows and into the underlying pelagic sediment and volcanic ash deposits. Recovered serpentinized ultramafic rocks and mudflow matrix materials are largely uniform in major element composition, spanning a limited range in SiO2, MgO, and Fe2O3 compositions. However, variation in trace element composition reflects interstitial water composition, which differs as a function of the temperature and pressure of the underlying subduction channel. Dissolved gases H2, CH4, and C2H6 are highest at the site farthest from the trench, which also has the most active fluid discharge of the Expedition 366 serpentinite mud volcanoes. These dissolved gases and their active discharge from depth likely support active microbial communities, which were the focus of in-depth subsampling and preservation for shore-based analytical and culturing procedures. The effects of fluid discharge were also registered in the porosity and gamma ray attenuation density data indicated by higher than expected values at some of the summit sites. These higher values are consistent with overpressured fluids that slow compaction of serpentinite mud deposits. In contrast, flank sites have significantly greater decreases in porosity with depth, suggesting that processes in addition to compaction are required to achieve the observed data. Thermal measurements reveal higher heat flow values on the flanks (~31 mW/m2) than on the summits (~17 mW/m2) of the seamounts. The new 2G Enterprises superconducting rock magnetometer (liquid helium free) revealed relatively high values of both magnetization and bulk magnetic susceptibility of discrete samples related to ultramafic rocks, particularly dunite. Magnetite, a product of serpentinization, and authigenic carbonates were observed in the mudflow matrix materials. In addition to coring operations, Expedition 366 focused on the deployment and remediation of borehole casings for future observatories and set the framework for in situ experimentation. Borehole work commenced at South Chamorro Seamount, where the original-style CORK was partially removed. Work then continued at each of the three summit sites following coring operations. Cased boreholes with at least three joints of screened casing were deployed, and a plug of cement was placed at the bottom of each hole. Water samples were collected from two of the three boreholes, revealing significant inputs of formation fluids. This suggests that each of the boreholes tapped a hydrologic zone, making these boreholes suitable for experimentation with the future deployment of a CORK-Lite. 

   more » « less