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1. Using Trace Elements in Olivine Phenocrysts to Test Models of Melt Differentiation at Convergent Margins: Constraints from Times Series in Monogenetic Volcanoes in the Central Transmexican Volcanic Belt

   Fleming, W.; Straub, S.M.; Gomez-Tuena, A.; Espinasa-Pereña, R.; Bindeman, I.N.; Stuart, F.M.; Batanova, V.G. (December 2019, AGU Fall Meeting 2019)

   Models of subduction zone magmatism ascribe the andesitic composition of arc magmas to crustal processes, such as crustal assimilation and/or fractional crystallization, that basaltic mantle melts experience during their ascent through the upper plate crust. However, results from time series study of olivine-phyric high-Nb basalts and basaltic andesites from two monogenetic arc volcanoes (V. Chichinautzin and Texcal Flow) that are constructed on the ~45 km thick continental basement of the central Transmexican Volcanic Belt (TMVB) are inconsistent with this model. Instead, ratios of radiogenic isotope and incompatible trace elements suggest that these volcanoes were constructed through multiple individual melt batches ascending from a progressively changing mantle source. Moreover, the high Ni contents of the olivine phenocrysts, together with their high mantle-like 3He/4Heoliv =7-8 Ra with high crustal δ18O oliv = +5.5 to +6.5‰ (n=12) point to the presence of secondary ‘reaction pyroxenites’ in the mantle source that create primary silicic arc magmas through melt-rock reaction processes in the mantle [1, 2] . Here we present additional trace element concentration of the high-Ni olivines by electron microprobe (Mn, Ca) and laser-ablation ICPMS (Li, Cr and V) analysis in order to test this model. Olivine Li (2-7 ppm) and Mn (1170- 2810 ppm) increase with decreasing fosterite (Fo89 to Fo75), while Cr (29-364 ppm), V (4-11 ppm) and Ca (825-2390 ppm) decrease. Quantitative modeling shows that these trends in their entirety cannot be controlled by fractional crystallization under variable melt water H2O or oxygen fugacity (fO2), or co-crystallization of Cr-spinel. Instead, the variations support the existence of compositionally distinct melt batches during earliest melt evolution. Moreover, the trace element trends are qualitatively consistent with a model of progressive source depletion by serial melting (shown in olivine Ca, V and Cr) that is triggered by the repetitive addition of silicic slab components (shown by olivine Li). These findings suggest mantle source variations are not eliminated despite the thick crust these magmas pass during ascent. [1] Straub et al. (2013) J Petrol 54 (4): 665-701; [2] Straub et al. (2015) Geochim Cosmochim Acta 166: 29-52. 

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2. Slab-derived devolatilization fluids oxidized by subducted metasedimentary rocks

   https://doi.org/10.1038/s41561-022-00904-7  

   Ague, Jay J.; Tassara, Santiago; Holycross, Megan E.; Li, Ji-Lei; Cottrell, Elizabeth; Schwarzenbach, Esther M.; Fassoulas, Charalampos; John, Timm (March 2022, Nature Geoscience)

   Abstract Metamorphic devolatilization of subducted slabs generates aqueous fluids that ascend into the mantle wedge, driving the partial melting that produces arc magmas. These magmas have oxygen fugacities some 10–1,000 times higher than magmas generated at mid-ocean ridges. Whether this oxidized magmatic character is imparted by slab fluids or is acquired during ascent and interaction with the surrounding mantle or crust is debated. Here we study the petrology of metasedimentary rocks from two Tertiary Aegean subduction complexes in combination with reactive transport modelling to investigate the oxidative potential of the sedimentary rocks that cover slabs. We find that the metasedimentary rocks preserve evidence for fluid-mediated redox reactions and could be highly oxidized. Furthermore, the modelling demonstrates that layers of these oxidized rocks less than about 200 m thick have the capacity to oxidize the ascending slab dehydration flux via redox reactions that remove H₂, CH₄and/or H₂S from the fluids. These fluids can then oxidize the overlying mantle wedge at rates comparable to arc magma generation rates, primarily via reactions involving sulfur species. Oxidized metasedimentary rocks need not generate large amounts of fluid themselves but could instead oxidize slab dehydration fluids ascending through them. Proposed Phanerozoic increases in arc magma oxygen fugacity may reflect the recycling of oxidative weathering products following Neoproterozoic–Palaeozoic marine and atmospheric oxygenation. 

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3. Architectural and Tectonic Control on the Segmentation of the Central American Volcanic Arc

   https://doi.org/10.1146/annurev-earth-082420-055108  

   Gazel, Esteban; Flores, Kennet E.; Carr, Michael J. (May 2021, Annual Review of Earth and Planetary Sciences)

   null (Ed.)

   Central America has a rich mix of conditions that allow comparisons of different natural experiments in the generation of arc magmas within the relatively short length of the margin. The shape of the volcanic front and this margin's architecture derive from the assemblage of exotic continental and oceanic crustal slivers, and later modification by volcanism and tectonic activity. Active tectonics of the Cocos-Caribbean plate boundary are strongly influenced by oblique subduction, resulting in a narrow volcanic front segmented by right steps occurring at ∼150-km intervals. The largest volcanic centers are located where depths to the slab are ∼90–110 km. Volcanoes that develop above deeper sections of the subducting slab are less voluminous and better record source geochemical heterogeneity. Extreme variations in isotopic and trace element ratios are derived from different components of thesubducted oceanic lithosphere. However, the extent that volcanoes sample these signatures is also influenced by lithospheric structures that control the arc segmentation. ▪  The architecture of Central America derives from the assemblage of exotic continental and oceanic crustal slivers modified by arc magmatism and tectonic processes. ▪  Active tectonics in Central America are controlled by oblique subduction. ▪  The lithospheric architecture and tectonics define the segmentation of the volcanic front, and thus the depth to the slab below a volcanic center. ▪  The composition of the subducted material is the main control of the along arc geochemical variations observed in Central American volcanoes. ▪  Geochemical heterogeneity in each segment is highlighted by extreme compositions representing the smaller centers with variations up to 65% of the total observed range. 

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4. Architectural and Tectonic Control on the Segmentation of the Central American Volcanic Arc

   https://doi.org/doi.org/10.1146/annurev-earth-082420-055108  

   Gazel, E.; Flores, K.E.; Carr, M.J. (January 2021, Annual review of earth and planetary sciences)

   null (Ed.)

   Central America has a rich mix of conditions that allow comparisons of different natural experiments in the generation of arc magmas within the relatively short length of the margin. The shape of the volcanic front and this margin's architecture derive from the assemblage of exotic continental and oceanic crustal slivers, and later modification by volcanism and tectonic activity. Active tectonics of the Cocos-Caribbean plate boundary are strongly influenced by oblique subduction, resulting in a narrow volcanic front segmented by right steps occurring at ?150-km intervals. The largest volcanic centers are located where depths to the slab are ?90?110 km. Volcanoes that develop above deeper sections of the subducting slab are less voluminous and better record source geochemical heterogeneity. Extreme variations in isotopic and trace element ratios are derived from different components of thesubducted oceanic lithosphere. However, the extent that volcanoes sample these signatures is also influenced by lithospheric structures that control the arc segmentation. ?? The architecture of Central America derives from the assemblage of exotic continental and oceanic crustal slivers modified by arc magmatism and tectonic processes. ?? Active tectonics in Central America are controlled by oblique subduction. ?? The lithospheric architecture and tectonics define the segmentation of the volcanic front, and thus the depth to the slab below a volcanic center. ?? The composition of the subducted material is the main control of the along arc geochemical variations observed in Central American volcanoes. ?? Geochemical heterogeneity in each segment is highlighted by extreme compositions representing the smaller centers with variations up to 65% of the total observed range. 

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5. Li isotope ratios of spring fluids as an effective tracer of slab-derived subducted sources across the Costa Rica forearc

   https://doi.org/10.1130/G51277.1  

   Helper, Jacob P.; Barnes, Jaime D.; Maarten de Moor, J.; Rodríguez, Alejandro; Barry, Peter H.; Ramos, Evan J.; Lassiter, John C. (July 2023, Geology)

   Spring waters from across the Costa Rica margin were analyzed for their Li and He isotope compositions to determine the utility of Li isotopes as a tracer of volatile sources in subduction zones. Li isotope ratios systematically decrease with increasing depth to the subducting slab: averaging +15.0‰ ± 9.2‰ in the outer forearc (<40 km to the slab), +9.3‰ ± 4.3‰ in the forearc (40–80 km to the slab), and +5.8‰ ± 2.8‰ in the arc (>80 km to the slab). In contrast, air-corrected 3He/4He values (reported relative to the ratio in air, RA) range from 0.4 to 7.5 RA and increase from predominantly crustal values near the trench to mantle values in the arc. Together, these data support progressive devolatilization of the subducting plate with slab-derived Li components sourced from shallowly expelled pore fluids in the outer forearc, sedimentary and/or altered oceanic crust contributing to the forearc, and limited slab input beneath the arc. 

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