A theoretical analysis on crack formation and propagation was performed based on the coupling between the electrochemical process, classical elasticity, and fracture mechanics. The chemical potential of oxygen, thus oxygen partial pressure, at the oxygen electrode-electrolyte interface (
We measure the molecular-to-atomic gas ratio,
- Authors:
- ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; more »
- Publication Date:
- NSF-PAR ID:
- 10383694
- Journal Name:
- The Astrophysical Journal
- Volume:
- 940
- Issue:
- 2
- Page Range or eLocation-ID:
- Article No. 176
- ISSN:
- 0004-637X
- Publisher:
- DOI PREFIX: 10.3847
- Sponsoring Org:
- National Science Foundation
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) was investigated as a function of transport properties, electrolyte thickness and operating conditions (e.g., steam concentration, constant current, and constant voltage). Our analysis shows that: a lower ionic area specific resistance (ASR), and a higher electronic ASR ( ) of the oxygen electrode/electrolyte interface are in favor of suppressing crack formation. The thus local pO2, are sensitive towards the operating parameters under galvanostatic or potentiostatic electrolysis. Constant current density electrolysis provides better robustness, especially at a high current density with a high steam content. While constant voltage electrolysis leads to greater variations of Constant current electrolysis, however, is not suitable for an unstable oxygen electrode because can reach a very high value with a gradually increased A crack may only occur under certain conditions when -
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