skip to main content


Title: Cold Deuterium Fractionation in the Nearest Planet-forming Disk
Abstract

Deuterium fractionation provides a window into the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed toward a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new Atacama Large Millimeter/submillimeter Array observations of DCO+and DCNJ= 2–1 at an angular resolution of 0.″5 (30 au) and combine them with archival data of higher energy transitions toward the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO+and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of 1.9 × 1012and 9.8 × 1011cm−2for DCO+and DCN, with typical kinetic temperatures for both molecules of 20–30 K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO+/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas-phase C/O enhancement within <40 au. Observations of DCO+and DCN in other disks, as well as HCN and HCO+, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks.

 
more » « less
NSF-PAR ID:
10392444
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ;
Publisher / Repository:
DOI PREFIX: 10.3847
Date Published:
Journal Name:
The Astrophysical Journal
Volume:
943
Issue:
1
ISSN:
0004-637X
Format(s):
Medium: X Size: Article No. 35
Size(s):
["Article No. 35"]
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    The dominant form of oxygen in cold molecular clouds is gas-phase carbon monoxide (CO) and ice-phase water (H2O). Yet, in planet-forming disks around young stars, gas-phase CO and H2O are less abundant relative to their interstellar medium values, and no other major oxygen-carrying molecules have been detected. Some astrochemical models predict that gas-phase molecular oxygen (O2) should be a major carrier of volatile oxygen in disks. We report a deep search for emission from the isotopologue16O18O (NJ= 21− 01line at 233.946 GHz) in the nearby protoplanetary disk around TW Hya. We used imaging techniques and matched filtering to search for weak emission but do not detect16O18O. Based on our results, we calculate upper limits on the gas-phase O2abundance in TW Hya of (6.4–70) × 10−7relative to H, which is 2–3 orders of magnitude below solar oxygen abundance. We conclude that gas-phase O2is not a major oxygen carrier in TW Hya. Two other potential oxygen-carrying molecules, SO and SO2, were covered in our observations, which we also do not detect. Additionally, we report a serendipitous detection of the C15NNJ= 25/2− 13/2hyperfine transitions,F= 3 − 2 andF= 2 − 1, at 219.9 GHz, which we found via matched filtering and confirm through imaging.

     
    more » « less
  2. null (Ed.)
    Context. Physical processes that govern the star and planet formation sequence influence the chemical composition and evolution of protoplanetary disks. Recent studies allude to an early start to planet formation already during the formation of a disk. To understand the chemical composition of protoplanets, we need to constrain the composition and structure of the disks from whence they are formed. Aims. We aim to determine the molecular abundance structure of the young disk around the TMC1A protostar on au scales in order to understand its chemical structure and any possible implications for disk formation. Methods. We present spatially resolved Atacama Large Millimeter/submillimeter Array observations of CO, HCO + , HCN, DCN, and SO line emission, as well as dust continuum emission, in the vicinity of TMC1A. Molecular column densities are estimated both under the assumption of optically thin emission from molecules in local thermodynamical equilibrium (LTE) as well as through more detailed non-LTE radiative transfer calculations. Results. Resolved dust continuum emission from the disk is detected between 220 and 260 GHz. Rotational transitions from HCO + , HCN, and SO are also detected from the inner 100 au region. We further report on upper limits to vibrational HCN υ 2 = 1, DCN, and N 2 D + lines. The HCO + emission appears to trace both the Keplerian disk and the surrounding infalling rotating envelope. HCN emission peaks toward the outflow cavity region connected with the CO disk wind and toward the red-shifted part of the Keplerian disk. From the derived HCO + abundance, we estimate the ionization fraction of the disk surface, and find values that imply that the accretion process is not driven by the magneto-rotational instability. The molecular abundances averaged over the TMC1A disk are similar to its protostellar envelope and other, older Class II disks. We meanwhile find a discrepancy between the young disk’s molecular abundances relative to Solar System objects. Conclusions. Abundance comparisons between the disk and its surrounding envelope for several molecular species reveal that the bulk of planet-forming material enters the disk unaltered. Differences in HCN and H 2 O molecular abundances between the disk around TMC1A, Class II disks, and Solar System objects trace the chemical evolution during disk and planet formation. 
    more » « less
  3. Abstract

    We present the first detection of13CCH in a protoplanetary disk (TW Hya). Using observations of C2H, we measure CCH/13CCH = 65 ± 20 gas with a CO isotopic ratio of12CO/13CO = 21 ± 5. The TW Hya disk exhibits a gas phase C/O that exceeds unity, and C2H is the tracer of this excess carbon. We confirm that the TW Hya gaseous disk exhibits two separate carbon isotopic reservoirs, as noted previously. We explore two theoretical solutions for the development of this dichotomy. One model represents TW Hya today with a protoplanetary disk exposed to a cosmic-ray ionization rate that is below interstellar as consistent with current estimates. We find that this model does not have sufficient ionization in cold (T< 40 K) layers to activate carbon isotopic fractionation. The second model investigates a younger TW Hya protostellar disk exposed to an interstellar cosmic-ray ionization rate. We find that the younger model has sources of ionization deeper in a colder disk that generates two independent isotopic reservoirs. One reservoir is12C-enriched carried by methane/hydrocarbon ices, and the other is13C-enriched carried by gaseous CO. The former potentially provides a source of methane/hydrocarbon ices to power the chemistry that generates the anomalously strong C2H emission in this (and other) disk systems in later stages. The latter provides a source of gaseous13C-rich material to generate isotopic enrichments in forming giant planets, as recently detected in the super-Jupiter TYC 8998-760-1 b by Zhang et al.

     
    more » « less
  4. Abstract

    Studying the physical and chemical conditions of young embedded disks is crucial to constrain the initial conditions for planet formation. Here we present Atacama Large Millimeter/submillimeter Array observations of dust continuum at ∼0.″06 (8 au) resolution and molecular line emission at ∼0.″17 (24 au) resolution toward the Class 0 protostar L1527 IRS from the Large Program eDisk (Early Planet Formation in Embedded Disks). The continuum emission is smooth without substructures but asymmetric along both the major and minor axes of the disk as previously observed. The detected lines of12CO,13CO, C18O, H2CO, c-C3H2, SO, SiO, and DCN trace different components of the protostellar system, with a disk wind potentially visible in12CO. The13CO brightness temperature and the H2CO line ratio confirm that the disk is too warm for CO freezeout, with the snowline located at ∼350 au in the envelope. Both molecules show potential evidence of a temperature increase around the disk–envelope interface. SO seems to originate predominantly in UV-irradiated regions such as the disk surface and the outflow cavity walls rather than at the disk–envelope interface as previously suggested. Finally, the continuum asymmetry along the minor axis is consistent with the inclination derived from the large-scale (100″ or 14,000 au) outflow, but opposite to that based on the molecular jet and envelope emission, suggesting a misalignment in the system. Overall, these results highlight the importance of observing multiple molecular species in multiple transitions to characterize the physical and chemical environment of young disks.

     
    more » « less
  5. Abstract The Molecules with ALMA at Planet-forming Scales (MAPS) Large Program provides a detailed, high-resolution (∼10–20 au) view of molecular line emission in five protoplanetary disks at spatial scales relevant for planet formation. Here we present a systematic analysis of chemical substructures in 18 molecular lines toward the MAPS sources: IM Lup, GM Aur, AS 209, HD 163296, and MWC 480. We identify more than 200 chemical substructures, which are found at nearly all radii where line emission is detected. A wide diversity of radial morphologies—including rings, gaps, and plateaus—is observed both within each disk and across the MAPS sample. This diversity in line emission profiles is also present in the innermost 50 au. Overall, this suggests that planets form in varied chemical environments both across disks and at different radii within the same disk. Interior to 150 au, the majority of chemical substructures across the MAPS disks are spatially coincident with substructures in the millimeter continuum, indicative of physical and chemical links between the disk midplane and warm, elevated molecular emission layers. Some chemical substructures in the inner disk and most chemical substructures exterior to 150 au cannot be directly linked to dust substructure, however, which indicates that there are also other causes of chemical substructures, such as snowlines, gradients in UV photon fluxes, ionization, and radially varying elemental ratios. This implies that chemical substructures could be developed into powerful probes of different disk characteristics, in addition to influencing the environments within which planets assemble. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement. 
    more » « less