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Graphene is one of the stiffest materials ever measured, and yet foams of this material experience such massive degradation in mechanical properties at low densities that they are worse than polymer foams. (Z. Qin, G. S. Jung, M. J. Kang and M. J. Buehler, Sci. Adv., 2017, 3, e1601536). 3D printed mechanical metamaterials have shown the unprecedented ability to alleviate such degradation, but all current 3D printing techniques capable of printing graphene foam are unable to reproduce the complex metamaterial architectures (e.g. insufficient resolution, toolpath limitations, etc.). Here we demonstrate high-resolution graphene foams incorporating hierarchical architecture which reduces mechanical degradation of graphene foams with decreasing density. Our technique achieves an order-of-magnitude finer resolution and far more intricate structures than any previous method. This technique opens new possibilities not only to enhance graphene foam mechanical properties, but to explore complex architectures and mesoscale effects for other graphene applications including energy storage and conversion, separations, and catalysis.
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Flexural behavior and microstructural material properties of sandwich foam core under arctic temperature conditions
This study investigates three types of foam core materials used in composite sandwich structures at various densities: H60, H100, F50, F90, PN115, PN200 and PN250. Three-point bending test is conducted to determine relationships between material and flexural properties at both room and low temperature Arctic conditions. X-ray micro-computed tomography is utilized to observe the microstructural relationships between foam density and mechanical properties of the core. This study evaluates Arctic temperature effects on mechanical properties for various types of foam core at varying densities with the intention for future Arctic applications. Although foam core materials become more brittle at a lower temperature, their flexural stiffness and flexural strength are further increased. However, due to the enhanced brittleness, the energy required for fracture is significantly reduced at low temperature conditions. This study utilizes statistical analysis to create contour plots and linear regression equations to predict flexural properties as a function of temperature and foam density. Molecular dynamics simulation is employed to verify experimental results to elucidate the effect of temperature on material behavior. This work provides a deeper understanding of how flexural strength relates to foam density, adding to existing data on foam strength properties under compressive, shear and tensile loads.
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- Award ID(s):
- 2152210
- PAR ID:
- 10396966
- Publisher / Repository:
- SAGE Publications
- Date Published:
- Journal Name:
- Journal of Sandwich Structures & Materials
- Volume:
- 26
- Issue:
- 2
- ISSN:
- 1099-6362
- Format(s):
- Medium: X Size: p. 205-224
- Size(s):
- p. 205-224
- Sponsoring Org:
- National Science Foundation
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