Abstract Electrowetting‐on‐dielectric (EWOD) has revolutionized digital microfluidics (DMF) by dynamically controlling surface wettability via electric fields. However, its reliance on external power, patterned electrodes, and complex circuitry limits device simplicity and portability. Here, tribo‐charge driven wetting (TCW) is introduced as a fundamentally new, electric‐free mechanism for active wettability control. Unlike voltage‐driven control in EWOD, TCW employs surface charges generated through contact electrification to modulate surface wettability, eliminating the need for electrodes, wiring, and power supplies. Using TCW, we demonstrate a substantial contact angle modulation of Δθ= 44.4°±1.1, achieved solely by a tribo‐actuator with its surface charge density of σ = −12.61 µC m−2. Comprehensive experimental and numerical analyses reveal that TCW performance scales strongly with actuator area and charge density but is remarkably insensitive to dielectric thickness within a practical range. Leveraging these features, core DMF operations are demonstrated, including droplet transport, merging, and generation from a reservoir, all accomplished without any electric components. Droplet motion reaches speeds up to 40 mm s−1, even across non‐planar terrains. Furthermore, fingertip‐controlled droplet manipulation highlights TCW's simplicity, cost‐effectiveness, and user‐interactivity. This work advances fundamentals of charge‐driven wettability control and establishes TCW as an electric‐free paradigm for active droplet control, opening new opportunities for resource‐limited, lab‐on‐a‐chip and point‐of‐care applications.
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A review of optoelectrowetting (OEW): from fundamentals to lab-on-a-smartphone (LOS) applications to environmental sensors
Electrowetting-on-dielectric (EWOD) has been extensively explored as an active-type technology for small-scale liquid handling due to its several unique advantages, including no requirement of mechanical components, low power consumption, and rapid response time. However, conventional EWOD devices are often accompanied with complex fabrication processes for patterning and wiring of 2D arrayed electrodes. Furthermore, their sandwich device configuration makes integration with other microfluidic components difficult. More recently, optoelectrowetting (OEW), a light-driven mechanism for effective droplet manipulation, has been proposed as an alternative approach to overcome these issues. By utilizing optical addressing on a photoconductive surface, OEW can dynamically control an electrowetting phenomenon without the need for complex control circuitry on a chip, while providing higher functionality and flexibility. Using commercially available spatial light modulators such as LCD displays and smartphones, millions of optical pixels are readily generated to modulate virtual electrodes for large-scale droplet manipulations in parallel on low-cost OEW devices. The benefits of the OEW mechanism have seen it being variously explored in its potential biological and biochemical applications. This review article presents the fundamentals of OEW, discusses its research progress and limitations, highlights various technological advances and innovations, and finally introduces the emergence of the OEW technology as portable smartphone-integrated environmental sensors.
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- Award ID(s):
- 2046134
- PAR ID:
- 10397355
- Date Published:
- Journal Name:
- Lab on a Chip
- Volume:
- 22
- Issue:
- 21
- ISSN:
- 1473-0197
- Page Range / eLocation ID:
- 3987 to 4006
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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