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  • Threefold reactivity of a COF-embedded rhenium catalyst: reductive etherification, oxidative esterification or transfer hydrogenation
Title: Threefold reactivity of a COF-embedded rhenium catalyst: reductive etherification, oxidative esterification or transfer hydrogenation
The reactivity of the novel Re( i ) catalyst [Re( C12 Anth-py 2 )(CO) 3 Br] is modulated by its interactions with the covalent organic framework (COF) TFB-BD. The complex catalyzes either reductive etherification, oxidative esterification, or transfer hydrogenation depending on its local environment (embedded in TFB-BD, in homogeneous solution or co-incubated with TFB-BD, respectively). The results highlight that COFs can drastically modulate the reactivity of homogeneous catalysts.  more » « less
Award ID(s):
2109175
PAR ID:
10398842
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
58
Issue:
86
ISSN:
1359-7345
Page Range / eLocation ID:
12074 to 12077
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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