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Title: Modulation of Chiroptical and Photophysical Properties in Helicenic Rhenium(I) Systems: The Use of an N ‐(Aza[6]helicenyl)‐NHC Ligand
Abstract

The photophysical and chiroptical properties of a novel, chiral helicene‐NHC−Re(I) complex bearing anN‐(aza[6]helicenyl)‐benzimidazolylidene ligand are described, showing its ability to emit yellow circularly polarized luminescence. A comparative analysis of this new system with other helicene‐Re(I) complexes reported to date illustrates the impact of structural modifications on the emissive and absorptive properties.

 
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Award ID(s):
2152633
NSF-PAR ID:
10401159
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Chemistry – A European Journal
Volume:
29
Issue:
21
ISSN:
0947-6539
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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