Abstract Friction-generated heat and the subsequent thermal evolution control fault material properties and thus strength during the earthquake cycle. We document evidence for transient, nanoscale fault rheology on a high-gloss, light-reflective hematite fault mirror (FM). The FM cuts specularite with minor quartz from the Pleistocene El Laco Fe-ore deposit, northern Chile. Scanning and transmission electron microscopy data reveal that the FM volume comprises a <50-μm-thick zone of polygonal hematite nanocrystals with spherical silica inclusions, rhombohedral twins, no shape or crystallographic preferred orientation, decreasing grain size away from the FM surface, and FM surface magnetite nanoparticles and Fe2+ suboxides. Sub–5-nm-thick silica films encase hematite grains and connect to amorphous interstitial silica. Observations imply that coseismic shear heating (temperature >1000 °C) generated transiently amorphous, intermixed but immiscible, and rheologically weak Fe-oxide and silica. Hematite regrowth in a fault-perpendicular thermal gradient, sintering, twinning, and a topographic network of nanometer-scale ridges from crystals interlocking across the FM surface collectively restrengthened fault material. Results reveal how temperature-induced weakening preconditions fault healing. Nanoscale transformations may promote subsequent strain delocalization and development of off-fault damage.
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Interfacial plasticity governs strain delocalization in metallic nanoglasses
Intrinsic size effects in nanoglass plasticity have been connected to the structural length scales imposed by the interfacial network, and control over this behavior is critical to designing amorphous alloys with improved mechanical response. In this paper, atomistic simulations are employed to probe strain delocalization in nanoglasses with explicit correlation to the interfacial characteristics and length scales of the amorphous grain structure. We show that strength is independent of grain size under certain conditions, but scales with the excess free volume and degree of short-range ordering in the interfaces. Structural homogenization upon annealing of the nanoglasses increases their strength toward the value of the bulk metallic glass; however, continued partitioning of strain to the interfacial regions inhibits the formation of a primary shear band. Intrinsic size effects in nanoglass plasticity thus originate from biased plastic strain accumulation within the interfacial regions, which will ultimately govern strain delocalization and homogenous flow in nanoglasses.
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- Award ID(s):
- 1554411
- NSF-PAR ID:
- 10403581
- Date Published:
- Journal Name:
- Journal of Materials Research
- Volume:
- 34
- Issue:
- 13
- ISSN:
- 0884-2914
- Page Range / eLocation ID:
- 2325 to 2336
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1557/jmr.2019.101
