An official website of the United States government
These data were collected on the CCGS (Canadian Coast Guard) Louis St. Laurent during BGOS (Beaufort Gyre Observing System) research cruises in 2012-2014 and 2016-2021 in the Beaufort Sea area. They are underway pCO2 (Partial pressure of carbon dioxide) data collected using an equilibrator-infrared method (SUPER CO2 system from Sunburst Sensors). Ancillary data for calculation of air-sea CO fluxes include temperature, salinity, atmospheric CO2, wind speed, and gas transfer velocity (calculated from Wanninkhof et al. (2009). Fluxes are not corrected for fractional ice-coverage. The specific goal of the study is to continue to operate an Arctic Observing Network (AON) for the measurement of the partial pressure of CO2 (pCO2), pH, and dissolved O2 (DO) focused on the surface waters of the Arctic Ocean (specifically, the Canada Basin). These data were collected on the CCGS (Canadian Coast Guard) Louis St. Laurent during a BGOS (Beaufort Gyre Observing System) research cruise in the Beaufort Sea area. It is underway pCO2 (partial pressure of carbon dioxide) data collected using an equilibrator-infrared method (SUPER CO2 system from Sunburst Sensors). Ancillary data for calculation of air-sea CO2 fluxes include temperature, salinity, atmospheric CO2.
more »
« less
Ice-Tethered Profiler Biogeochemical Time-Series Data, Arctic Ocean, 2012-2021
The goal of the proposed study is to establish an Arctic Observing Network (AON) for sea surface partial pressure of carbon dioxide (pCO2) and pH in the perennially ice-covered portion of the Arctic Ocean. The carbon cycle is of particular concern in the Arctic because it is unknown how carbon sources and sinks will change in response to warming and the reduction of summer sea ice cover, and whether these changes will lead to increased greenhouse gas accumulation in the atmosphere. Furthermore, the penetration of anthropogenic caron dioxide (CO2) into the Arctic Ocean is leading to acidification with potentially serious consequences for organisms. Little is known about pCO2 and the inorganic carbon cycle in the central Arctic Ocean because most measurement programs to date have focused on the Arctic shelves during the accessible summer period. The investigators propose to use an existing component of the Arctic Observing Network, the Ice-Tethered Profilers (ITP), as platforms for deployment of in situ pCO2 and pH sensors. ITPs are automated profiling systems distributed throughout the perennial Arctic ice pack that telemeter data back to shore: 44 ITPs have been deployed since 2004 and the project is currently slated to continue through 2013. In the proposed work, a total of 6 ITPs will be equipped with CO2 sensors and four of these will also have pH sensors. The sensors will be fixed on the ITP cable ~2-4 meters below the ice. Each unit will include additional sensors for dissolved O2, salinity, and photosynthetically available radiation (and in some cases chlorophyll-a fluorescence) and will be capable of making 12 measurements per day for at least one year. These data, available in near real-time on the ITP web site (www.whoi.edu/itp/), will lead to a better understanding of the Arctic Ocean's role in regulating greenhouse gases and how the ecology of the Arctic will change with warming and acidification. The investigators will also engage in outreach programs including public presentations, podcasts, and school visits. A portion of the budget is also dedicated to the development of a climate-change/ocean acidification exhibit to be displayed in the University of Montana's science museum. The exhibit will reside at the museum for three months, then visit over 15 rural and tribal communities annually over a three year period. Undergraduate students will be recruited to assist with the sensor testing and data analysis, gaining a higher level of technical knowledge than possible through a traditional degree program. These data were collected using in situ sensors for the partial pressure of CO2 (pCO2), pH, dissolved oxygen (DO), photosynthetically available radiation (PAR), temperature, salinity and depth. Sensors were deployed at ~6 meter depth on ice-tethered profilers, in collaboration with Woods Hole Oceanographic Institution (Rick Krishfield and John Toole). Data are available at the website http://www.whoi.edu/page.do?pid=20781.
more »
« less
- Award ID(s):
- 1951294
- PAR ID:
- 10409720
- Publisher / Repository:
- NSF Arctic Data Center
- Date Published:
- Subject(s) / Keyword(s):
- EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > CARBON EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > CARBONATE EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY EARTH SCIENCE > OCEANS > OCEAN CHEMISTRY > PH IN SITU/LABORATORY INSTRUMENTS > RADIATION SENSORS > LICOR QUANTUM SENSOR IN SITU/LABORATORY INSTRUMENTS > CONDUCTIVITY SENSORS IN SITU/LABORATORY INSTRUMENTS > CHEMICAL METERS/ANALYZERS > GAS SENSORS 1 METER TO 30 METERS HOURLY TO DAILY OTHER POINT MULTIPLE
- Format(s):
- Medium: X Other: text/xml
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
This collection contains repeated vertical profiles of ocean temperature and salinity versus pressure, as well as oxygen and velocity for some instruments. Data were collected between about 7 and 750m of the Arctic Ocean by Ice-Tethered Profilers (ITPs) that crawled up and down a conducting wire suspended from a buoy frozen into the ice pack. The profiles were collected roughly twice a day, depending on ITP programming, over the course of months to years. The vertical resolution of the final processed data is 1m, with horizontal resolution depending on ice drift speeds. ITPs have been released in different parts of the Arctic Ocean including near the North Pole and are intended to cover the whole Arctic ocean with depths exceeding 750m.more » « less
-
Ocean acidification is occurring in conjunction with warming and deoxygenation as a result of anthropogenic greenhouse gas emissions. Multistressor experiments are critically needed to better understand the sensitivity of marine organisms to these concurrent changes. Growth and survival responses to acidification have been documented for many marine species, but studies that explore underlying physiological mechanisms of carbon dioxide (CO2) sensitivity are less common. We investigated oxygen consumption rates as proxies for metabolic responses in embryos and newly hatched larvae of an estuarine forage fish (Atlantic silverside, Menidia menidia) to factorial combinations of CO2×temperature or CO2×oxygen. Metabolic rates of embryos and larvae significantly increased with temperature, but partial pressure of CO2 (PCO2) alone did not affect metabolic rates in any experiment. However, there was a significant interaction between PCO2 and partial pressure of oxygen (PO2) in embryos, because metabolic rates were unaffected by PO2 level at ambient PCO2, but decreased with declining PO2 under elevated PCO2. For larvae, however, PCO2 and PO2 had no significant effect on metabolic rates. Our findings suggest high individual variability in metabolic responses to high PCO2, perhaps owing to parental effects and time of spawning. We conclude that early life metabolism is largely resilient to elevated PCO2 in this species, but that acidification likely influences energetic responses and thus vulnerability to hypoxia.more » « less
-
null (Ed.)Abstract. The western Arctic Ocean, including its shelves and coastal habitats, has become a focus in ocean acidification research over the past decade as thecolder waters of the region and the reduction of sea ice appear to promote the uptake of excess atmospheric CO2. Due to seasonal sea icecoverage, high-frequency monitoring of pH or other carbonate chemistry parameters is typically limited to infrequent ship-based transects duringice-free summers. This approach has failed to capture year-round nearshore carbonate chemistry dynamics which is modulated by biological metabolismin response to abundant allochthonous organic matter to the narrow shelf of the Beaufort Sea and adjacent regions. The coastline of the Beaufort Seacomprises a series of lagoons that account for > 50 % of the land–sea interface. The lagoon ecosystems are novel features that cycle between“open” and “closed” phases (i.e., ice-free and ice-covered, respectively). In this study, we collected high-frequency pH, salinity,temperature, and photosynthetically active radiation (PAR) measurements in association with the Beaufort Lagoon Ecosystems – Long Term Ecological Research program – for an entire calendar yearin Kaktovik Lagoon, Alaska, USA, capturing two open-water phases and one closed phase. Hourly pH variability during the open-water phases are someof the fastest rates reported, exceeding 0.4 units. Baseline pH varied substantially between the open phase in 2018 and open phase in 2019 from ∼ 7.85to 8.05, respectively, despite similar hourly rates of change. Salinity–pH relationships were mixed during all three phases, displaying nocorrelation in the 2018 open phase, a negative correlation in the 2018/19 closed phase, and a positive correlation during the 2019 open phase. The high frequency of pH variabilitycould partially be explained by photosynthesis–respiration cycles as correlation coefficients between daily average pH and PAR were 0.46 and 0.64for 2018 and 2019 open phases, respectively. The estimated annual daily average CO2 efflux (from sea to atmosphere) was5.9 ± 19.3 mmolm-2d-1, which is converse to the negative influx of CO2 estimated for the coastal Beaufort Seadespite exhibiting extreme variability. Considering the geomorphic differences such as depth and enclosure in Beaufort Sea lagoons, furtherinvestigation is needed to assess whether there are periods of the open phase in which lagoons are sources of carbon to the atmosphere, potentiallyoffsetting the predicted sink capacity of the greater Beaufort Sea.more » « less
-
With the increasing threat of ocean acidification and the important role of the oceans in the global carbon cycle, highly precise, accurate, and intercomparable determination of inorganic carbon system parameters is required. Thermodynamic relationships enable the system to be fully constrained using a combination of direct measurements and calculations. However, calculations are complicated by many formulations for dissociation constants (over 120 possible combinations). To address these important issues of uncertainty and comparability, we evaluated the various combinations of constants and their (dis)agreement with direct measurements over a range of temperature (−1.9–40 ◦C), practical salinity (15–39) and pCO2 (150–1200 μatm). The results demonstrate that differences between the calculations and measurements are significantly larger than measurement uncertainties, meaning the oft-stated paradigm that one only needs to measure two parameters and the others can be calculated does not apply for climate quality ocean acidification research. The uncertainties in calculated pHt prevent climate quality pHt from being calculated from total alkalinity (TA) and dissolved inorganic carbon (DIC) and should be directly measured instead. However, climate quality TA and DIC can often be calculated using measured pH and DIC or TA respectively. Calculations are notably biased at medium-to-high pCO2 values (~500–800 μatm) implying models underestimate future ocean acidification. Uncertainty in the dissociation constants leads to significant uncertainty in the depth of the aragonite saturation horizon (>500 m in the Southern Ocean) and must be considered when studying calcium carbonate cycling. Significant improvements in the precision of the thermodynamic constants are required to improve pHt calculations.more » « less
