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Traditionally, precipitates in a material are thought to serve as obstacles to dislocation glide and cause hardening of the material. This conventional wisdom, however, fails to explain recent discoveries of ultrahigh-strength and large-ductility materials with a high density of nanoscale precipitates, as obstacles to dislocation glide often lead to high stress concentration and even microcracks, a cause of progressive strain localization and the origin of the strength–ductility conflict. Here we reveal that nanoprecipitates provide a unique type of sustainable dislocation sources at sufficiently high stress, and that a dense dispersion of nanoprecipitates simultaneously serve as dislocation sources and obstacles, leading to a sustainable and self-hardening deformation mechanism for enhanced ductility and high strength. The condition to achieve sustainable dislocation nucleation from a nanoprecipitate is governed by the lattice mismatch between the precipitate and matrix, with stress comparable to the recently reported high strength in metals with large amount of nanoscale precipitates. It is also shown that the combination of Orowan’s precipitate hardening model and our critical condition for dislocation nucleation at a nanoprecipitate immediately provides a criterion to select precipitate size and spacing in material design. The findings reported here thus may help establish a foundation for strength–ductility optimization through densely dispersed nanoprecipitates in multiple-element alloy systems.
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A nanodispersion-in-nanograins strategy for ultra-strong, ductile and stable metal nanocomposites
Abstract Nanograined metals have the merit of high strength, but usually suffer from low work hardening capacity and poor thermal stability, causing premature failure and limiting their practical utilities. Here we report a “nanodispersion-in-nanograins” strategy to simultaneously strengthen and stabilize nanocrystalline metals such as copper and nickel. Our strategy relies on a uniform dispersion of extremely fine sized carbon nanoparticles (2.6 ± 1.2 nm) inside nanograins. The intragranular dispersion of nanoparticles not only elevates the strength of already-strong nanograins by 35%, but also activates multiple hardening mechanisms via dislocation-nanoparticle interactions, leading to improved work hardening and large tensile ductility. In addition, these finely dispersed nanoparticles result in substantially enhanced thermal stability and electrical conductivity in metal nanocomposites. Our results demonstrate the concurrent improvement of several mutually exclusive properties in metals including strength-ductility, strength-thermal stability, and strength-electrical conductivity, and thus represent a promising route to engineering high-performance nanostructured materials.
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- PAR ID:
- 10410478
- Date Published:
- Journal Name:
- Nature Communications
- Volume:
- 13
- Issue:
- 1
- ISSN:
- 2041-1723
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript
- Journal Article:
- https://doi.org/10.1038/s41467-022-33261-5
