Twinning is an important mode of plastic deformation in low crystal-symmetry materials, particularly hexagonal closepacked (HCP) metals, such as Zr, Mg, and Ti (Ref 1, 2). Deformation twins form first by nucleating twin embryos where suitable defects and stresses are present (Ref 3), mostly at grain boundaries (Ref 4), and then developing them into thin lamellae by propagation of the twin tip (Ref 5), and finally expanding the lamellae via twin boundary migration . This step-by-step process produces a three-dimensional (3D) volumetric twin domain with an abrupt lattice reorientation with respect to the parent crystal and localized shear. For instance, the 1012 È É tensile twin in Mg reorients the crystal by 86.3°and imposes a 12.9% characteristic shear (Ref 2). Consequently, heterogeneous micromechanical fields within and around the twin domains in the surrounding crystal are generated ( Ref 6,[11][12][13][14]. Accurate evaluation of the stress and strain fields at the twin tip and around the twin boundaries can provide insight into how twins develop after formation and affect the macroscopic deformation response (Ref 2,6,15). Various experimental techniques are used to measure the stress/strain fields, including surface techniques, such as highresolution electron backscatter diffraction (HR-EBSD) with digital image correlation (DIC), as well as nondestructive techniques, like 3D x-ray diffraction (3D-XRD). HR-EBSD with DIC is able to measure strain on the sample surface with approximately 50 nm spatial resolution and an error of 10 -4 (Ref 12). 3D-XRD is able to acquire spatially resolved micromechanical fields in the interior of the sample with$ 1 μm resolution and an error of 10 -3 (Ref 14). On the other hand, x-ray synchrotron with the differential aperture x-ray microscopy (DAXM) technique can obtain spatially resolved stress/strain fields from the interior of the sample with$250 nm resolution and errors of 10 -4 (Ref 13). Although these techniques have successfully measured the stress/strain fields associated with the twins, the spatial resolution is insufficient for understanding the twinning processes at twin boundaries and twin tips, which have facets/interfaces a few nm in length ( Ref 8,10,16,17). To overcome this issue, high-resolution transmission electron microscopy (HR-TEM) with nanobeam electron diffraction (NBED) method has been employed to map the elastic strain fields around a twin domain with a spatial resolution of$0.2 nm and an error of$6910 -3 (Ref 18). However, the elastic strain suggested by this technique is up to 10% in a relatively large region, far beyond the material elastic strain limit. These elastic strain fields are unrealistically high. Recently, the nanoelectron precession diffraction (N-PED) technique has been shown to obtain realistic elastic strain fields with a spatial resolution of a few nm (Ref 19,20). It has been successfully employed to map the elastic strain fields near the grain boundaries in boron carbide and dislocations in magnesium (Ref 19,20). In this work, this N-PED technique is employed to measure the elastic strains within and around 1012 È É tensile twin domains in HCP magnesium. The grain microstructure of a polycrystalline material can be heterogeneous and the twin morphology can be complex (Ref [21][22][23][24], making it difficult to deconvolute the source for the heterogeneity in the experimentally measured strain fields. It is unclear whether the measured strain fields are primarily governed by the intrinsic twinning shear process or twin morphology or by the interaction of twins with other microstructural features. In turn, it is almost impossible to develop a comprehensive understanding of deformation twins from experimentally measured stress or strain fields alone. To address this, a spatially resolved elasto-viscoplastic fast Fourier transform (EVP-FFT) model (Ref 25) is combined with the N-PED technique. Specifically, the EVP-FFT model is employed to identify the features of the twin responsible for the measured heterogeneous strain fields in and around the twin domains. First, the experimentally observed twinned crystal is simulated, and the model calculated strain fields are compared with N-PED measurements. The model predicts the twin-induced stresses and defect distributions that arise solely from the intrinsic twinning shear transformation, without the influence of external loads and nearby twins, which are difficult to fully characterize and account for. Furthermore, through a systematic investigation, the respective roles of the geometry of the twin, alignment of the twinning shear direction with the twin boundary, and the presence of neighboring twins on the development of elastic strains are analyzed.
The paper is structured as follows. The experimental details such as material, initial loading, strain mapping technique are presented in Sect. 2. Section 3 briefly describes the EVP-FFT framework for modeling twins explicitly. Measured and calculated elastic strain fields are presented in Sects. 4.1 and 4.2, respectively. The calculated dislocation density fields ahead of the twin in the surrounding crystal are discussed in Sect. 4.3. In Sects. 4.4 and 4.5, the effect of neighboring twins and twin morphology on the elastic strain fields is explored computationally. The main conclusions on the extent to which twin boundary irregularity and nearby twin structures affect the twin-tip fields and possible growth are given in Sect. 5.
A polycrystalline AZ31B magnesium alloy comprised of several hundred-micron size equiaxed grains was examined in this study. The initial texture of the material was found to have basal texture. The sample was compressed in the rolling direction to 2% engineering strain (Ref 20,(26)(27)(28). A section of the compressed sample was electropolished to electron transparency, enabling observation of the microstructure, which contained numerous lenticular twins terminating within grain interiors. A staggered array of twins was located, see Fig. 1a, and tilted such that a [ 1120] direction for both the parent grain and twin was aligned with the beam direction. The specimen was imaged using a Philips CM200 TEM operated at 200 kV with a 10-µm condenser aperture, creating a nearly parallel beam and diffraction spots rather than disks. The microscope was operated in TEM mode with the beam location and precession controlled by an external DigiSTAR unit. Spot diffraction patterns were recorded from a 2.5 µm92.7 µm region with a 10 nm step size, 4 nm beam size, 0.8°precession angle, and an exposure time of approximately 20 ms for each diffraction pattern. Using these diffraction patterns, a digital aperture was placed over the central spot to generate a virtual brightfield scanning transmission electron microscope (STEM) image that reveals diffraction contrast in the region, seen in Fig. 1a. Figure 1b shows an orientation map of the same region highlighting the abrupt change of in-plane orientation across the twin boundary. The observed twins are irregular in two ways. Firstly, they have unique morphologies, with rough twin boundaries that deviate from the 1012 È É twin boundary plane. Secondly, the long dimension of the twin (most likely the propagation direction) is misaligned from the twinning shear direction by$23°.
To calculate the elastic strain fields surrounding and within the irregular twins, a high-resolution scan with a step size of 4 nm was recorded in the region identified in Fig. 1b. Using the TOPSPIN software (NanoMEGAS) (Ref 29), the relative 2D elastic strain fields were calculated in the parent crystal surrounding the twin using a reference diffraction pattern from the location marked in Fig. 2. The reference location is selected in such a way that the diffraction pattern at that point would not be affected by the twins and thus can represent the un-twinned strained parent crystal. To calculate the elastic strains within the twin, a reference diffraction pattern is taken from the center of the twin, shown in Fig. 3. The reference point is$80 nm from the twin boundaries. The EVP-FFT model is built upon a periodic square grid of discrete voxels. The stresses, r x ð Þ, at each material point, x, are related to the elastic strains, e e x ð Þ, by a time-discretized Hooke's law:
In the above, C x ð Þ is the elastic stiffness tensor and the superscripts indicate an increment in time, t, by an amount Dt. The total strain tensor e x ð Þ is equal to the sum of the elastic strain and the plastic strain tensor. In the present work, the latter is comprised of plastic strain due to slip, e p x ð Þ, and the homogenous twin shear transformation strain, e tw x ð Þ, in the twin domain. Accordingly, the elastic strain, e e x ð Þ, is given by,
where _ e p x ð Þ is constitutively related to the stress through a sum over the N active slip systems that the user defines. _ e p x ð Þ is written as:
In the above, the Schmid tensor, m s , is the symmetric part of b s n s ð Þ , where b s and n s are the unit vectors along the slip direction and the slip plane normal, respectively, of slip system s. The strength s s c x ð Þ is the critical resolved shear stress (CRSS) needed to activate slip system s, _ c o is a normalization factor and n is the stress exponent. A twin domain is identified a priori in the crystal. Uniformly across the domain, the characteristic shear strain associated with the twin is reached by incrementing the strain, De tw x ð Þ, as follows:
where S tw is the characteristic twin shear of the material, and N tw is the user-defined number of twin strain increments, which is kept sufficiently large to ensure convergence. The strain tensors e tw and De tw are null outside of the twin domain.
Following the dislocation density (DD)-based hardening law, the CRSS, s s c x ð Þ for each slip system, s, is evolved as a function of strain rate and temperature (Ref 35). Below we provide a brief summary and for more details, refer the reader to (Ref 35).
The resistance to slip is determined through a sum of multiple factors and is written as:
The Peierls stress, s s 0 , represents the initial slip resistance of slip system s and is dependent on the initial dislocation density and intrinsic material properties. The scalar resistance s s debris is due to arrays of dislocation substructures and scales according to (Ref 36):
where K is a numerical constant equal to 0.086 (Ref 36, 37), b s is the Burgers vector, l is the shear modulus, and q debris is the total debris dislocation density. The density q debris is calculated through the sum of debris contributed by each slip system: The color scheme in the orientation map follows the standard stereographic triangle with respect to in-plane direction. Twin 2 is selected for elastic strain mapping, and the region is marked in (b) @q debris ¼ q X s f s @q s rem @c a dc s ðEq 7Þ
In the above, q is the rate coefficient for how debris accumulates and set to 4 in this work. The density q s rem is the remnant dislocation density of each slip system that contributes to the formation of debris. f s is a term that describes debris dislocation storage rates, which increases with the amount of debris collected as:
where A s is a temperature-dependent constant that describes how dislocation-dislocation interactions lead to the generation of debris. Lastly, s s forest represents the resistance to slip due to arrays of forest dislocations that block dislocation glide and scales as (Ref 38, 39): Here v is a dislocation interaction coefficient and is set to 0.9. In this work, dislocations of slip system mode, such as basal, prismatic, or pyramidal, can only be hardened by forest dislocations from the same type. The stored forest dislocation densities evolve via a competition between dislocation generation term with coefficient k s 1 that describes the trapping of gliding dislocations by forest dislocations and a thermally controlled annihilation term that represents the dynamic recovery of stored dislocations (Ref 27, 40, 41), i.e., @q s @c s ¼ k s
where the coefficient on the dynamic recovery k s 2 is given by:
where k, _ e; _ e 0 , D s , and g s are Boltzmann's constant, the strain rate at each voxel, a reference strain rate (set to be 10 7 1/s), a drag stress, and a normalized activation energy of slip system s.
The experimentally obtained STEM micrograph shown in Fig. 1 is digitized into a 3759350 voxel simulation cell, for use as the initial microstructure, so that the model surface microstructure exactly mirrors the observed one. Since the subsurface structure is not known and we employ periodic boundary conditions, a columnar microstructure is adopted with the thickness of 6 voxels in the Z-direction. To minimize the effect of periodicity and image forces, the crystal is encased in the x-y plane in a 50-voxel thick homogeneous layer, which approximates the response of polycrystalline Mg.
The STEM technique provided crystallographic orientations for the entire microstructure is used. The average crystallographic orientations of the parent grain and twin domains are (156°, 95°, 267°) and (69°, 85°, 86°), respectively, in the Bunge convention. The twin variant is identified to be 0112 À Á 0111 Â Ã , with both the twin plane normal and twin shear direction lying within the x-y plane. The twinning shear direction is oriented 23.05°counter-clockwise from the +y direction and the twin plane normal lies 22.90°counter-clockwise from the +x direction. As such, no strain gradients from the twin are expected in the z direction and the strain and stress fields of interest lie in the x-y plane.
As mentioned in Sect. Deformation twinning is initiated from an unloaded state to capture the strain fields that develop purely from the formation of the twins, without the effects of any arbitrary loading. Twinning occurs through the incremental development of the characteristic twinning shear, 12.9% for the 1012 È É tensile twin in pure Mg (Ref 1). After the twin has fully developed, the upper three z-layers of the simulation cell are virtually removed to create a free surface (Ref 34). This step is accomplished by setting the material properties of those layers to be an isotropic linear elastic material that is extremely compliant with a Young's modulus of 1 MPa, intended to approximate the response of a vacuum. The simulation cell is then allowed to relax to a new energetic minimum. The resulting micromechanical fields are expected to be closer in approximation to those obtained experimentally through surface techniques (Ref 34). In all cases presented below, the calculated strain fields after free surface relaxation are then compared with the measured ones.
Initially, we focus our attention on the development of a single twin, labeled "twin 2" in Fig. 1a, without the influence of the neighboring twins. Later, we study the combined effects of all the twins seen in Fig. 1.
The elastic strain fields around the twin tip were measured utilizing the N-PED technique described in Sect. 2. The reference point used for the elastic strain calculations surrounding the twin tip is marked in Fig. 2. From the measured strain fields shown in the top row, it is observed that tensile e e xx strains develop on both sides of the twin tip, while the e e yy strains are tensile on the left and compressive on the right side of the tip. Large elastic shear strains e e xy are concentrated in a small region ahead of the twin tip. Furthermore, the shear strains in the region to the right of the twin tip are around 0.3%, while a relatively strain-free region exists to the left side of the twin tip. It should be noted that the deformation history of the sample, specifically in the local region investigated in this study, is unknown, and the build-up of dislocation substructures in the grain could influence the strain measurement. The elastic strains are also measured inside the twin domain using a diffraction pattern obtained from the center of the twin as a reference. The calculated elastic strain fields inside the twin domain are shown in Fig. 3. The strain field inside the twin domain is relatively small and homogeneous compared to the surrounding parent crystal. The observed low strain values result from the choice of reference point, which is taken from the same twin domain. The actual absolute elastic strain values, in other words, may be higher. The elastic strain profile along line C-D is plotted in Fig. 3d. Along line C-D, e e yy , and e e xy oscillate irregularly between ±0.5%, while e e xx is slightly compressive, with strains reaching -0.5%. Overall, the relative strains inside the twin are relatively homogenous and low, qualitatively consistent with observations from NBED techniques (Ref 18).
Figure 4 presents the calculated elastic strain fields that develop from the twin and free surface relaxation. These elastic strain fields are the actual values, unlike in the experiment where the relative strains are obtained. We postulate that the calculated strain fields would be roughly equivalent to the measured relative strains for the following reasons. In the calculations, no macroscopic loading is imposed so that calculated elastic strain fields result only from the twins. In the experiment, the reference point is taken from the parent grain, which has an effect of macroscopic loading and not the twinning shear. Thus, the measured relative strain fields most likely developed from the twins and not from the macroscopic loading, making them synonymous with those calculated.
The elastic strain fields e e xx , e e yy , and e e xy inside the twin domain are shown in Fig. (4b-d), and those in the parent matrix in Fig. (4e-g). The predicted strain components e e yy and e e xy agree well with the experimentally observed values. A strain asymmetry for e e yy can be seen, with tensile strains up to 0.03% on the left of the twin tip and compressive strains up to -0.04% on the right of the twin tip. The e e xy component shows a large localization at the twin tip, which agrees with the experiment. The e e xx strain component exhibits the largest discrepancy from the experimentally measured values. As shown in Fig. 4e, the e e xx fields ahead of the twin tip are compressive and decreasing in a conical shape moving away from the twin tip.
To directly compare with the strains measured along a line crossing the twin tip, the calculated strains along the line A-B marked in Fig. 4e, are plotted in Fig. 4h. Along line A-B, the model predicts compressive e e xx strains on both sides of the twin tip, with slightly lower strains of $ -0.005% on the left side and -0.02% on the right side of the twin tip. However, the calculated e e xx fields are relatively low compared to the other strain components, and it is possible that dislocation structures near the twin tip could result in relatively higher measured strains. All the measured e e xx , e e yy , and e e xy strain components, seen in Fig. 2, extend as a diagonal band, which likely developed due to external loading, deformation history not accounted for in simulation.
Compared to the experimentally measured strains, the calculated e e xx , e e yy , and e e xy strain components are more uniform inside the twin, as seen in Fig. 4b-d. For a closer view, Fig. 4i plots these components along the line C-D. As shown, the model predicts that e e xx is positive, and e e yy and e e xy are negative. However, the measured e e xx is negative, while both e e yy and e e xy oscillate in sign. The discrepancy in strain inside the twin domain could be due to the simplified model geometry used for the remaining twin domain outside of the STEM micrograph. Also, the oscillations in the e e yy and e e xy components could be due to the presence of dislocations that cut across the twins, as seen in Fig. 1a.
In addition to the elastic strains, the EVP-FFT model predicts all components of the stress tensor. The calculated distributions of stress components r xx , r yy , and r xy are shown in Fig. 5a-c, respectively. The out-of-plane stress components, r zz , r yz , and r xz , are nearly zero everywhere, as expected from the free surface relaxation boundary conditions we imposed. The calculated nonzero stresses are within reasonable limits of Mg and of the similar range as those measured by x-ray diffraction techniques (Ref 14). Additionally, the twin plane resolved shear stresses (TRSS) are calculated by resolving the stress tensor at each material point on the crystallographic twin plane and along the twinning shear direction. Figure 5d presents the TRSS map around the twin structure. Any positive TRSS value is a potential driving stress for the development of the twin. It can be observed in Fig. 5d that a positive TRSS concentrated at the tip of the twin in a conical shape with the line of height that is rotated counterclockwise from the vertical by approximately 23°. This driving stress is nearly symmetrically aligned about the twinning shear direction and favorable for propagation in the direction along the long dimension of the twin.
The analysis, thus far, indicates that the asymmetric shape of the twin tip generates an asymmetric stress/strain field in the surrounding parent crystal ahead of it. The magnitudes of these stresses are sufficiently intense to be accommodated by plasticity. It is anticipated that the resulting distributions of dislocations would be heterogeneous as well. Figure 6a-c shows the calculated total dislocation density per slip mode. The dark blue regions correspond to the initial dislocation density. Prismatic and pyramidal I type dislocations can be seen at the twin tip and locally around some regions of the twin boundary; however, they mainly develop within the twin domain itself. Basal dislocation density accumulates both within the twin and in the parent matrix far away from the twin. However, band of concentrated dislocation density can be observed emanating from the twin tip at an angle approximately 30°clockwise from the vertical direction. The calculated dislocation distributions are consistent with the observed dislocation arrays that can be seen emanating from the twin tip in the STEM micrographs, see in Fig. 6d, as well as in other studies (Ref 21, 44-46).
Up to now, we analyzed the micromechanical fields that are generated ahead of a twin tip assuming the twin was isolated. However, the actual microstructure shown in Fig. 1 contains many nearby parallel twins that may influence the measured elastic strains (Ref 26,47,48). To determine the extent at which neighboring twins can influence strains that develop around a single twin, an additional simulation was performed, wherein which all five twin domains seen in the STEM micrograph were modeled, as illustrated in Fig. 7a. The resulting strain fields are shown in Fig. 7c-e. Figure 7b presents the e e xx , e e yy , and e e xy strain components measured along line A-B, as marked in Fig. 7a. These components are remarkably like those in the isolated twin case, presented in Fig. 2h. The strain asymmetry across the twin tip is still observed for e e yy , with tensile strains reaching 0.045% on the left side of the twin and compressive strains reaching -0.04% on the right side. The e e xy component exhibits a comparable concentration at the twin tip, reaching shear strains of $0.04%. Lastly, e e xx along line A-B is tensile and nearly homogenous. Previously, it was noted that e e xx along the line A-B in the single twin was compressive. However, due to the fields of the nearby twins, e e xx increases slightly by $0.01% becoming tensile across the twin tip, more consistent with experimentally measured values. Evidently, the neighboring twins affect the strain fields at the twin tip, although minimally.
As seen in Fig. 4, twin boundaries tend to be asymmetric and wavy, and as mentioned earlier, this morphology is common for HCP twins. The twins studied here, for instance in Fig. 4a, are asymmetric and the apparent twin propagation direction (i.e., the direction of the longest dimension of the twin) is skewed from the twinning shear direction. Yet, to date, whether the geometry of the twin tip has any effect on its continued propagation has not been systematically studied.
To investigate the geometric effects of twins on their propagation, three hypothetical configurations are considered. Figure 8 shows all three configurations and the model calculated respective strain fields. In Fig. 8a-c, the same crystallographic orientation of the parent matrix is considered, as seen in Fig. 4, and thus the twinning shear direction is the same, but the twin morphology is idealized to be symmetric. Next, in Fig. 8d-f, the irregular twin morphology is preserved, but the crystallographic orientation of parent matrix is selected so that the twinning shear direction is now parallel to the longest dimension of the twin. Last, in Fig. 8g-i, the twin morphology is symmetric and the twinning shear direction aligned with the twin long dimension.
Figure 8 compares the strain fields for all three cases. Interestingly, the resulting elastic strain fields are remarkably similar to those seen in Fig. 4e-g. The only notable difference lies in the distribution of e e xx along the lateral sides of the twin in the symmetrically shaped twin compared to the original irregular twin. Furthermore, the elastic strain fields in Fig. 8d-f and Fig. 8g-i are nearly identical, although they clearly differ from the actual twin configuration shown in Fig. 4. These results imply that the twin geometry plays a relatively minor role on the distributions of the micromechanical fields, whereas the twinning shear direction has a greater influence on the measured micromechanical fields around a twin.
In this work, the elastic strain fields within and around 1012 È É tensile twins in AZ31B magnesium alloy are characterized. The elastic strain fields are measured using the nanoprecision electron diffraction (N-PED) technique. Unlike other nm resolution elastic strain measurement techniques, like nanobeam electron diffraction (NBEB), the measured strains values using the N-PED technique are realistic and within the elastic limit of the material. Also, the measured elastic strain values are very similar to those obtained using in-situ x-ray synchrotron techniques. Explicit simulation of deformation twinning using an EVP-FFT framework along with the free surface relaxation process correctly captures the experimentally measured heterogenicity in the elastic strain fields. Apart from the elastic strain fields, the EVP-FFT model also provides the dislocation density and stress fields, which are not easily obtainable from the experiment. The model was then used to elucidate the effects of nearby twins and the twin geometry on the development of elastic strains ahead of twin and within the twin. The simulation results reveal that the nearby twins weakly influence elastic strains around and inside a twin. As the final important finding, it is shown that the twinning shear direction is the major contributor to the observed micromechanical fields
Journal of Materials Engineering and Performance