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Abstract The Cambro‐Ordovician interval marks a significant transition from extinction to bio‐diversification in deep time. However, the relationship of bio‐transition to volcanism, commonly characterized by mercury (Hg) systematics in sedimentary records, has not been examined. We present the first Cambro‐Ordovician Hg systematics from the Scandinavian Alum Shale. Our results show pronounced Furongian Hg enrichments, coupled with positive Δ199Hg, Δ200Hg, and Δ201Hg values and negative Δ204Hg values that we ascribe to atmospheric Hg transport over long‐distances, while Early Ordovician Hg anomalies, characterized by near‐zero mass‐independent isotope values, indicative of submarine source. Our findings are supported by two new proxies: molybdenum‐Hg and vanadium‐δ202Hg co‐variations, demonstrating Hg systematics were strongly influenced by changes in source and depositional conditions. Constrained by a synchronous atmospheric‐tectonic‐oceanic model, we hypothesize Furongian subaerial volcanism contributed to global extinction and oceanic anoxia, whereas Early Ordovician submarine volcanism concurrent with ocean water upwelling promoted the nascent bio‐diversification.
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Mercury isotope evidence for marine photic zone euxinia across the end-Permian mass extinction
Abstract The driving forces, kill and recovery mechanisms for the end-Permian mass extinction (EPME), the largest Phanerozoic biological crisis, are under debate. Sedimentary records of mercury enrichment and mercury isotopes have suggested the impact of volcanism on the EPME, yet the causes of mercury enrichment and isotope variations remain controversial. Here, we model mercury isotope variations across the EPME to quantitatively assess the effects of volcanism, terrestrial erosion and photic zone euxinia (PZE, toxic, sulfide-rich conditions). Our numerical model shows that while large-scale volcanism remains the main driver of widespread mercury enrichment, the negative shifts of Δ199Hg isotope signature across the EPME cannot be fully explained by volcanism or terrestrial erosion as proposed before, but require additional fractionation by marine mercury photoreduction under enhanced PZE conditions. Thus our model provides further evidence for widespread and prolonged PZE as a key kill mechanism for both the EPME and the impeded recovery afterward.
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- Award ID(s):
- 1760203
- PAR ID:
- 10412159
- Publisher / Repository:
- Nature Publishing Group
- Date Published:
- Journal Name:
- Communications Earth & Environment
- Volume:
- 4
- Issue:
- 1
- ISSN:
- 2662-4435
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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