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1. Early Diagenesis in the Hypoxic and Acidified Zone of the Northern Gulf of Mexico: Is Organic Matter Recycling in Sediments Disconnected From the Water Column?

   https://doi.org/10.3389/fmars.2021.604330  

   Rabouille, Christophe; Lansard, Bruno; Owings, Shannon M.; Rabalais, Nancy N.; Bombled, Bruno; Metzger, Edouard; Richirt, Julien; Eitel, Eryn M.; Boever, Anthony D.; Beckler, Jordon S.; et al (March 2021, Frontiers in Marine Science)

   null (Ed.)

   Hypoxia and associated acidification are growing concerns for ecosystems and biogeochemical cycles in the coastal zone. The northern Gulf of Mexico (nGoM) has experienced large seasonal hypoxia for decades linked to the eutrophication of the continental shelf fueled by the Mississippi River nutrient discharge. Sediments play a key role in maintaining hypoxic and acidified bottom waters, but this role is still not completely understood. In the summer 2017, when the surface area of the hypoxic zone in the nGoM was the largest ever recorded, we investigated four stations on the continental shelf differentially influenced by river inputs of the Mississippi-Atchafalaya River System and seasonal hypoxia. We investigated diagenetic processes under normoxic, hypoxic, and nearly anoxic bottom waters by coupling amperometric, potentiometric, and voltammetric microprofiling with high-resolution diffusive equilibrium in thin-films (DET) profiles and porewater analyses. In addition, we used a time-series of bottom-water dissolved oxygen from May to November 2017, which indicated intense O 2 consumption in bottom waters related to organic carbon recycling. At the sediment-water interface (SWI), we found that oxygen consumption linked to organic matter recycling was large with diffusive oxygen uptake (DOU) of 8 and 14 mmol m –2 d –1 , except when the oxygen concentration was near anoxia (5 mmol m –2 d –1 ). Except at the station located near the Mississippi river outlet, the downcore pore water sulfate concentration decrease was limited, with little increase in alkalinity, dissolved inorganic carbon (DIC), ammonium, and phosphate suggesting that low oxygen conditions did not promote anoxic diagenesis as anticipated. We attributed the low anoxic diagenesis intensity to a limitation in organic substrate supply, possibly linked to the reduction of bioturbation during the hypoxic spring and summer. 

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2. A Two Decadal (1993–2012) Numerical Assessment of Sediment Dynamics in the Northern Gulf of Mexico

   https://doi.org/10.3390/w11050938  

   Zang, Zhengchen; Xue, Z. George; Xu, Kehui; Bentley, Samuel J.; Chen, Qin; D’Sa, Eurico J.; Ge, Qian (May 2019, Water)

   We adapted the coupled ocean-sediment transport model to the northern Gulf of Mexico to examine sediment dynamics on seasonal-to-decadal time scales as well as its response to decreased fluvial inputs from the Mississippi-Atchafalaya River. Sediment transport on the shelf exhibited contrasting conditions in a year, with strong westward transport in spring, fall, and winter, and relatively weak eastward transport in summer. Sedimentation rate varied from almost zero on the open shelf to more than 10 cm/year near river mouths. A phase shift in river discharge was detected in 1999 and was associated with the El Niño-Southern Oscillation (ENSO) event, after which, water and sediment fluxes decreased by ~20% and ~40%, respectively. Two sensitivity tests were carried out to examine the response of sediment dynamics to high and low river discharge, respectively. With a decreased fluvial supply, sediment flux and sedimentation rate were largely reduced in areas proximal to the deltas, which might accelerate the land loss in down-coast bays and estuaries. The results of two sensitivity tests indicated the decreased river discharge would largely affect sediment balance in waters around the delta. The impact from decreased fluvial input was minimum on the sandy shoals ~100 km west of the Mississippi Delta, where deposition of fluvial sediments was highly affected by winds. 

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3. Dynamic manganese cycling in the northern Gulf of Mexico

   https://doi.org/10.1016/j.marchem.2024.104466  

   Davis, Jessalyn E; Robinson, Rebecca S; Estes, Emily R; Oldham, Veronique E; Solomon, Evan A; Kelly, Roger P; Bell, Katherine E; Resing, Joseph A; Bundy, Randelle M (November 2024, Marine Chemistry)

   Transport processes along the river-ocean continuum influence delivery of nutrients, carbon and trace metals from terrestrial systems to the marine environment, impacting coastal primary productivity and water quality. Although trace metal transformations have been studied extensively in the Mississippi River Delta region of the Northern Gulf of Mexico, investigations of manganese (Mn) and the presence of ligand-stabilized, dissolved manganese (Mn(III)-L) and its role in the transformation of trace elements and organic matter during riverine transport and estuarine mixing have not been considered. This study examined the chemical speciation of dissolved and particulate Mn in the water column and sediment porewaters in the Mississippi River and Northern Gulf of Mexico in March of 2021 to explore transformations in Mn speciation along the river-ocean continuum and the impact of different processes on the distribution of Mn. Total dissolved Mn concentrations were highest in the Mississippi River and decreased offshore, while Mn(III)-L contributed most to the dissolved Mn pool in near-shore waters. Porewater profiles indicated that ligand stabilization prevented dissolved Mn(III) reduction below the depth of oxygen penetration and in the presence of equimolar dissolved iron(II). Dissolved Mn(III)-L was enriched in bottom waters at all Northern Gulf of Mexico stations, and diffusive flux modelling of porewater dissolved Mn suggested that reducing sediments were a source of dissolved Mn to the overlying water column in the form of both reduced Mn(II) and Mn(III)-L. A simple box model of the Mn cycle in the Northern Gulf of Mexico indicates that Mn(III)-L is required to balance the Mn budget in this region and is an integral, and previously unconsidered, piece of the Mn cycle in the Northern Gulf of Mexico. The presence of Mn(III)-L in this system likely has an outsized impact on trace element scavenging rates, oxidative capacity, and the carbon cycle that have not been previously appreciated. 

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4. Intraseasonal Variability of the Diurnal Cycle of Precipitation in the Philippines

   https://doi.org/10.1175/JAS-D-19-0152.1  

   Natoli, Michael B.; Maloney, Eric D. (November 2019, Journal of the Atmospheric Sciences)

   null (Ed.)

   Abstract Precipitation in the region surrounding the South China Sea over land and coastal waters exhibits a strong diurnal cycle associated with a land–sea temperature contrast that drives a sea-breeze circulation. The boreal summer intraseasonal oscillation (BSISO) is an important modulator of diurnal precipitation patterns, an understanding of which is a primary goal of the field campaign Propagation of Intraseasonal Tropical Oscillations (PISTON). Using 21 years of CMORPH precipitation for Luzon Island in the northern Philippines, it is shown that the diurnal cycle amplitude is generally maximized over land roughly 1 week before the arrival of the broader oceanic convective envelope associated with the BSISO. A strong diurnal cycle in coastal waters is observed in the transition from the inactive to active phase, associated with offshore propagation of the diurnal cycle. The diurnal cycle amplitude is in phase with daily mean precipitation over Mindanao but is nearly out of phase over Luzon. The BSISO influence on the diurnal cycle on the eastern side of topography is nearly opposite to that on the western side. Using wind, moisture, and radiation products from the ERA5 reanalysis, it is proposed that the enhanced diurnal cycle west of the mountains during BSISO suppressed phases is related to increased insolation and weaker prevailing onshore winds that promote a stronger sea-breeze circulation when compared with the May–October mean state. Offshore propagation is suppressed until ambient midlevel moisture increases over the surrounding oceans during the transition to the active BSISO phase. In BSISO enhanced phases, strong low-level winds and increased cloudiness suppress the sea-breeze circulation. 

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5. Surface macro- and micro-nutrients within the Copper River plume region respond to along-shore winds

   https://doi.org/10.1016/j.marchem.2025.104508  

   Ortega, ELS; Reister, I; Danielson, SL; Aguilar-Islas, AM (May 2025, Marine Chemistry)

   T he Copper River is a major source of freshwater to the Northern Gulf of Alaska (NGA) shelf with a seasonal cycle t hat reaches peak discharge in summer. This glacially-fed river also provides a large input of dissolved chemicals t o the NGA, and because of its large particle load, it impacts the distribution of particle-reactive elements. Summertime sampling of shelf water properties was carried out within the Copper River plume region during two y ears: first during a period of upwelling-favorable winds and higher river discharge (4–7 July 2019) and later during lower river discharge and more typical downwelling conditions (11–13 July 2020). Although these wind conditions were observed in separate years, both can occur over the course of a single summer. We found that the e xport of most nutrients to surface shelf waters was enhanced under upwelling-favorable winds accompanied by higher river discharge compared to downwelling conditions and lower discharge. For example, greater cross- shelf plume transport in 2019 resulted in higher mid-shelf surface inventories for nitrate +nitrite (N +N), silicic acid (H4 SiO 4 ), phosphate (PO4 3 − ), dissolved Fe (dFe), and dissolved Cu (dCu) compared to 2020. Entrainment of relatively macronutrient-rich subsurface waters under upwelling conditions may also have contributed t o the enhancement of these mid-shelf nutrient inventories. The observed high N:P ratios in plume waters were likely driven by the scavenging of P within particle-laden plume waters. Similarly, we observed lower than expected [dFe] (1.58 to 6.12 nM) in particle-laden plume waters, likely a result of enhanced scavenging combined with low concentrations of dissolved Fe-binding ligands. Although dNi and dZn have a river source, we observed lower concentrations in surface shelf waters under upwelling conditions, suggesting enhanced dilution b y relatively micronutrient-poor subsurface waters. Results highlight the influence of sub-seasonal variations in atmospheric forcing on nutrient distributions and suggest that this forcing also impacts the location and timing of primary production hotspots during summer, adding to the ecological mosaic of the NGA across a range of temporal and spatial scales. 

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