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1. Formation of the End-on Bound Lanthanide Dinitrogen Complexes [(R 2 N) 3 Ln–N═N–Ln(NR 2 ) 3 ] 2– from Divalent [(R 2 N) 3 Ln] 1– Salts (R = SiMe 3 )

   https://doi.org/10.1021/jacs.0c01021  

   Ryan, Austin J. ; Balasubramani, Sree ganesh ; Ziller, Joseph W. ; Furche, Filipp ; Evans, William J. ( May 2020 , Journal of the American Chemical Society)

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2. Reductive C–O Cleavage of Ethereal Solvents and 18-Crown-6 in Ln(NR 2 ) 3 /KC 8 Reactions (R = SiMe 3 )

   https://doi.org/10.1021/acs.inorgchem.3c00689  

   Chung, Amanda B. ; Stennett, Cary R. ; Moore, William N. ; Fang, Ming ; Ziller, Joseph W. ; Evans, William J. ( April 2023 , Inorganic Chemistry)
3. Evaluating electrochemical accessibility of 4f n 5d 1 and 4f n+1 Ln( ii ) ions in (C 5 H 4 SiMe 3 ) 3 Ln and (C 5 Me 4 H) 3 Ln complexes

   https://doi.org/10.1039/D1DT02427B  

   Trinh, Michael T. ; Wedal, Justin C. ; Evans, William J. ( October 2021 , Dalton Transactions)

   The reduction potentials (reported vs. Fc + /Fc) for a series of Cp′ 3 Ln complexes (Cp′ = C 5 H 4 SiMe 3 , Ln = lanthanide) were determined via electrochemistry in THF with [ n Bu 4 N][BPh 4 ] as the supporting electrolyte. The Ln( iii )/Ln( ii ) reduction potentials for Ln = Eu, Yb, Sm, and Tm (−1.07 to −2.83 V) follow the expected trend for stability of 4f 7 , 4f 14 , 4f 6 , and 4f 13 Ln( ii ) ions, respectively. The reduction potentials for Ln = Pr, Nd, Gd, Tb, Dy, Ho, Er, and Lu, that form 4f n 5d 1 Ln( ii ) ions ( n = 2–14), fall in a narrow range of −2.95 V to −3.14 V. Only cathodic events were observed for La and Ce at −3.36 V and −3.43 V, respectively. The reduction potentials of the Ln( ii ) compounds [K(2.2.2-cryptand)][Cp′ 3 Ln] (Ln = Pr, Sm, Eu) match those of the Cp′ 3 Ln complexes. The reduction potentials of nine (C 5 Me 4 H) 3 Ln complexes were also studied and found to be 0.05–0.24 V more negative than those of the Cp′ 3 Ln compounds. 

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4. Synthesis, Structure, and Magnetism of Tris(amide) [Ln{N(SiMe 3 ) 2 } 3 ] 1− Complexes of the Non-traditional +2 Lanthanide Ions

   https://doi.org/10.1002/chem.201800610  

   Ryan, Austin J. ; Darago, Lucy E. ; Balasubramani, Sree Ganesh ; Chen, Guo P. ; Ziller, Joseph W. ; Furche, Filipp ; Long, Jeffrey R. ; Evans, William J. ( May 2018 , Chemistry - A European Journal)
5. Reactivity of [Ce(NR 2 ) 3 ] (R = SiMe 3 ) with Prospective Carbon Atom Transfer Reagents

   https://doi.org/10.1021/acs.organomet.0c00186  

   Kent, Greggory T. ; Staun, Selena L. ; Wu, Guang ; Hayton, Trevor W. ( July 2020 , Organometallics)

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