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Title: Decarboxylative ring-opening of 2-oxazolidinones: a facile and modular synthesis of β-chalcogen amines
We report herein the synthesis of primary and secondary β-chalcogen amines through the regioselective ring-opening reaction of non-activated 2-oxazolidinones promoted by in situ generated chalcogenolate anions. The developed one-step protocol enabled the preparation of β-selenoamines, β-telluroamines and β-thioamines with appreciable structural diversity and in yields of up to 95%.  more » « less
Award ID(s):
1942971
NSF-PAR ID:
10420352
Author(s) / Creator(s):
; ; ; ; ; ; ;
Date Published:
Journal Name:
RSC Advances
Volume:
12
Issue:
53
ISSN:
2046-2069
Page Range / eLocation ID:
34496 to 34502
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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