Fabrication of highly stable, reversible, and efficient portable sensors for the detection of explosives for safety and security is challenging due to the robustness of the currently available detection tools, limiting their mass deployment to the explosion prone areas. This paper reports a new direction towards the sensing of nitro- and peroxide-based explosives using highly stable rare-earth-doped BaWO 4 nanofibers with remarkable sensitivity and reversibility. BaWO 4 nanofibers doped with Tb 3+ and Eu 3+ ions are fabricated through a sol–gel electrospinning process, and their emission characteristics and application as a fluorescent probe for the sensing of 2-nitrotoluene and H 2 O 2 , explosive taggants representing a broad class of explosives, are studied in detail. Scheelite structured BaWO 4 nanofibers exhibit excellent luminescence characteristics, and the rare-earth ion doping in the polycrystalline BaWO 4 nanofibers is tailored to achieve blue, green, red, and white light emissions. These nanofibers are extremely sensitive to 2-nitrotoluene and H 2 O 2 with rapid response time, and sensitivity is observed within the range of 1–400 ppb and 1–10 ppm, towards 2-nitrotoluene and H 2 O 2 , respectively. The fluorescence quenching of BaWO 4 nanofibers in the presence of 2-nitrotoluene and H 2 O 2 is exponential with the quenching constants up to 1.73 × 10 6 and 2.73 × 10 4 L mol −1 , respectively, which are significantly higher than those of most of the fluorescent probes based on metal–organic frameworks and conjugated organic materials. After exposing to 2-nitrotoluene, the luminescence of the nanofibers is retained completely upon heating at 120 °C for 10 min and the sensory response is retained as fresh nanofibers, and currently available fluorescent explosive sensors could not achieve such a recovery. The high sensitivity and selectivity of scalable rare-earth-doped BaWO 4 nanofibers provide a new platform for the simultaneous detection of two classes of explosives.
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Color tunable aerogels/sponge-like structures developed from fine fiber membranes
The development of macroscopic aerogels from 1D systems, such as nanofibers, has resulted in a novel pathway to obtain porous and lightweight architectures. In this work, bright green, red, and tunable color emitting aerogels were obtained with luminescent nanofibers as the precursor system. A simple, low cost, and environmentally friendly process is followed where luminescent fillers are encapsulated within fibers which were subsequently freeze-dried to form 3D aerogels and sponge-like structures. Moreover, the aerogels/sponge-like structures show higher photoluminescence intensity than the fiber mats due to an increase of porosity which provides higher and direct interaction with the fillers and therefore an efficient light absorption resulting in higher luminescence. Manganese doped zinc germanate (Mn: Zn 2 GeO 4 ) nanorods and chromium doped zinc gallate (Cr: ZnGa 2 O 4 ) nanoparticles were used as the source of green and red emissions respectively. By precisely adjusting the stoichiometric ratios of nanorods and nanoparticles within the nanofibers, a broad spectrum output is obtained from the final aerogels. We foresee that these types of photoluminescent aerogels have promising potential applications in a variety of fields such as display devices, solid-state lighting, sensors, etc.
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- Award ID(s):
- 2122178
- PAR ID:
- 10420474
- Date Published:
- Journal Name:
- Materials Advances
- Volume:
- 3
- Issue:
- 6
- ISSN:
- 2633-5409
- Page Range / eLocation ID:
- 2716 to 2725
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/D1MA00946J
